锂电池用6μm电解铜箔添加剂的研究

采用正交试验法研究了羟乙基纤维素(HEC)、硫脲(N)、聚乙二醇(P6000)和N,N-二甲基二硫代甲酰胺丙烷磺酸钠(DPS)这四种添加剂对6μm电解铜箔性能的影响。最佳的添加剂配方为:HEC 1.0 mg/L,P6000 2.0 mg/L,N 0.05 mg/L,DPS 2.0 mg/L。     

细长铜管内壁化学流镀镍-磷合金工艺的研究

介绍了细长铜管内壁化学流镀镍-磷合金工艺。探讨了铜及其合金化学镀镍触发时间的影响因素。研究了铜管内壁溶液流速与沉积速率的关系。     

含铜和镍电镀污泥还原氨浸工艺及反应动力学分析

采用还原氨浸工艺实现电镀污泥中铜、镍的浸出。在20%(质量分数)氨水+0.3 mol/L (NH₄)₂CO₃+0.4 mol/L Na₂SO₃的浸出体系中,当固液比为1∶15,在70℃下浸出3h,铜、镍的浸出率别为95.84%和90.12%。反应动力学分析表明,氨-碳酸铵-亚硫酸钠体系浸出电镀污泥中铜、镍受界面传质和固体膜层扩散共同控制。     

铜氧化物超导体正常态禁带宽度的计算

介绍了1种近似计算氧化物禁带宽度的方法,并对高温超导铜氧化物进行了计算。结果表明,铜氧化物超导体的禁宽度E_g值大多集中在8.50~8.80eV之间。在同一体系的超导氧化物中,Cu-O层结构的变化,产生的结果是T_C随E_g的增加而减小,而在YBa₂Cu₃O_y中氧含量的变化导致T_C随E_g的增加而增加。超导体中正常态的E_g值与超导电性可能存在着相关关系。氧化物中平均电离能是决定其能隙E_g值的主要因素。     

斜轧磷铜球轧制力研究

为提高磷铜球单机生产率,获取磷铜球轧制的力能参数,为轧机设计提供依据,进行了磷铜球双头孔型设计及单双头轧制实验.实验中对不同转速下单双头斜轧磷铜球轧制压力进行了测试,将测得的结果进行分析,得出双头斜轧φ19 mm磷铜球的轧制力比单头斜轧φ28 mm小.实验采用计算机测试技术,取得了比较满意的实验结果.     

Enhanced Air Stability and Li Metal Compatibility of Li-Argyrodite Electrolytes Triggered by In2O3 Co-Doping for All-Solid-State Li Metal Batteries

Sulfide solid electrolytes (SSEs) have become an ideal candidate material for all-solid-state Li metal batteries (ASSLMBs) because of their high ionic conductivity. However, the vile Li incompatibility and poor air stability of SSEs barriers their commercial application. Herein, novel Li_6+2xP_1−xIn_xS_5−1.5xO_1.5xCl (0 ≤ x ≤ 0.1) SSEs are synthesized via In and O co-doped Li₆PS₅Cl. By regulating the substitution concentration, the prepared Li_6.12P_0.92In_0.08S_4.88O_0.12Cl exhibits considerable ionic conductivity (2.67 × 10⁻³ S cm⁻¹) and enhanced air stability. Based on the first-principles density functional theory (DFT) calculation, it is predicted that In³⁺ replaces P⁵⁺ to form InS₄⁵⁻ tetrahedron and O²⁻ replaces S²⁻ to form PS₃O⁴⁻ group. The mechanism of enhancing air stability by In, O co-substituting Li₆PS₅Cl is clarified. More remarkably, the formation of Li-In alloys induced by Li_6.16P_0.92In_0.08S_4.88O_0.12Cl electrolyte at the anode interface is beneficial to reducing the migration barrier of Li-ions, promoting their remote migration, and enhancing the stability of the Li/SSEs interface. The optimized electrolyte shows superior critical current density (1.4 mA cm⁻²) and satisfactory Li dendrite inhibition (stable cycle at 0.1 mA cm⁻² over 3000 h). The ASSLMBs with Li_6.16P_0.92In_0.08S_4.88O_0.12Cl electrolyte reveal considerable cycle stability. This work emphasizes In, O co-doping to address redox issues of sulfide electrolytes.     

Operando Reconstruction of Porous Carbon Supported Copper Selenide Promotes the C2 Production from CO2RR

Precisely regulating surface reconstruction of copper (Cu) chalcogenides-based catalysts to promote the multicarbon (C₂₊)selectivity of the electrochemical CO₂ reduction reaction (CO₂RR) is hampered by the challenging control of the intractable anions and the optimal Cu^δ+ reduction (0 < δ < 1). Herein, a porous carbon-supported copper selenides electrocatalyst that can remarkably improve the C₂-product yield and especially unveil the time-revolved electrochemical CO₂RR reconstruction process to enable the high C₂-selectivity, most notably for ethanol is constructed. The Faradic efficiency (FE) of C₂-products achieved is as high as ≈85.2% with a partial current density of 229.5 mA cm⁻². Operando infrared spectroscopy and density functional theory (DFT) calculations unravel that the surface Se vacancies (V_Se) formation brings closer the neighboring Cu⁺ atoms and activates the Cu sites, thereby rendering efficient generation of the key intermediates (^*CO and ^*CHO) and lowering the C–C coupling barrier for C₂ production. The appearance of metallic Cu can shorten the next-nearest Cu⁰–Cu⁺ distance for O atom to bridge in, leading to the preferential formation of ^*OC₂H₄ towards ethanol instead of C–O bond cleavage to form ethylene. This work opens the avenue of designing suitable local atomic structures catalysts to engage the intermediates for targeted CO₂RR products.     

钙处理H13钢中夹杂物的转变

利用真空感应炉和扫描电镜等设备, 实验研究了钙处理对H13模具钢中夹杂物的影响, 并对钢中夹杂物的转变进行了热力学计算, 讨论了钙处理对夹杂物成分和结构的影响.结果表明:钙处理H13钢后, 夹杂物尺寸减小, 圆形度提高, 夹杂物面积比降低;夹杂物由钙处理前的Si O₂-Al₂O₃系夹杂物转变为Ca O-Si O₂-Al₂O₃- (MgO) 系夹杂物, 钢中Ca质量分数达到12×10^-6时, 夹杂物完全处于Ca O-Si O₂-Al₂O₃- (MgO) 相图的1400℃低熔点区以内;钢中高的T.O含量使Ca S不会在钙处理后形成, 钢中Ca/T.O的质量分数比达到0.3时, 复合夹杂物中的Al₂O₃将会完全消除; (Mn, Cr) S夹杂依附氧化物夹杂析出, Mn、Cr和S的偏析程度决定了复合氧硫化物夹杂的形貌.     

酸铜染料型光亮剂的优缺点

目前光亮硫酸盐镀铜生产中,国产的MN型光亮剂与进口复配的染料型光亮剂并行使用,这2种类型光亮剂各有优缺点。染料型光亮剂能在宽电流密度范围内获得均匀的光亮整平镀层外观,更适用于复杂件电镀,镀液调整较为简单。由于染料的盐析与聚沉,镀层易起麻砂。MN型光亮剂在高中电流密度区光亮整平性优于染料型,而且允许液温较低。笔者正在开发的一种染料型光亮剂,多项性能均有所提高,操作液温上下限拓宽至9~35°C,达到全镜面光亮。