Spin Dependent Hopping in Ti Doped La0.67 Ca0.33 MnO3

A systematic investigation of the magnetic and transport properties of Ti doped La0.67Ca0.33MnO3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x =0. 055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system.     

Effects of Y and Ce on Microstructures and Properties of Nb-Si System Composites

The effects of yttrium and cerium on microstructures and properties of Nb-Si system composites were investigated by scanning electron microscopy( SEM), energy dispersive spectrum(EDS), X-ray diffraction(XRD) and high temperature oxidation experiments.It is found that the coarse primary silicide phase became finer and more homogeneous with Y and Ce addition.The results of high temperature oxidation experiments show that the oxidation rates of NbSi system composites with an appropriate amount of Y and Ce decrease compared with those of alloys without Y or Ce addition, and oxidation products mainly distribute along the phase boundaries between the Nb solid solution and silicide.     

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白马庙气田蓬莱镇气藏储层致密 ,孔隙结构复杂 ,非均质性强 ,单井产能低 ,研究储层特征和受控因素 ,加强储层改造方是气藏效益开发的出路。储层精细研究揭示 ,气井产能受沉积相和构造条件控制 ;高、中产井与大而厚、物性好的河口坝、河道砂坝沉积微相有关 ,纵向上具很强的层段性 ,主产层集中在Ⅳ～③、Ⅲ～③两套砂组 ,其钻探成功率分别达 82 %和 10 0 % ;平面上多分布于主体构造和东南鼻状突起 ,二者高、中产能井分别占 30 %和 70 %。在深入的地质研究和储层压裂评层选井的基础上 ,采用多层打开、分层压裂、多层合采的方法可提高气井产能 ,并形成了一套行之有效的压裂评层选井的综合配套技术。采用该技术优选出 19口井 ,已实施 5口井全获成功 ,气产量成倍或十几倍增加 ,其中白浅 4 5井气无阻流量高达 18× 10 4m3 /d ,白浅 38井投产 16 5d净增产值 10 0余万元     

Synthesis, Characterization and Crystal Structure of Quaternary Complex of Gadolinium （Ⅲ）

Ａｎｕｍｂｅｒｏｆｌａｎｔｈａｎｉｄｅｔｅｒｎａｒｙｃｏｍｐｌｅｘｅｓｃｏｎ ｔａｉｎｉｎｇｈｅｔｅｒｏｃｙｃｌｉｃａｍｉｎｅｓｈａｖｅｂｅｅｎｒｅｐｏｒｔｅｄｓｉｎｃｅ1960 [1] .Ｉｎｒｅｃｅｎｔｙｅａｒｓｍｕｃｈａｔｔｅｎｔｉｏｎｈａｓｂｅｅｎｐａｉｄｔｏｑｕａｔｅｒｎａｒｙｃｏｍｐｌｅｘｅｓｏｆｌａｎｔｈａｎｉｄｅｓｂｅｃａｕｓｅｏｆｉｎ ｔｅｒｅｓｔｉｎｇｓｔｒｕｃｔｕｒｅ ,ｃｏｏｒｄｉｎａｔｉｏｎｍｏｄｅ ,ｃｏｍｐｅｔｉｔｉｏｎｒｅ ａｃｔｉｏｎａｎｄｐｒｏｐｅｒｔｙ[2～ 9] .ＥＳＲｃａｎｅ…     

稀土改善09CuPTiRE耐候钢耐蚀性的作用机理

应用扫描电镜(SEM)、离子探针(IMA)、X射线光电子能谱(XPS)和交流阻抗法研究含不同稀土耐候钢稀土提高耐大气腐蚀作用机理。结果表明,合适的稀土含量可显著提高钢的耐腐蚀性,稀土能促进Si、Cu和P在内锈层中以Si~(4+)、Cu~+和P~(5+)形态富集,并观察到锈层中的稀土。钢中加入稀土形成了致密连续厚而粘附性好的含硅铜稀土的复合铁锈层,从而提高了抗大气腐蚀性能。     

Low temperature synthesis of aluminium titanate by an aqueous sol-gel route

Formation of aluminium titanate (AT) has been achieved at low temperature through sol-gel process using boehmite and titanium hydroxide as precursors by controlling the particle size at nanoscale followed by in-situ peptisation. The formations of AT phase, particle size distributions, sintering and thermal expansion characteristics, and microstructural features have been reported. DTA and XRD analysis have been performed to confirm the formation of AT. A 94% relative density was obtained for aluminium titanate sintered at 1550 °C with controlled grain size in the range of 2-3 μm.     

难洗选铁矿工艺流程改造

介绍了他达铁矿高平洗选厂由于矿石原矿性质变化，原工艺流程已不能满足生产要求，进行技改的措施、工艺设计。     

影响铁精矿K2O、Na2O、SiO2含量的因素分析

用统计分析方法 ,分析了影响精矿K2 O、Na2 O、SiO2 含量的因素 ,并根据分析结论提出了对生产工艺进行定向控制的条件     

稀土棕红色陶瓷颜料的制备

在低温下,采用溶胶均匀共沉淀法合成了含少量稀土氧化物CeO2的棕色陶瓷颜料,并应用颜色测定、SEM及XRD分析等手段对颜料的颜色、粒度及结晶构造进行了表征。同时,将合成的颜料应用于陶瓷釉料中,表明该颜料可以应用于1320℃的高温环境下。     

鞍钢现有人造富矿产能及1600万t/a生铁规模的合理炉料结构的探讨

简要介绍了鞍钢现有人造富矿生产能力，分析了鞍钢生产1600万t／a生铁所需要的炉料数量、品种和质量，并提出了解决炉料缺口的方法和措施。