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181.
Hrudananda Jena K. V. Govindan Kutty T. R. N. Kutty 《Journal of Alloys and Compounds》2003,350(1-2):102-112
Structural transformation and ionic transport properties are investigated on wet-chemically synthesized La1−xMnO3 (x=0.0–0.18) compositions. Powders annealed in oxygen/air at 1000–1080 K exhibit cubic symmetry and transform to rhombohedral on annealing at 1173–1573 K in air/oxygen. Annealing above 1773 K in air or in argon/helium at 1473 K stabilized distorted rhombohedral or orthorhombic symmetry. Structural transformations are confirmed from XRD and TEM studies. The total conductivity of sintered disks, measured by four-probe technique, ranges from 5 S cm−1 at 298 K to 105 S cm−1 at 1273 K. The ionic conductivity measured by blocking electrode technique ranges from 1.0×10−6 S cm−1 at 700 K to 2.0×10−3 S cm−1 at 1273 K. The ionic transference number of these compositions ranges from 3.0×10−5 to 5.0×10−5 at 1273 K. The activation energy deduced from experimental data for ionic conduction and ionic migration is 1.03–1.10 and 0.80–1.00 eV, respectively. The activation energy of formation, association and migration of vacancies ranges from 1.07 to 1.44 eV. 相似文献
182.
通过对两个工程实例的冷水机组测试结果对比分析,得出污垢对冷水机组造成了热阻增加,接热效果变差,制冷量减少以及制冷效率下降等严重后果,并推算出机组由此所带来的运行费用的增加。运行管理人员应该注意对机组加强清洗保养工作,以提高机组的经济运行水平。 相似文献
183.
本文对ST-102C式NaI(Tl)晶体中碘原子K层X射线的五种主要成分K_(α1)、K_(α2)、K_(β1)、K_(β2)和 K_(β3)的逃逸率分别进行了计算,然后根据五种 X 射线的相对强度进一步计算了加权平均逃逸率。计算中所选用的初始入射 X 射线能量在33.5—1000keV 之间。 相似文献
184.
Kazufumi Ogawa 《Polymer International》1992,28(1):25-33
Studies have been carried out on KrF excimer laser light (EX), X-ray or electron beam (EB) induced polymerization of 10,12-pentacosadiynoic acid (PDA) Langmuir-Blodgett (LB) films in relation to molecular density or molecular arrangement of the films using X-ray diffraction analysis, infrared (IR) spectroscopy and Raman spectroscopy. The molecular arrangement or density of the PDA LB films was controlled by subphase conditions when the films were built up, such as pH, temperature of a subphase or salt concentration in the subphase. Polymerization sensitivity of the PDA LB film was affected by the arrangement or molecular density. On low density (A type) films the polymerization occurred by irradiation with EX, X-ray or EB, but on high density (B type) films the polymerization occurred only when the irradiation was carried out by high energy beams such as X-ray or EB. Decomposition of polymerized films was observed further by excessive irradiation of EX or X-ray, but not on the B type films. It was revealed by X-ray diffraction analysis that in the A type film, the PDA molecules bent to a larger extent than those in the B type film and the polymerization proceeded topochemically, that is, the thickness decreased little after EB irradiation in a helium atmosphere. On the other hand, in the B type film, the thickness decreased by about 10% as a result of EB irradiation. By IR reflection-absorption (RA) and Raman measurements, it was confirmed that conjugated diacetylenic bonds disappeared and conjugated double and new conjugated triple bonds appeared after high energy beam irradiations. These results support the supposition that 1,4-polymerization, i.e. polydiacetylene type polymerization, occurs easily in the A type film and 1,2- or 3,4-polymerization, i.e. polyacetylene type polymerization, occurs in the B type film, and that the polymerized A type film was decomposed at the polydiacetylenic bond when the irradiation continued further. It was also shown that the polyacetylene type polymer was obtained only when the B type film was irradiated with the high energy beam. 相似文献
185.
Necessity of XPS spectrum,deconvolution,disadvantages of the traditional Fast Fourier Tranderm decon-volution method(FFT),princtple,method and advantage ofMaximum Entropy Deconvolution Method (MEM) are de-scribed.Criteria for determing the number of data points sam-pled in MEM are the main point disccussed in the paper,someXPS deconvolution applications of our MEM software showthat the MEM makes XPS deconvolution much easier than thetraditional FFT method. 相似文献
186.
The ALCHEMI method for locating the sites of foreign atoms within crystals is known to be sensitive to the delocalized emission of X-rays. This can result in large errors in some cases through differences in delocalization for different excitations or by error amplification in the ratio method of analysis. An alternative approach to the analysis of ALCHEMI data, using multivariate statistical analysis, is extended to the case of multiple impurities. Initial results from zone-axis channelling experiments for a Yb-doped zirconolite (CaZrTi2O7) are shown to confirm the improved accuracy of this method, especially for axial orientations. Data were collected using a 400-keV analytical electron microscope fitted with an intrinsic Ge X-ray detector. The potential advantages for ALCHEMI analysis of Ge detectors are considered. 相似文献
187.
本文报道用不同离子两步交换技术,在玻璃衬底上制作K~+离子交换掩埋波导的新工艺,它不要求施加外电场。用X射线能谱(XES)分析技术测试了K~+离子的浓度分布,证明所制出的样品是掩埋波导。 相似文献
188.
LIGA工艺的发展及应用 总被引:5,自引:1,他引:4
介绍了LIGA(lithographie,galvanoformungandabformung)技术以及在此基础上开发出来的准LIGA(like-LIGA)技术、SLIGA(sacrificialLIGA)、M2LIGA(movingmaskLIGA)技术和抗蚀剂回流LIGA(PRLIGA———photoresistreflowLIGA)技术等。利用这一系列LIGA技术,可以生成具有高深宽比的复杂微结构,如微尖阵列、球形曲面、活动部件等,能较好地满足MEMS发展的需要。最后指出了目前这些方法存在的缺陷。 相似文献
189.
The kinetics of the carbothermal reduction of clay under argon atmosphere has been investigated by the X-ray diffraction method. The clay-carbon (excess) mixture was formed into 2 cm diameter disks of different thicknesses. Experimental data evidences the significant effect of sample thickness on the reaction rate at 1400 °C. Decreasing thickness promotes mullite dissociation and formation of SiC and alumina powders. Mathematical modeling of the reaction system showed the gas diffusion in the Knudsen regime through the pellet to be the rate controlling step. Diffusivity of CO and reacted core tortuosity factor have been calculated. 相似文献
190.