圆形离心浮选机的研究与应用

圆形离心浮选机是由自吸式气泡发生器和圆柱—圆锥形分选槽体组成的浮选设备 ,利用矿浆射流形成的离心力场强化了重力场中的气泡碰撞矿化和泡沫析出过程。工业试验结果表明 :圆形离心浮选机对煤泥特别是细煤泥的浮选效果好 ,具有浮选速度快 ,分选选择性好 ,单位容积处理能力大等优点 ,是实现微细矿物分选的有效设备     

Adsorption and decomposition of H2S on Pd(1 1 1) surface: a first-principles study

Gradient-corrected density functional theory was used to investigate the adsorption of H₂S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H₂S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H₂S decomposition giving rise to adsorbed S and H were determined. Both H₂S_(ad) → SH_(ad) + H_(ad) and SH_(ad) → S_(ad) + H_(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H₂S on Pd(1 1 1) surface is a facile process.     

浅析硫磺回收装置中的自动控制设计

大规模高含硫原油的炼制工艺必须配套设置脱硫和硫磺回收装置。笔者针对硫磺回收装置的特点,为确保装置的安全平稳运行,提出了该装置自动控制设计中需要严格监控的工艺参数及重点部位,叙述了仪表选型原则和精确测量与控制的原理和方法。     

200kt／a蒸馏装置硫腐蚀典型事例分析

通过对200kt/a蒸馏装置几起硫腐蚀典型事例的分析,提出了改进措施,消除了腐蚀泄漏隐患,确保了装置安全、平稳、长周期运行。     

某硅线石矿石选别中除铁研究

针对矿石中硅线石微细嵌布，铁矿物嵌布亦较细。且有近二分之一铁在非金属矿物晶格之中，除铁难的特点，通过试验研究对比采用一段磨矿磁选除铁后磁尾浮选富集硅线石．浮选精矿再磨后酸浸再除铁的工艺方法，获得了理想的除铁效果，使硅线石精矿质量达到较高品质。     

Laboratory simulated slipstream testing of novel sulfur removal processes for gasification application

The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project is investigating an Early Entrance Coproduction Plant (EECP) concept to evaluate integrated electrical power generation and methanol production from coal and other carbonaceous feedstocks. Research, development and testing (RD&T) that is currently being conducted under the project is evaluating cost effective process systems for removing contaminants, particularly sulfur species, from the generated gas which contains mainly synthesis gas (syngas), CO₂ and steam at concentrations acceptable for the methanol synthesis catalyst. The RD&T includes laboratory testing followed by bench-scale and field testing at the SG Solutions Gasification Plant located in West Terre Haute, Indiana. Actual synthesis gas produced by the plant was utilized at system pressure and temperature for bench-scale field testing.     

Sulfur distribution in coke and sulfur removal during pyrolysis

In order to investigate the mechanisms of coke desulfurization by blowing additional gas into coking chamber during pyrolysis process, some experiments were conducted to study the effects of some factors on the distribution of sulfur in coke. These factors include pyrolysis temperatures, the kinds of the blowing gases and the diameters of coking chamber. It was found that sulfur was mainly released at the range of 300–600 °C. Under this temperature range, the sulfur content in coke can be reduced by 0.05–0.06% by blowing N₂, CO or CH₄, and by 0.14% by blowing H₂ at a space velocity of 1.2 mm/s compared with the absolute sulfur content of 0.92% in the case without gas feeding. Obviously, H₂ is more effective on sulfur removal than N₂, CO or CH₄. The total, organic and inorganic sulfur contents in coke increase with increasing the diameter of coking chamber under identical pyrolysis conditions. Both organic and inorganic sulfur contents in coke increase regularly from the center to brim at identical height of a coke column for all the cases. In addition, the organic and inorganic sulfur contents at the cranny surface are higher than those in interior at the same sampling position. X-ray photoelectron spectroscopy (XPS) analyses suggest that the main contributions to the increase of inorganic and organic sulfur contents are due to the formation of negative bivalent sulfur and thiophenic compounds, respectively.     

含碳酸盐萤石矿石全弱酸性浮选新工艺

对含碳酸盐较高的萤石矿石提出了不加纯碱的全弱酸性浮选新工艺,获得CaF_298.21％、SiO_20.67％,回收率为93.25％的良好指标,实现了低模数碳酸盐—萤石矿石的高纯分离。     

横向光泵获得S_2紫外激光

用ＸｅＣｌ准分于激光器（３０８．１ｎｍ）横向泵浦Ｓ２激光器，又成功地实现了Ｓ２Ｂ－Ｘ态近ＵＶ波段的激光振荡。在波长３３０．９～３９０．０ｎｍ范围内观测到６条近ＵＶ激光输出。测量了有关的激光参数。