Proton and hydrogen formation by cyclohexyl benzene during overcharge of Li-ion batteries

This study provides experimental evidence for proton and hydrogen formation caused by the anodic electropolymerization of cyclohexyl benzene (CHB), which is a popular electrolyte additive for overcharge protection of lithium-ion batteries (LIBs). It is found that considerable H₂ evolution is observed in overcharged LiCoO₂/graphite cells, especially when CHB is included as an electrolyte additive. In order to confirm the proton generation during the CHB oxidation, Pt/Pt-rotating ring disc electrode (RRDE) measurements are performed in 1 M Li(C₂F₅SO₂)₂N ethylene carbonate/ethyl methyl carbonate (1/2, v/v) solutions with and without CHB. The cathodic ring current is intimately correlated to the anodic disc current, and the cathodic reaction at the ring is determined to be the reduction of the proton. The proton generation efficiency during the CHB oxidation is as high as 90%. Proton liberation is also observed during the anodic decomposition of the electrolyte solvents, although it occurs in a much less stoichiometric way compared with that during the CHB oxidation.     

龙开口水电站溢流坝段动力模型破坏试验研究

采用仿真混凝土材料研究了龙开口水电站溢流坝段在不同因素影响下的动力破坏特征,并通过对6个模型试验结果的分析探讨了溢流坝段的动力破坏机理。试验中考虑了坝体-库水的动力相互作用以及横河向地震动对大坝破坏的影响,采用规范谱波和场地谱波两种地震动激励进行模型超载破坏分析。试验结果为工程设计和评价溢流坝段的抗震性能提供依据。     

新材料在汽车发动机上的应用探析

作为汽车重要组成部分的发动机 ,一直是人们研究的重点。汽车发动机性能的提高 ,在很大程度上依赖于材料的选用和加工工艺等因素。本文介绍了现代汽车发动机主要零部件新材料选用、结构设计及工艺现状 ,指出了未来汽车发动机新材料的发展趋势和应用前景     

APDT-00三极放电管全自动打印机的研制

介绍了新近研制的APTD - 0 0三极放电管全自动打印机的结构特点及整机设计的关键技术 ,阐述了自动上料机构、打印机构和控制电路的设计     

乳胶厚度对卤化银反射全息图衍射特性的影响

实验研究了自制的超细颗粒卤化银乳剂SDUF－1分别在AAC显影、改进的R－10漂白处理及改进的GP－8溶解物理显影处理条件下，其乳胶厚度对反射全息图衍射特性的影响。实验结果表明，在这两种不同处理条件下衍射效率与胶厚的关系有相当大的差别，合适的乳胶厚度分别为12μm和6μm左右。     

纳米氧化铝的制备及应用

介绍了高科技产品纳米氧化铝的 3大制备方法 :固相法、气相法、液相法的优缺点 ,以及纳米氧化铝的应用与发展前景     

The boundary contour method for two-dimensional Stokes flow and incompressible elastic materials

 A variant of the boundary element method, called the boundary contour method (BCM), offers a further reduction in dimensionality. Consequently, boundary contour analysis of two-dimensional (2-D) problems does not require any numerical integration at all. While the method has enjoyed many successful applications in linear elasticity, the above advantage has not been exploited for Stokes flow problems and incompressible media. In order to extend the BCM to these materials, this paper presents a development of the method based on the equations of Stokes flow and its 2-D kernel tensors. Potential functions are derived for quadratic boundary elements. Numerical solutions for some well-known examples are compared with the analytical ones to validate the development. Received 28 August 2001 / Accepted 15 January 2002     

非晶软磁合金的巨磁阻抗效应及应用

近来在ＦｅＣｏＳｉＢ等Ｃｏ基非晶体丝带中现了巨磁阻抗效应，由于在一小的直流纵向偏置场下该效应能使丝带两端的交流电压发生大而灵敏的变化，因而在磁记录头和传顺技术中具有巨大的应用科学潜能，受到各国学者的关注，本文简单介绍了巨磁阻抗效应的来源，并综述了近年来非晶体软磁合金材料的的巨磁阻抗效应及应用的研究进展，文章最后说明了尚待深入解决的问题。     

Ti基MnO_x型DSA析氧电极材料的性能

本文报导了新型 Ti/SnO_2+MnO_x+RuO_2/MnO_x(DSA)电极材料的各种性能,其中包括电极的导电性、表面粗糙度、电化学活性表面积、析氧阳极特性等,并用 X 射线衍射法进行了物相分析、用 SEM观察了表面形貌。确认该电极性能良好,加之成本较低,可作为酸性介质中的析氧电极材料。     

难熔金属与硬质材料进展─—从第十三届国际普兰西会议看发展动向（Ⅰ）

根据第十三届国际普兰西会议获得的信息，对国际上难熔金属、硬质合金、硬质材料和涂层技术等方面近几年来的研究和发展动态进行了综合评述。最后，提出了几点自己的看法。