利用α-甲基苯乙烯合成佳乐麝香的研究

介绍一种新的佳乐麝香合成方法，并就反应的参数对反应过程的影响进行了探讨。     

Fatty acid esterification by reactive distillation: Part 2—kinetics-based design for sulphated zirconia catalysts

In a previous study on the basis of reaction equilibrium, it was demonstrated that the synthesis of fatty acids esters of heavy alcohols by catalytic reactive distillation (RD) is basically feasible. Presently, the analysis is expanded to the kinetics-based design applied to the synthesis of 2-ethylhexyl dodecanoate. Experimental data for a super-acidic sulphated zirconia catalyst are employed. It is shown that this catalyst is highly selective even for the high alcohol/acid ratios as prevail in a RD column. To avoid catalyst deactivation, liquid-liquid segregation into an organic and an aqueous phase must be prevented, and operating temperatures beyond must be chosen. A kinetic model based on liquid activities is proposed, with parameters determined from both kinetic and equilibrium measurements. A typical column design has 13 reactive stages with a catalyst loading of , temperature profile of 400-, and a space velocity of for 99.9% purity product ester. A modified Damköhler number is proposed.     

Online stiffness estimation for robotic tasks with force observers

In this paper we propose an online stiffness estimation technique for robotic tasks based only on force data, therefore, not requiring contact position information. This allows estimations to be obtained in robotic tasks involving interactions with unstructured and unknown environments where geometrical data is unavailable or unreliable. Our technique – the Candidate Observer Based Algorithm (COBA) – uses two force observers, configured with different candidate stiffnesses, to estimate online the actual target object stiffness. COBA is embedded in a force control architecture with computed torque in the task space. The theoretical presentation of the algorithm, as well as simulation tests and experimental results with a lightweight robot arm are also presented.     

一种关于目标罚参数的精确罚函数法

罚函数法是一种将约束优化问题转化为无约束问题的重要方法.对于一般的约束优化问题,通过加入新参数,给出了一种改进的精确罚函数和这种罚函数的精确罚定理证明,提出了求解这种罚函数的算法.实验表明该算法是有效的.     

磁力驱动器涡流损失的研究

对磁力驱动器金属隔离套在交变磁场中引起的涡流损失进行了理论计算 ,并与实测结果进行了对比。指出合理选择金属隔离套的相关参数 ,可以有效控制涡流损失的大小     

Continuous-velocity lattice gas cellular automata for miscible binary fluid and its application to simulation of interface instability

Continuous-velocity lattice gas cellular automata (CVLGA) is extended to miscible binary fluid systems. A new parameter is introduced in order to control the diffusivity of the fluids. The correlation between the diffusivity and the new parameter proves that there exists the maximum value of the diffusivity. Quantitative verifications of the model are carried out with numerical simulations of the diffusion phenomena across a falling fluid film. The model is then applied to the simulations of Rayleigh-Taylor instability during the gravitational mixing phenomena. The qualitative tendency of the growth of the interface instability is the same as that obtained in conventional numerical methods.     

Study of probability integration method parameter inversion by the genetic algorithm

In order to obtain accurate probability integration method(PIM) parameters for surface movement of multi-panel mining, a genetic algorithm(GA) was used to optimize the parameters. As the measured surface movement is affected by more than one mining panel, traditional PIM parameter inversion model is difficult to ensure the reliability of the results due to the complexity of rock movement. With crossover,mutation and selection operators, GA can perform a global optimization search and has high computation efficiency. Compared with the pattern search algorithm, the fitness function can avoid falling into local minima traps. GA reduces the risk of local minima traps which improves the accuracy and reliability with the mutation mechanism. Application at Xuehu colliery shows that GA can be used to inverse the PIM parameters for multi-panel surface movement observation, and reliable results can be obtained. The research provides a new way for back-analysis of PIM parameters for mining subsidence under complex conditions.     

热作模具钢热疲劳损伤因子的研究

由于Uddeholm标准图谱评定热疲劳程度尚不够完善，无法精确地评定热疲劳裂纹的级别，因此编制了一套计算机图像分析软件，对热疲劳裂纹进行定量分析，并完善了热疲劳损伤因子，用它定量地分析了进口8407和国产4C45MoSiV1热作模具钢的热疲劳性能，揭示了热模钢的热疲劳性能的变化规律，实现了热疲劳裂纹的计算机辅助评定。     

Φ159mm限动芯棒连轧管机组限动速度的确定

芯棒是限动芯棒连轧管机组的主要变形工具之一,限动速度的合理设定有助于减小芯棒磨损,提高产品质量,降低生产成本。采用MPM连轧数模及德国Meer公司的二级控制方法,可推算出与芯棒限动速度有关的参数,再根据生产实际予以修正,可以得到最佳参数。介绍了鞍钢集团新钢铁有限责任公司合理确定限动芯棒连轧管机组芯棒限动速度的方法。     

一类自适应预测控制方法及在电液比例控制中的应用

为电液比例系统提供了一个输入输出增量式线性时变模型，采用加权限定记忆回归法来估计模型参数，在此基础上进而提出了一种自适应预测控制方法，并给出了最优控制律，仿真结果表明了该线性时变模型和参数估计算法的可行性，表明该自适应预测控制方法具有优良的控制品质。