全文获取类型
收费全文 | 16059篇 |
免费 | 2154篇 |
国内免费 | 617篇 |
专业分类
电工技术 | 424篇 |
综合类 | 948篇 |
化学工业 | 4543篇 |
金属工艺 | 2074篇 |
机械仪表 | 377篇 |
建筑科学 | 380篇 |
矿业工程 | 2049篇 |
能源动力 | 383篇 |
轻工业 | 503篇 |
水利工程 | 34篇 |
石油天然气 | 783篇 |
武器工业 | 88篇 |
无线电 | 886篇 |
一般工业技术 | 1824篇 |
冶金工业 | 3353篇 |
原子能技术 | 69篇 |
自动化技术 | 112篇 |
出版年
2024年 | 68篇 |
2023年 | 267篇 |
2022年 | 507篇 |
2021年 | 632篇 |
2020年 | 654篇 |
2019年 | 465篇 |
2018年 | 469篇 |
2017年 | 565篇 |
2016年 | 608篇 |
2015年 | 699篇 |
2014年 | 935篇 |
2013年 | 1018篇 |
2012年 | 1186篇 |
2011年 | 1119篇 |
2010年 | 849篇 |
2009年 | 852篇 |
2008年 | 684篇 |
2007年 | 939篇 |
2006年 | 887篇 |
2005年 | 819篇 |
2004年 | 718篇 |
2003年 | 629篇 |
2002年 | 558篇 |
2001年 | 468篇 |
2000年 | 427篇 |
1999年 | 332篇 |
1998年 | 276篇 |
1997年 | 221篇 |
1996年 | 183篇 |
1995年 | 122篇 |
1994年 | 127篇 |
1993年 | 88篇 |
1992年 | 104篇 |
1991年 | 83篇 |
1990年 | 57篇 |
1989年 | 42篇 |
1988年 | 26篇 |
1987年 | 25篇 |
1986年 | 23篇 |
1985年 | 13篇 |
1984年 | 20篇 |
1983年 | 9篇 |
1982年 | 12篇 |
1981年 | 14篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1977年 | 5篇 |
1974年 | 3篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
52.
The chemical composition, defect structure, and diffusion in nickel sulfide -Ni3S2 have been investigated in H2S-H2 mixtures containing between 1 and 65% H2S between 560 and 700°C. Gravimetric, density, and X-ray studies were carried out. In the thermodynamically stable compound the ratio of Ni/S varied between 1.3 and 1.75. The X-ray examination showed a step change in the lattice parameter at the Ni/S ratio 1.4. A linear dependence of the density values (between 5.5 and 6.2 g/cm3) on the composition was observed. On the basis of the chemical composition and density measurements the number of nickel and sulfur atoms in 1 cm3 were determined. It has been shown that the Ni3S2 phase is defected in both anion and cation sublattices and that its chemical formula may be described as follows: Ni3±yS2x, where y 2x. It has been found that in the mixture containing 10% H2S the process of defect formation is determined by their diffusion in the sulfide. The temperature dependence of the diffusion coefficient is described by the equation D = 13.15 exp(-30,000/RT) cm2/sec. No dependence of D on the sulfur partial pressure was observed, but this may be due to the relatively large uncertainties in the measurement of the diffusion coefficients. 相似文献
53.
1 INTRODUCTIONTheoxidationofunalloyedcopperandnickelhasalreadybeenstudiedindetail.Whilethehigh tem peratureoxidationofCu Nialloys ,alsostudiedanumberoftimestodate[13] ,isanexampleofarela tivelysimpleclassofscalingofbinaryalloysbyasin gleoxidant,becausethemetalsformacontinuousse riesofsolidsolutions ,whiletheiroxides ,CuO ,Cu2 OandNiO ,exhibitsmallmutualsolubilitiesandshowsignificantdifferencesinthethermodynamicstabilityandparabolicgrowthrates .Thus ,copper richalloysformexternalscales… 相似文献
54.
G. Pantazopoulos 《Journal of Materials Engineering and Performance》2002,11(4):402-407
C 38500 is a widely used copper alloy with a great variety of applications from decoration and architecture to mechanical/electrical
engineering. The chemical composition of this alloy offers superior machinability and subsequently increased productivity
in high-speed machining and manufacturing processes. In European countries, this alloy is used primarily as free cutting brass
(CW 614N according to EN 12164: 1998), similar to C 36000 alloy, which is used also for thread rolling. The lower percentage
of Cu compared to C 36000 (nominal 58% instead of 61%) decreases the cost of the raw materials. This paper reports the principal
aspects of microstructure, mechanical properties, and machinability of this alloy in relation to the industrial manufacturing
process used. 相似文献
55.
将瞬变电磁法(Transient Electromagnetic Method,TEM)应用到布敦花铜矿矿区的解释中,首先需建立电磁感应模型,对瞬变电磁场中的二次磁场频率、时间特性进行分析,通过MATLAB软件进行程序编写,得出相应的特性曲线图。然后分别计算早、晚期视电阻率和全程视电阻率,得出瞬变电磁场在矿区变化时的视电阻率参数变化,得出相应的数据结论。最后,利用MATLAB的网格化函数,对数据进行处理,模拟出瞬变电磁场在铜区时的异常场变化,完成对矿区的解释。从结果分析可以看出,利用瞬变电磁法解释的结果比利用物探资料进行矿区解释的结果更简单、更精确。这样一来,既提高了工作效率,又提高了解释的准确率。 相似文献
56.
57.
Yuping Liu Jinli Yu Yongfeng Lun Yawen Wang Yi Wang Shuqin Song 《Advanced functional materials》2023,33(44):2304184
Metal nanoclusters (MNCs) are compositionally well-defined and also structurally precise materials with unique molecule-like properties and discrete electronic energy levels. Atomically precise ligand-protected Cu nanoclusters (LP-CuNCs) are one category of typical MNCs that usually demonstrate unique geometric and electronic structures to serve as electrocatalysts. However, the synthesis, application, as well as structure-performance relationship of LP-CuNCs are not adequately studied. Significantly, the ligands are essential to the geometric structure, crystal structure, size, and electronic structure of LP-CuNCs, which determine their physiochemical properties and applications. In this review, significant progress in the ligand design of LP-CuNCs, and their application in electrocatalytic reactions is introduced. The general basics of ligand-protected MNCs (LP-MNCs) are first introduced and the functions of ligands are emphasized. Subsequently, a series of different ligands for LP-CuNCs including thiolates, phosphines, alkynyl, polymers, and biomolecules are highlighted. Thereafter, their applications in different electrocatalytic reactions are discussed. It is believed that this review will not only inspire the design and synthesis of novel LP-CuNCs, but also contribute to the extension of their applications in electrocatalytic reactions and the establishment of accurate structure-performance relationships. 相似文献
58.
Pimpisut Worakajit Pinit Kidkhunthod Thanasee Thanasarnsurapong Saran Waiprasoet Hideki Nakajima Taweesak Sudyoadsuk Vinich Promarak Adisak Boonchun Pichaya Pattanasattayavong 《Advanced functional materials》2023,33(25):2209504
Solution-processed copper(I) thiocyanate (CuSCN) typically exhibits low crystallinity with short-range order; the defects result in a high density of trap states that limit the device's performance. Despite the extensive electronic applications of CuSCN, its defect properties are not understood in detail. Through X-ray absorption spectroscopy, pristine CuSCN prepared from the standard diethyl sulfide-based recipe is found to contain under-coordinated Cu atoms, pointing to the presence of SCN− vacancies. A defect passivation strategy is introduced by adding solid I2 to the processing solution. At small concentrations, the iodine is found to exist as I− which can substitute for the missing SCN− ligand, effectively healing the defective sites and restoring the coordination around Cu. Computational study results also verify this point. Applying I2-doped CuSCN as a p-channel in thin-film transistors shows that the hole mobility increases by more than five times at the optimal doping concentration of 0.5 mol.%. Importantly, the on/off current ratio and the subthreshold characteristics also improve as the I2 doping method leads to the defect-healing effect while avoiding the creation of detrimental impurity states. An analysis of the capacitance-voltage characteristics corroborates that the trap state density is reduced upon I2 addition. 相似文献
59.
Zhuoran Lv Baixin Peng Ximeng Lv Yusha Gao Keyan Hu Wujie Dong Gengfeng Zheng Fuqiang Huang 《Advanced functional materials》2023,33(16):2214370
Alloying-type metal sulfides with high theoretical capacities are promising anodes for sodium-ion batteries, but suffer from sluggish sodiation kinetics and huge volume expansion. Introducing intercalative motifs into alloying-type metal sulfides is an efficient strategy to solve the above issues. Herein, robust intercalative In S motifs are grafted to high-capacity layered Bi2S3 to form a cation-disordered (BiIn)2S3, synergistically realizing high-rate and large-capacity sodium storage. The In S motif with strong bonding serves as a space-confinement unit to buffer the volume expansion, maintaining superior structural stability. Moreover, the grafted high-metallicity Indium increases the bonding covalency of Bi S, realizing controllable reconstruction of Bi S bond during cycling to effectively prevent the migration and aggregation of atomic Bi. The novel (BiIn)2S3 anode delivers a high capacity of 537 mAh g−1 at 0.4 C and a superior high-rate stability of 247 mAh g−1 at 40 C over 10000 cycles. Further in situ and ex situ characterizations reveal the in-depth reaction mechanism and the breakage and formation of reversible Bi S bonds. The proposed space confinement and bonding covalency enhancement strategy via grafting intercalative motifs can be conducive to developing novel high-rate and large-capacity anodes. 相似文献
60.
Structure and Magnetic Property Control of Copper Hydroxide Acetate by Non‐Classical Crystallization 下载免费PDF全文
RuiQi Song Theodora Krasia‐Christoforou Christian Debus Helmut Cölfen 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(9)
Copper hydroxide acetate (CHA), one layered hydroxide compound with tunable magnetism, attracts great interest because of its potential applications in memory devices. However, ferromagnetism for CHA is only demonstrated by means of GPa pressure. Herein, a new method is reported, involving the combination of different crystallization pathways to control crystallization of amorphous CHA toward the formation of CHA/polymer composites with tunable magnetic properties and even a tunability that can be tested at room temperature. By using poly[(ethylene glycol)6 methyl ether methacrylate]‐block‐poly[2‐(acetoacetoxy) ethyl methacrylate] (PEGMA‐b‐PAEMA) diblock copolymers as additives in combination with a post‐treatment process by ultracentrifugation, it is demonstrated that CHA and PEGMA‐b‐PAEMA form composites exhibiting different magnetic properties, depending on CHA in‐plane nanostructures. Analytical characterization reveals that crystallization of CHA is induced by ultracentrifugation, during which CHA nanostructures can be well controlled by changing the degrees of polymerization of the PEGMA and PAEMA blocks and their block length ratios. These findings not only present the first example of using crystallization from polymer stabilized amorphous precursors toward the generation of magnetic nanomaterials with tunable magnetism but also pave the way for the future design of functional composite materials. 相似文献