化学法处理混合电镀废水及药剂选择

通过热动力学分析、理论计算和实验,确定在碱性条件下用NaClO作氧化剂,Na₂S和FeSO₄作还原剂处理混合电镀废水的工艺流程,并通过计算和实验确定了Na₂S与FeSO₄的最佳药剂比:Na₂S为80%~90%,FeSO₄为10%~20%.Na₂S+FeSO₄比单独使用FeSO₄少产生60%~70%的污泥.该工艺在实际工程运行过程中效果良好.     

二维磁性材料与自旋系统研究进展

自旋系统是一类基于电子自旋工作的器件,具有高速、低功耗等优点,其中磁存储器被认为是下一代存储器的领跑者之一。二维材料有着天然的界面性能优势,接近微缩极限的尺寸特点,以及二维结构带来的物理特性,在自旋系统中有望得到广泛运用。本文概述了二维材料在自旋领域的最新研究进展,介绍了一些常见的二维磁性材料,讨论了基于二维材料的二维自旋器件,以及回顾了基于二维材料的磁性调控,最后总结了这一领域仍然面临的挑战,并对未来发展进行了展望。     

垃圾焚烧发电技术主要问题及其对策

介绍了我国城市生活垃圾的主要处理方式;通过对国内外情况的比较与分析,得出我国城市生活垃圾处理的最佳方式是CFB焚烧(垃圾与煤可混烧)发电;介绍了CFB发电技术的特点、工艺流程、存在的问题及未来的发展前景。     

NiCuZn ferrite flakes prepared using a sol-gel bubble method and its magnetic properties

Ni_0.23Cu_0.11Zn_0.66Fe₂O₄ ferrite flakes, with thickness of about 8 μm and average diameter of 20-35 μm, were prepared using a sol-gel bubble method. Morphology, phase evolution, static and dynamic magnetic properties of the flakes and their composites were studied. Magnetic measurements showed that easy magnetization direction of the flaky filler composite was parallel to its sample plane. Composites made of silicone resins and flakes had higher complex permeability, which can be attributed to the reduction in demagnetization factor due to their flaky shapes. This sol-gel bubble method should be also applicable to fabricating flakes of other multi-component oxides.     

Structural, magnetic and dielectric properties of La2−xCaxNiO4+δ (x = 0, 0.1, 0.2, 0.3)

The synthesis, structural, magnetic and dielectric properties of a new type of high permittivity materials La_2−xCa_xNiO_4+δ (x = 0, 0.1, 0.2, 0.3) (abbreviated as LCNs) were reported. The samples were prepared through conventional solid state reaction route. Detailed structural information was retrieved by Rietveld refinement; normalized bond length and bond valence was calculated to investigate the compression/dilation effect of bonds and atoms in unit cell. It can be found all samples belong to K₂NiF₄ structure with space group I4/mmm. Doping of Ca in La₂NiO_4+δ shrinks the unit cell and makes the structure tend to become instable. Three types of (La, Ca)-O bonds, and two kinds of Ni-O bonds exist in LCNs. Along c axis there are alternately compressed (La,Ca)O₉ dodecahedra and lengthened NiO₆ octahedra. Room temperature magnetic measurements show that the materials are paramagnetic and Ca doping can improve the spontaneous magnetization. Furthermore, all samples have colossal values of the dielectric constant (?) at frequencies lower than 1 kHz. Interestingly, La_1.8Ca_0.2NiO_4+δ maintains its high permittivity at frequencies up to 1 MHz while La_1.7Ca_0.3NiO_4+δ has the lowest dielectric loss (tan δ). Calcium doping can effectively enhance ? and inhibit tan δ. The distortion of (La,Ca)O₉ dodecahedra can well explain their dielectric properties.     

Cobalt-iron cyanide hollow cubes: Three-dimensional self-assembly and magnetic properties

Cobalt-iron cyanide hollow cubes have been synthesized via a poly(vinylpyrrolidone) assisted solvothermal route. A unique formation process: self-assembly followed by Ostwald ripening process, has been put forward to take account for the construction of hollow cubes. The rod-like nanocrystals first assemble as porous cubes via an oriented attachment process. Then, the porous cubes undergo an Ostwald-ripening process, which create interior spaces and result in the formation of hollow cubes. The magnetic property investigation reveals that K_0.22Co_0.58Fe_2.2(CN)₆ hollow cubes exhibit a ferromagnetic behavior.     

Mixed Messages about Mixed Tenure: Do Reviews Tell the Real Story?

Mixed tenure is the predominant development and regeneration strategy and is a key component of UK housing and urban policy. It is purported to provide wide-ranging social, environmental and economic benefits to residents. While there is a large literature on mixed tenure, policy makers are likely to rely on reviews and summaries of the evidence rather than primary studies. But can they rely on such reviews? Using systematic review methods this paper critically appraises recent reviews for the evidence that mixed tenure policies and strategies have achieved any of these expected benefits. Of the six UK reviews of primary studies, most drew on less than half the available primary studies, none provided a critical appraisal of individual studies and made no comment on conflicting evidence between and within studies. While the reviews gave indications of the deficiencies of the evidence base, rather than focus on the implications of these deficiencies, four of the six reviews emphasised the positive effects of tenure mix.     

提高铝土矿选精矿过滤效率研究

铝土矿选精矿过滤脱水难的问题一直困扰着选矿-拜耳法生产,针对陶瓷过滤机在当前使用中效率极差问题,本文从影响过滤效率的各个方面进行了大量的实验研究工作,分析了影响陶瓷过滤机效率的原因并提出了对策,对解决当前铝土矿选精矿的过滤脱水难的问题具有一定的指导意义。     

兆瓦级双馈风力发电机混合绕组谐波分析

推导并分析了Y-△混合绕组的绕组系数及谐波幅值强度,并将之用于兆瓦级的双馈风力发电机中,通过有限元仿真分析了不同定转子槽型对谐波的影响,并与普通Y绕组进行对比,指出Y-△混合绕组能提高基波分量的绕组系数,同时对某些谐波能降低甚至消除。本文介绍的分析方法有助于风力发电机的电磁性能优化设计。