Modified Indigo Method For Gaseous And Aqueous Ozone Analyses

The indigo method developed by Bader and Hoigné for aqueous ozone analysis was modified to allow for both gaseous and aqueous ozone determination. Gas or water samples were extracted with a gas-tight syringe containing a known volume of indigo reagent. The modified procedure provided a more consistent basis for gaseous and aqueous ozone determination allowing for more accurate ozone mass balance calculations. Direct gaseous ozone UV absorbance with molar absorptivity of 3,000 M^?1cm^?1 at 258 nm was used as primary standard to determine the molar absorptivity of the indigo reagent. The molar absorptivity of indigo reagent, assuming a 1:1 stoichiometric ratio for the reaction between indigo and ozone, was determined to be 23,150 ± 80 M^?1cm^?1, or approximately 16 percent higher than that of 20,000 M^?1cm^?1 suggested by Bader and Hoigné. An independently calibrated membrane-electrode ozone monitor showed good correlation with indigo method results using the molar absorptivity value determined in this study. The apparent molar absorptivity of aqueous ozone at the wavelength of 258 nm measured by the modified indigo method increased from 2,400 to 3,600 M^?1cm^?1 in the investigated ozone concentration range of 0.4 to 11.0 mg/L. This variation might have been caused by the inherent interference of unidentified ozone byproducts, which presence was supported with scanning spectra in the wavelength range of 200 to 300 nm.     

3-溴-4-氟苯甲醛的气相色谱分析方法

采用气相色谱法,氢火焰离子化检测器,选用3%OV-17填充柱,正十三烷为内标,气化室和检测器温度为180℃,柱温120℃,对3溴4氟苯甲醛进行定量测定。该方法简单、快速、准确、适用,标准偏差0.26%,变异系数0.27%,平均回收率100.1%。     

高效液相色谱法在农药残留分析中的应用

介绍了高效液相色谱法在农药残留分析中的应用,列举了一些杀虫剂、除草剂、杀菌剂的分析方法,指出了高效液相色谱法在农药残留分析中发展方向。     

2D12型往复式压缩机气阀故障诊断的时频分析方法

分析了 2D12型往复式压缩机气阀的工作过程 ,针对气阀工作特点提取吸气阀与排气阀均关闭时刻的压缩阶段的局域声音信号 ,应用广义双线性时频法诊断气阀故障 ,给出了正常气阀和故障气阀的时频分析图     

—Review Paper—Current State-Of-The-Art Measurements Of Ozone In The Gas Phase And In Solution

This paper is a critical review and summary of the analytical procedures currently used by operating water utilities to control ozone treatment processes, considering disinfection as well as the many oxidative applications of ozone in water treatment applications. The role of common interferences in the various methods is described.

In operating U S., Canadian, European, and Japanese water treatment plants currently employing ozone as a primary disinfectant, ozone nearly always is followed by the addition of small quantities of chlorine, chlorine dioxide, or chloramine to provide the residual in the distribution system and to act as a secondary disinfectant. Clearly, the analytical procedures used must distinguish between the various species. This review critically presents these various factors and their implication with respect to “true values” of ozone determined under widely varying conditions.     

The far infra-red spectrum of poly(vinyl chloride)

The far infra-red spectrum of a poly(vinyl chloride) sample prepared by the urea clathrate (UC) route has been measured at various temperatures in the range 60 to 320 K. The results, taken in conjunction with those for two less highly ordered polymers, indicate that a revision of the assignments of earlier workers, based on normal coordinate calculations and on the measured spectra of secondary alkyl chlorides such as 2-chlorobutane, is required. The band at 65 cm^?1 is attributed to a lattice mode and is not indicative of weak hydrogen bonds of the type CH…ClC. However, it is suggested that the band at 185 cm^?1, which is particularly clear and sharp with the UC polymer, probably originates from an interaction of this type, occurring specifically at tight chain folds.     

Internal fracture of notched epoxy resins

The brittle fracture of round-notched epoxy resin bars subjected to plane strain bending has been studied at varying strain rates. Observations of fracture processes and surface morphologies revealed that the internal crack was nucleated at the plastic-elastic boundary when the plastic deformation zone at the notch root reached a certain size. A slip-line field theory allows calculation of the stress components at the plastic-elastic boundary from a knowledge of the location of the internal crack. An analysis of the data concluded that the triaxial stress level ahead of the plastic zone was raised by plastic constraints to an ideal fracture stress which is considerably larger than that of glassy thermoplastics.     

论搜索软件对网络安全的影响

随着我国互联网技术的快速发展,我们今天的学习、工作和生活各个方面都离不开互联网技术的支撑,互联网技术对我们每一刻都会产生很大的影响,那么随着互联网技术的发展,搜索软件也逐渐占领了一席之地,并且在发展过程中,逐渐渗透到了网络中心的每一个角落,对于互联网技术的发展带来很大的影响.在这些网络发展和利用过程中,很多的私人信息、重要数据等成为了病毒或者是黑客的攻击对象,那这些行为对于网络的安全使用带来了很大的威胁,因此正确的认识到这些漏洞所在,针对搜索软件对于网络安全使用的影响效果进行分析探讨,从而提出有效的解决方式来提高网络的安全使用性能.     

磁力驱动器涡流损失的研究

对磁力驱动器金属隔离套在交变磁场中引起的涡流损失进行了理论计算 ,并与实测结果进行了对比。指出合理选择金属隔离套的相关参数 ,可以有效控制涡流损失的大小     

软件工程标准化现状与分析

当前社会已进入信息化时代,计算机技术在人们生活中的应用十分的广泛,计算机信息技术在很大的程度上推动了我国的经济社会的发展,促进了我国的国家建设,并且加快了我国实现工业化以及现代化的进度。而软件工程则是计算机信息技术中的重要组成,软件工程是整个信息系统中的最为重要的部分。本文对软件工程的标准化现状进行了相关分析,并提出了加强我国软件工程标准化体系的制定的步骤。