在UO_2(NO_3)_2-TBP-CCI_4有机相中光化还原制备铀(Ⅳ)的研究

本文的目的是研究在TBP有机相中光化还原铀(Ⅵ)以制备铀(Ⅳ)。选用了高压汞灯作为激发光源,CCl_4为TBP的稀释剂。研究了反应温度、原始水相溶液组成等因素对铀(Ⅳ)产额和亚硝酸生成量的影响。推荐了制备铀(Ⅳ)的适宜条件。     

硝酸铀酰光化还原的研究

本文的目的是探讨光化还原制备硝酸钠(Ⅳ)。研制了一个与硝酸钠酰的吸收光谱匹配较好的金属卤化物灯——镓灯作为激发光源,在不另加滤光器的条件下,对几种还原剂的还原能力作了比较,并对乙醇作还原剂时,硝酸浓度、乙醇浓度、初始铀酰离子浓度以及温度等因素对光化还原铀(Ⅵ)到铀(Ⅳ)的还原率的影响进行了研究。     

循环流化床风室的压力脉动特性分析

针对直径为0.205m,高度为7m的冷态高密度循环流化床(CFB)试验台,在表观气速为6.3m/s的条件下,借助小波理论对不同循环流率、不同出口结构的压力脉动特性进行了分析。结果表明:不管是高密度条件下还是低密度条件下的压力脉动,均属于低频脉动,脉动幅度为0~12.5Hz;在相同的出口结构和同一表观气速下,随着循环流率的增加,风室的压力增加,压力脉动的幅度也增加;在同一表观气速和相同循环流率下,Г型突变出口结构的风室压力和压力脉动幅度的增长速率均比C型光滑出口结构的大。     

一种主变压器特殊运行方式的参数计算及应用

运城500kV变电站主变升压改造期间,两组主变需要在分接开关参数不一致的情况下并列运行,对这种特殊运行方式下两组主变并列运行的匹配分头进行了选择,对其引起的环流进行了计算分析,并就两组主变特殊运行方式过渡期可能遇到的负荷分配及控制等问题进行了探讨,为确保运城站主变在升压改造期间的安全稳定运行提供了决策依据,所述方法已在运城站升压改造过程中得到验证并取得了良好效果。     

浅谈铝合金板带退火炉节能降耗

主要从生产组织、工艺优化、余热利用等六个方面介绍了铝及铝合金退火炉节能降耗的方法和措施.     

Slicing Software for Model Construction

Applying finite-state verification techniques (e.g., model checking) to software requires that program source code be translated to a finite-state transition system that safely models program behavior. Automatically checking such a transition system for a correctness property is typically very costly, thus it is necessary to reduce the size of the transition system as much as possible. In fact, it is often the case that much of a program's source code is irrelevant for verifying a given correctness property.In this paper, we apply program slicing techniques to remove automatically such irrelevant code and thus reduce the size of the corresponding transition system models. We give a simple extension of the classical slicing definition, and prove its safety with respect to model checking of linear temporal logic (LTL) formulae. We discuss how this slicing strategy fits into a general methodology for deriving effective software models using abstraction-based program specialization.     

基于多体动力学的汽轮机振动声辐射机理及传递路径

采用多体动力学方法进行汽轮机机械振动激励源精确分析,在激励源分析结果的基础上研究低频激励下的机组振动响应,并采用声传递向量（Acoustic Transfer Vector,ATV）方法研究汽轮机组表面与外场辐射的声压传递贡献量,从多体动力学的角度并结合流固耦合的方法综合分析汽轮机组振动噪声产生机理并研究噪声典型传递路径。研究结果表明,旋转激励源为汽轮机组的主要振动激励源,在低频段汽轮机组辐射模式为单极子,在中高频段汽轮机组辐射模式为偶极子。由噪声辐射的指向性极坐标图可知,在不同高度处噪声指向性相似,并都在长度方向上取得噪声声压级较大值,具有较强的指向性。计算方法对汽轮机组减振降噪研究具有一定的指导意义。     

Lithium Intercalation Compound Dramatically Influences the Electrochemical Properties of Exfoliated MoS2

MoS₂ and other transition metal dichalcogenides (TMDs) have recently gained a renewed interest due to the interesting electronic, catalytic, and mechanical properties which they possess when down‐sized to single or few layer sheets. Exfoliation of the bulk multilayer structure can be achieved by a preliminary chemical Li intercalation followed by the exfoliation due to the reaction of Li with water. Organolithium compounds are generally adopted for the Li intercalation with n‐butyllithium (n‐Bu‐Li) being the most common. Here, the use of three different organolithium compounds are investigated and compared, i.e., methyllithium (Me‐Li), n‐butyllithium (n‐Bu‐Li) and tert‐butyllithium (t‐Bu‐Li), used for the exfoliation of bulk MoS₂. Scanning transmission electron microscopy (STEM), Raman spectroscopy, X‐ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV) are adopted for a comprehensive characterization of all materials under investigation. In addition, catalytic properties towards the hydrogen evolution reaction (HER) and capacitive properties are also tested. Different organolithium compounds exhibit different extent of Li intercalation resulting in different degrees of exfoliation. The inherent electrochemical behavior of MoS₂ consisting of significant anodic and cathodic peaks as well as its capacitive behavior and catalytic properties towards hydrogen evolution reaction are strongly connected to the exfoliation compound used. This research significantly contributes to the development of large‐scale synthesis of electrocatalytic MoS₂‐based materials.     

2－氨基－4－氯苯酚的合成研究

提出了以对二氯苯为原料，经硝化，水解和还原三步合成２－氨基－４－氯苯酚的讨了影响反应的因素。产品总收率达７７％。     

Myoglobin/gold nanoparticles/carbon spheres 3-D architecture for the fabrication of a novel biosensor

A novel biosensor based on a myoglobin/gold nanoparticles/carbon spheres (Mb-AuNPs-CNs) 3-D architecture bioconjunction has been fabricated for the determination of hydrogen peroxide (H₂O₂). Cyclic voltammetry (CV), Fourier transform infrared (FT-IR) spectroscopy and scanning electron microscopy (SEM) were used to characterize the bioconjunction of the AuNPs-CNs with Mb. Experimental results demonstrate that the AuNPs-CNs hybrid material is more effective in facilitating electron transfer of the immobilized enzyme than CNs alone, which can be attributed to the unique nanostructure and larger surface area of the bioconjunction. The biosensor displayed good performance for the detection of H₂O₂ with a wide linear range from 0.28 μmol/L to 116.5 μmol/L and a detection limit of 0.12 μmol/L. The Michaelis-Menten constant K _M^app value was estimated to be 0.3 mmol/L. The resulting biosensor exhibited fast amperometric response, and good stability, reproducibility, and selectivity to H₂O₂. This article is published with open access at Springerlink.com