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51.
采用溶胶-凝胶法制备了系列AlPO4-Al2O3催化剂,利用XRD、TG-DTA、NH3-TPD和催化剂评价等方法,研究了制备条件对催化剂结构和缩醛化反应催化性能的影响,结果表明,Al2O3的存在不仅能提高AlPO4的热稳定性,而且可以调节催化剂的表面酸性性能。在适宜的缩醛化反应条件下,400 ℃焙烧和Al2O3质量分数为15%的AlPO4-Al2O3催化剂样品具有较好的催化活性,1,2-丙二醇转化率达28.1%,AlPO4-Al2O3催化剂的缩醛化反应活性与表面弱酸中心的酸量成顺变关系。 相似文献
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Xinli ZHU Kailu YU Dangguo CHENG Yueping ZHANG Qing XIA Changjun LIU 《Frontiers of Chemical Engineering in China》2008,2(1):55-58
The NH3-TPD characterization was conducted to confirm that the acidity of Mo-Fe/HZSM-5 zeolite could be selectively modified via
the glow discharge plasma treatment. The plasma catalyst treatment could totally change the distribution of aromatic products
with higher methane conversion compared to the untreated catalyst. Some polycyclic aromatics such as anthracene, pyrene and
phenanthrene were also produced over the plasma treated catalyst, in addition to benzene, toluene and naphthalene, which were
normally obtained over the untreated catalyst. 相似文献
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Application of ATR-FTIR for a rapid and simultaneous determination of sugars and organic acids in apricot fruit 总被引:1,自引:0,他引:1
Sylvie Bureau David Ruiz Maryse Reich Barbara Gouble Dominique Bertrand Jean-Marc Audergon Catherine M.G.C. Renard 《Food chemistry》2009
A simple, fast and accurate Fourier transform mid-infrared spectroscopy method was developed for simultaneously determining sugar and organic acid contents in apricot fruit slurries using the attenuated total reflectance. The potential of this method coupled with chemometric techniques based on partial least squares was assessed by comparison with currently used enzymatic determination of sucrose, glucose, fructose, malic acid and citric acid. Fruits of eight contrasted cultivars harvested at different ripening stages were used in this study and randomly divided in a calibration set (505 apricots) and in a validation set (252 apricots). The most suitable region was found in the range between 1500 and 900 cm−1. Good prediction performances were obtained (R2 ? 0.74 and RMSEP ? 18%). Results concerning the prediction of other quality traits such as firmness, skin colour, ethylene production, soluble solids content and titratable acidity were discussed. 相似文献
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Sylvie Bureau David Ruiz Maryse Reich Barbara Gouble Dominique Bertrand Jean-Marc Audergon Catherine M.G.C. Renard 《Food chemistry》2009
A non-destructive optical method based on near-infrared spectroscopy has been used for the evaluation of apricot fruit quality. Diffuse reflectance measurements (800–2500 nm), physical, physiological and biochemical measurements were performed individually on 877 apricot fruits from eight contrasted cultivars harvested at different ripening stages. Relationships between spectral wavelengths and quality attributes were evaluated by application of chemometric techniques based on partial least squares (PLS) on fruit set divided randomly into two groups: 598 fruits for calibration and 279 for validation. Good prediction performance was obtained for soluble solids and titratable acidity with correlation coefficients of 0.92 and 0.89 respectively and root mean square errors of prediction of 0.98% Brix and 3.62 meq 100 g−1 FW respectively. For the other quality traits such as firmness, ethylene, individual sugars and organic acids, the prediction models were not satisfactorily accurate due to the high error of calibration and prediction. 相似文献
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Tadashi Yoshihashi Nguyen Thi Thu Huong Vipa Surojanametakul Patcharee Tungtrakul Warunee Varanyanond 《Journal of food science》2005,70(1):S34-S37
ABSTRACT: The effect of package and temperature on 2–acetyl-1–pyrroline content in milled aromatic rice during storage was investigated. 2 -Acetyl-1 -pyrroline content was decreased faster at higher storage temperature. However, fat acidity of rice was increased during storage and inversely correlated with 2–acetyl-1–pyrroline content at an early stage of storage. The difference in 2–acetyl-1 -pyrroline recovery from the samples, which were extracted with ethanol at 40 °C and 75 °C, revealed that the starch bound and free forms of 2–acetyl-1–pyrroline may occur in aromatic rice. These results suggested that the biosynthesis of 2–acetyl-1 -pyrroline before starch structure formation in rice kernel could play a key role in the aroma quality of aromatic rice. 相似文献
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