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81.
To confirm the reliability of the theory of phase equibria of multicomponent polymer 1/multicomponent polymer 2 systems (i.e. quasi-binary systems) and the method of computer experiment based on this theory (Brit. Polym. J., 23 (1990)285; 23 (1990)299; Polym. Int., 29 (1992)219), could point curves (CPC), two-phase volume ratios ( R ) and critical solution points (CSP) have been determined experimentally for the quasi-binary mixtures of poly(ethylene oxide) (M¯w = 647, M¯w/M¯n = 1.15; M¯w and M¯n, the weight-average and numberaverage molecular weights, respectively) and poly(propylene oxide) (M¯w = 2028, M¯w/M¯n = 1.08; and Mw = 2987, Mw/Mn = 1.13). The hydroxyl end groups of both polymers were methoxylated in advance by the Cooper & Booth method (Polymer, 18 (1977)164). The thermodynamic interaction parameter between both polymers, χ12, and the concentration dependence parameters for the above quasi-binary systems were determined by the method proposed in a previous paper (Brit. Polym. J., 23 (1990)299). CPC, R and CSP values calculated on the basis of the theory are in good agreement with the values determined experimentally. 相似文献
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84.
Marcio Schwaab 《Chemical engineering science》2006,61(17):5791-5806
Model discrimination procedures are useful tools for selection of the best mathematical models to be used to represent a specific chemical process. The present paper presents and discusses a new sequential discrimination procedure, which makes use of model probabilities and concentrates the efforts on models with higher probabilities. Model probabilities are determined based on simple statistical arguments. Four numerical examples illustrate the application of the proposed discrimination procedure. The obtained results indicate that the new procedure is able to discriminate kinetic models with fewer experiments when compared to other procedures and also indicates when model discrimination is not possible and, thus, when the sequential design must be halted. Furthermore, the speed of the proposed discrimination procedure can be controlled by tuning a design parameter which reflects the analyst's mood (confidence) towards the discrimination problem and allows for increase or decrease of the number of experiments required for model discrimination during the sequential procedure. 相似文献
85.
文中主要针对多爆炸成型弹丸空爆战斗部,在分析区域识别和占空比识别两种不同扫描准则的基础上,应用蒙特卡洛方法计算了战斗部对目标的毁伤概率.通过仿真计算结果对比分析,获得了不同扫描准则对毁伤概率的影响,结果可为多爆炸成型弹丸空爆战斗部设计和选择使用扫描准则提供参考依据. 相似文献
86.
在役油气管道安全评定软件 总被引:1,自引:0,他引:1
PSAforWindows是运行在Windows系统下的油气管道安全评定软件。该软件既可以用于在开挖中发现的管道局部缺陷的剩余强度的精确评定 ,又可以用于腐蚀检测之后对管道全线的安全评定与剩余寿命预测。软件中采用了非线性有限元分析、失效评定图和概率性的评定方法等最新成果。介绍该软件的结构、模块、软件特点、主要功能和操作界面 相似文献
87.
This article is concerned with the l2-approximation of a given transfer function f by a rational one whose order is prescribed. We show that the sum of the indices of the critical points of the criterion is generically equal to 1, and in particular does not depend on f. 相似文献
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We say that a distribution over {0,1}n is (ε,k)-wise independent if its restriction to every k coordinates results in a distribution that is ε-close to the uniform distribution. A natural question regarding (ε,k)-wise independent distributions is how close they are to some k-wise independent distribution. We show that there exist (ε,k)-wise independent distributions whose statistical distance is at least nO(k)·ε from any k-wise independent distribution. In addition, we show that for any (ε,k)-wise independent distribution there exists some k-wise independent distribution, whose statistical distance is nO(k)·ε. 相似文献
90.
[Correction Notice: An erratum for this article was reported in Vol 29(6) of Journal of Experimental Psychology: Learning, Memory, and Cognition (see record 2007-16865-001). On page 684, Table 4, all correlations should have been identified as having a pp then q") as indicating a high conditional probability P(q|p). Participants estimated the probability that a given conditional is true (Experiments 1A, 1B, and 3) or judged whether a conditional was true or false (Experiments 2 and 4) given information about the frequencies of the relevant truth table cases. Judgments were strongly influenced by the ratio of pq to p?q cases, supporting the conditional probability account. In Experiments 1A, 1B, and 3, judgments were also affected by the frequency of pq cases, consistent with a version of mental model theory. Experiments 3 and 4 extended the results to thematic conditionals and showed that the pragmatic utility associated with believing a statement also affected the degree of belief in conditionals but not in logically equivalent quantified statements. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献