45钢/W8Co3N高速钢刀具的摩擦焊接研究

对 45钢 /W8Co3N高速钢刀具的摩擦焊接工艺及焊接效果进行了试验研究 ,结果表明 ,采用优化的摩擦焊接工艺参数及合理的焊后热处理工艺可获得具有良好显微组织和力学性能的焊接接头。     

Studies of glycolysis of poly(ethylene terephthalate) recycled from postconsumer soft‐drink bottles. I. Influences of glycolysis conditions

The glycolysis of recycled poly(ethylene terephthalate) flakes by ethylene glycol (EG) is investigated. Bis‐2‐hydroxyethyl terephthalate (BHET) and oligomers are predominately glycolysis products. The influences of glycolysis temperature, glycolysis time, and the amount of catalyst (cobalt acetate) are illustrated. The BHET, dimer, and oligomers are predominately glycolysis products. The optimum glycolysis temperature is found to be 190°C. If a 190°C glycolysis temperature, 1.5‐h glycolysis time, and 0.002 mol glycolysis catalyst (cobalt acetate) are used, the glycolysis conversion is almost 100%. The glycolysis conversion rate increases significantly with the glycolysis temperature, glycolysis time, and the amount of cobalt acetate. Thermal analyses of glycolysis products are examined by differential scanning calorimetry. In addition, the chemical structures of glycolysis products are also determined by a Fourier transform IR spectrophotometer. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 80: 943–948, 2001     

Electrochemical studies of the nickel electrode with cobalt modification

The electrochemical behaviour of the paste-type nickel hydroxide electrode with cobalt-modified nickel foam was investigated using galvanostatic charge–discharge, electrochemical impedance spectroscopy, cyclic voltammetry and current pulse relaxation methods. Experimental results showed that the performance of the nickel electrode with substrate deposition of a thin layer of cobalt was improved markedly. This improvement could be attributed to the enhanced electrical conduction between the substrate and the active material. The enhanced electrical conduction increases the charge efficiency and the discharge depth of the nickel electrodes and therefore increases the utilization of the active material. This suggests that the electrical conduction between the substrate and the active material is essential to the practical use of paste-type nickel hydroxide electrodes.     

Tin–cobalt electrodeposition from sulfate–gluconate baths

The electrodeposition of tin + cobalt alloys from a slightly acidic sulfate–gluconate bath on both vitreous carbon and copper substrates has been studied for different [Sn(II)]/[Co(II)] ratios in the bath, varying between 1/10 and 1/2. A relationship between the electrochemical stripping analysis and the morphology of the deposits has been found. Two different types of deposit were obtained. At low [Sn(II)]/[Co(II)] ratios and relatively high deposition rates a nodular, cobalt-rich, nanocrystalline coating was obtained, while at high [Sn(II)]/[Co(II)] ratios and low deposition rates a new, well-defined tetragonal SnCo phase was obtained, with cell parameters of a = 3.087 Å and c = 5.849 Å. This structure favours hydrogen evolution.     

江西某地钴银矿冶金试验研究

以某低品位钴银矿浮选精矿为原料,在湿法提取冶金过程中先将砷固留在焙砂中,然后采用适宜的脱砷剂将其从浸出液中除去。用硫化法净化浸出液中的重金属离子,用萃取法分离镍、钴,最后用合格的含钴溶液帛取草酸钴产品。而银存留于浸出渣中待回收。     

A Mechanistic Study of Low Temperature CO Oxidation over Cobalt Oxide

The CO oxidation over Co₃O₄ and Co₃O₄/Al₂O₃ has been investigated using flow reactor and in situ FTIR studies. Cobalt oxide shows very high activity even at room temperature. However, a gradual deactivation takes place during reaction. The deactivated catalyst shows the presence of two different carbonate species and one graphite-like species. A possible mechanism for the deactivation is discussed.     

准噶尔盆地基底构造与地壳分层结构

基于4 条盆地转换波剖面、1 条人工地震深反射-折射剖面和重磁反演以及相关深部探测结果,将准噶尔盆地地壳结构划分为3 个构造层,即沉积盖层、古生界褶皱基底层和结晶地壳层,确定了B、G、C₁（或G₁）、C 和M 界面及其参数特征。盆地具褶皱基底与结晶基底的“双层基底”构造特征,为陆壳性质。现今总体表现为东侧、北侧和西侧埋深较浅,盆地中部由北往南呈倾斜加深;褶皱基底北厚南薄,三个泉凸起带以北厚度为4~10 km,以南为0~4 km,昌吉凹陷一带最薄,为0~1 km. 盆地的莫霍面存在卡拉麦里-乌伦古北西西向上地幔隆起区、卡拉麦里-帐北和加依尔-四棵树南北向上地幔隆起区以及由此分割的凹陷区和斜坡带。     

开发醋酸锰产品的技术经济评估

简要介绍了醋酸锰产品的性质与用途,分析了醋酸锰在PTA生产中的使用状况及未来前景;重点阐述了以PTA副产品中回收的钴锰混合物为原料,进一步开发生产醋酸锰催化剂的工艺技术路线;并从装置投资、生产成本及预期获利等方面,对醋酸锰项目建成后的经济效益进行了筒要评估。     

热处理气氛及掺钴对NiO电极赝电容器性能的影响

在讨论赝电容形成机理的基础上,应用电化学阴极沉积法在Ni基片上制得Ni(OH)2膜,经热处理得到NiO膜。研究发现,Ni(OH)2在空气中热处理所得NiO在KOH水溶液中能形成赝电容,但在N2气氛中热处理所得的NiO在KOH水溶液中未能形成赝电容;钴掺入NiO使比电容量显著增大。     

高钴硫酸锌溶液中钴的分离研究

主要研究了湿法炼锌过程中高钴硫酸锌溶液中的β－萘酚化学沉淀法净化分离,以亚硝酸钠为氧化剂,反应体系中生成的α－亚硝基－β－萘酚为沉钴剂,系统地讨论了钴的分离条件。研究结果表明,β－萘酚除钴法用于高钴硫酸锌溶液中钴的分离,具有除钴效率高,选择性好,工艺条件易于控制等优点。