Synthesis and characterisation of carboxylic acid and diphenylphosphine derivatives in the 1,3-diyne series: Spectral properties of polydiacetylene carboxylates

Symmetrically substituted 1,3-diynes containing hydroxyalkyl ( 1a-d ), bromoalkyl ( 1e-h ) (diphenylphosphinyl) ( 1i-k ) and carboxyalkyl ( 2a-d ) substituents have been prepared and characterised; the phosphine derivative ( 1k ) has been converted with alkyl iodides ( RI ; R = Me, Et) into bis(phosphonium) salts ( 1l and m ). During preparation of the diynedioic acid. ( 2a ), the non-centrosymmetrical diyne, HO₂CCH₂C?C—C?C(CH₂)₂OH ( 3 ), was also isolated. ⁶⁰Co γ-Irradiation of diacetylene monomers ( 2a – d ) and 10,12-tricosadiyn-1-oic acid gave the corresponding polydiacetylene derivatives ( 4a – d and 5 ), respectively. Rubidium salts of ( 4c ) and ( 4d ), a barium salt of ( 4c ), and a potassium salt of ( 5 ) were prepared and isolated; soluble potassium salts of the carboxylic acid polymers ( 4 ) were generated in aqueous solution. The effects of changes in pH on the UV/visible absorption spectra of aqueous solutions of selected carboxylic acid polydiacetylenes have been recorded, and are discussed.     

抽油机减速器齿轮的失效分析

找出了人字齿轮减速器在工作中右端齿轮出现严重磨损的原因并进行了分析。提出在国内现有制造技术的条件下，对于37kN·m以下的减速器应推广使用斜齿轮传动。     

矿用扁平接链环静态电测实验及有限元分析

对φ30的矿用扁平接链环进行静态拉伸电测实验，分析并得出产生最大强度的位置。同时应用ANSYS有限元分析软件对接链环的力学简化模型进行分析，与实验结果相比较，有助于找出齿部破坏规律，对齿形的改进及今后的疲劳分析具有重要意义。     

非标准工况下空分设备增产氩的研究与实践

文章对非标准工况下的空分设备增产氩措施进行了研究。以宝钢6#60000m3/h空分设备为例,通过设计型算法和校核型算法,建立了空分设备精馏的数学模型,通过改变数学模型的参数,分析了在非标准工况下精馏塔内的组分浓度分布,并提出了优化后的操作方案和操作参数,实施后提高了空分设备的氩提取率,取得了显著的经济效益。     

电子商务中SET协议的安全缺陷研究

目前SET协议在电子商务交易中应用越来越广泛,因此,对SET协议的安全性的要求就越来越高。论文在SET协议的交易流程基础上,分析了其安全机制采用的技术和优点,指出了SET协议安全性存在的一些问题。     

堆载预压法加固软基土体稳定性的有限元分析

堆载预压过程中,进行相应的稳定分析对于控制加载速率、确定加载高度是必须进行的一项工作,采用有限单元法对此进行了探讨,详细阐述了有限元理论分析边坡稳定的几种重要因素,并考虑分步堆载的特点,模拟堆载过程,具有一定的工程实际意义。     

Putting it all together – Formal verification of the VAMP

In the verified architecture microprocessor (VAMP) project we have designed, functionally verified, and synthesized a processor with full DLX instruction set, delayed branch, Tomasulo scheduler, maskable nested precise interrupts, pipelined fully IEEE compatible dual precision floating point unit with variable latency, and separate instruction and data caches. The verification has been carried out in the theorem proving system PVS. The processor has been implemented on a Xilinx FPGA. A shorter version of this article with the title “Instantiating uninterpreted functional units and memory system: functional verification of the VAMP” appeared in [8]. The work reported here was done while all the authors were with Saarland University.     

川中丘陵区一种新型小流域径流输沙模型的建立与应用

径流输沙模型对定量评价水沙的输出响应具有重要的意义。本研究在已有研究成果的基础上，通过对四川盐亭县林山西沟小流域的径流、泥沙进行现场观测与分析，提出含沙量单位线的定义及其确定方法，建立了适应该小流域的径流输沙模型。并应用实测资料进行比较，表明模型的模拟结果可靠，模拟过程确定性系数达0．8以上，为川中丘陵区小流域径流输沙过程的预测预报提供了一个新方法。     

Development of a Magnetic Suspension Densimeter and Measurement of the Density of Toluene

The development of a magnetic suspension densimeter that has been built for measurement of the density of compressed liquid at pressures up to 30 MPa in the temperature range 20 to 150°C is described. The densimeter was first built by the author and his coworkers at NIST. We describe here further improvements made on a second system built at NMIJ based on the same principle. The densimeter uses a small coil suspended from an electronic balance. Within the coil is placed a sample cell in which the pressurized sample and a buoy, which is a permanent magnet, are enclosed. For measurement of density, balance readings are recorded (1) with the buoy at rest and (2) with the buoy in magnetic suspension. The measurement procedure is basically a hydrostatic weighing, which is simpler than those of conventional magnetic densimetry. As an example, measurements of toluene density performed as part of an inter-laboratory comparison are presented. The data agreed with reliable literature values to within a few hundredths of a per cent.     

天楼地枕水电站的综合自动化改造

天楼地枕水电公司为实现水电站"无人值班,少人值守"的目标,对水电站进行了综合自动化改造,论述了该自动化系统的结构特点及实施情况.