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41.
Progress in flotation de-silica 总被引:1,自引:1,他引:1
胡岳华 《中国有色金属学会会刊》2003,13(3)
1 INTRODUCTIONBayer sprocessisatypicalmethodtoproducea luminumoxidefrombauxite .Forthediasporic baux ite ,theBayer sprocesscaneconomicallyproducealu minumoxideonlywhenthemassratioofAl2 O3toSiO2 >10 .However ,inChina ,thealuminumoxidewasmainlyproducedbyusing“sinteringprocess”or“in parallelBayer sinteringcombination process”technologiesbecausethediasporic bauxiteischarac terizedbyhighcontentofaluminumoxideandsilicabutlowAl2 O3/SiO2 (average 5 6 ) .Thesetwotech nologieshavetheproble… 相似文献
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Sun Shuiyu Wang Dianzuo Li Bodan Central-South University of Technoloyy Changsha China 《中国有色金属学会会刊》1993,(3)
The adsorption mechanisms of HS~- ions existing in air-saturated alkaline solutions on sulphide minerals (including pyrite, arsenopyrite, chalcopyrite and galena) were investigated. The measurement of adsorption density, solvent extraction-chemical analysis of neutral sulphur at the surfaces, measurements of pulp potential and voltammogram, and flotation tests were done. Both the electrochemical and non-electrochemi cal adsorption models of HS~- ions were established. The former was observed and resulted in the formation of neutral sulphur (S°)when the pyrite and arsenopyrite were chosen, and hence renders the surfaces hy drophobic and induced the two minerals flotation. It is called Na_2S-induced flotation. On the other hand, the latter took place and did not produce S° when the chalcopyrite and galena were selected, and hence de presses the collectorless flotation of the two minerals. The adsorptions of HS~- ions were mainly influenced by potentials, pH and the electron structures of the mineral surfaces. 相似文献
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PRESSUREDISTRIBUTIONINTHEAIR-SPARGEDHYDROCYCLONE¥Chu,Liangyin;LuoQian(MineralEngineeringDepartment,NortheasternUniversity,She... 相似文献
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FLOWFIELDINAIR-SPARGEDHYDROCYCLONEChu,Liangyin;Luo,Qian(MineralEngineeringDepartment,P.O.Box139NortheasternUniversity,Shenyan... 相似文献
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提出抑制锌硫首先脱除石墨,铜铅混选及分离,锌硫化先浮选方案,获得了铅、锌、硫三种精矿产品,选矿指标较为理想。合理的利用了井下酸性水,降低了选矿成本和对环境的污染。 相似文献
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The main disadvantage of the Claus process is that by introducing air as oxidant a large volume of tail gas is produced. This must be treated to reduce atmospheric emissions of sulfur-containing gases. The costs of the tail-gas unit are a significant fraction of the total capital and operating costs for sulfur recovery. A new process uses thermal decomposition of hydrogen sulfide in the presence of carbon dioxide instead of air oxidation. The products of this reaction are hydrogen, carbon monoxide, elemental sulfur, water vapor and carbonyl sulfide. Carbonyl sulfide is easily converted to H2S and C02 by liquid- or vapor-phase hydrolysis. Unreacted H2S and C02 are recovered by absorption and recycled to the reactor. Since no air is introduced, there is no tail gas and the tail-gas unit is eliminated, giving a substantial reduction in capital investment. The concentrations of sulfur-containing gases in the product streams depend only on the operation of the absorber and stripper units and can be controlled to very low levels by increasing stripper boil-up. Process operating costs depend on the level of sulfur recovery required and can also be much lower than those of the modified Claus Process.
The process chemistry depends on a shift in the equilibrium of H2S decomposition caused by reaction of hydrogen with C02 by the reverse of the water-gas-shift reaction. Catalysts for this chemistry have been identified. Reactor conversion is further improved by rapid cooling of the reactor effluent gas. Other aspects of process design and operation confer further advantages with respect to the Claus process; however, the process equipment used is similar to that used in a Claus plant. Retrofit of existing plant to the new technology can therefore be considered. 相似文献
The process chemistry depends on a shift in the equilibrium of H2S decomposition caused by reaction of hydrogen with C02 by the reverse of the water-gas-shift reaction. Catalysts for this chemistry have been identified. Reactor conversion is further improved by rapid cooling of the reactor effluent gas. Other aspects of process design and operation confer further advantages with respect to the Claus process; however, the process equipment used is similar to that used in a Claus plant. Retrofit of existing plant to the new technology can therefore be considered. 相似文献
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采用苯乙烯膦酸与脂肪醇组成的复合捕收剂浮选金红石矿取得了较好效果,通过改进的Hallimond管浮选试验、吸附量测定试验、捕收剂溶液表面张力和金红石表面接触角的测量以及X射线光电子能谱测试(XPS),详细研究了复合捕收剂的协同作用机理。试验结果表明:苯乙烯膦酸在金红石表面发生了化学吸附,脂肪醇与苯乙烯膦酸相互联结,其疏水基指向水相,从而增强了金红石表面的疏水性,提高浮选结果。 相似文献