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51.
Xianjin Li Tianyu Li Pengcheng Xu Congxin Xie Yunhe Zhang Xianfeng Li 《Advanced functional materials》2021,31(22):2100133
Bromine-based flow batteries (Br-FBs) are considered one of the most promising energy storage systems due to their features of high energy density and low cost. However, they generally suffer from uncontrolled diffusion of corrosive bromine particularly at high temperatures. That is because the interaction between polybromide anions and the commonly used complexing agent (N–methyl–N–ethyl–pyrrolidinium bromide [MEP]) decreases with increasing temperatures, which causes serious self-discharge and capacity fade. Herein, a novel bromine complexing agent, 1–ethyl–2–methyl–pyridinium bromide (BCA), is introduced in Br-FBs to solve the above problems. It is proven that BCA can combine with polybromide anions very well even at a high temperature of 60 °C. Moreover, the BCA contributes to decreasing the electrochemical polarization of Br−/Br2 couple, which in turn improves their power density. As a result, a zinc–bromine flow battery with BCA as the complexing agent can achieve a high energy efficiency of 84% at 40 mA cm−2, even at high temperature of 60 °C and it can stably run for more than 400 cycles without obvious performance decay. This paper provides an effective complexing agent to enable a wide temperature range Br-FB. 相似文献
52.
《Ceramics International》2021,47(20):28338-28347
Transition metal oxides have been explored in supercapacitor applications owing to their safety, low cost, high specific capacitance and high electrochemical activity. Among all transition metal oxides, zinc oxide based materials show remarkable response for designing the supercapacitors with high electrochemical activity. Here in, Mn doped ZnO (Zn1-xMnxO3 with x = 0, 0.25, 0.50, 0.75 and 1) was synthesized by a facile hydrothermal method. Doping of Mn into the ZnO increased the surface area and decease the charge transfer resistance for the Zn0.5Mn0.5O3. All the synthesized materials were characterized by x-ray diffraction (XRD), scanning electron microscopy SEM), BET, electrochemical tests and other various analytical techniques to confirm the structural, morphological, textural and suprcapacitive properties. The synthesized material Zn0.5Mn0.5O3 having the porous nanoribons structure with BET surface area (2490 cm2/g). The electrochemical studies showed significantly enhanced response toward pseudocapacitive nature. The synthesized material exhibited the excellent specific capacitance (515F/g), specific energy (28.61 Wh/kg) and specific power (1000 W/kg) at current density of 2 mA/g. Such impressive and superior properties make the MnZnO3 material as promising candidate for new generation supercapacitor applications. 相似文献
53.
《Journal of the European Ceramic Society》2022,42(4):1568-1575
Li7La3Zr2O12-based garnet-type solid electrolytes are promising candidates for use in all-solid-state lithium batteries (ASSLBs). However, their potential in large-scale commercial applications is largely hindered by the time/energy-consuming and lithium-wasting synthetic method which typically needs a long-duration high temperature solid state reaction process. Herein we invent a fast preparation route that involves a short-period thermal reaction (1100 °C for 10 min) in laboratory muffle furnaces following by conventional hot pressing technique to get almost fully dense (Al, Ga, Ta, Nb)-doped garnet-type electrolytes with high phase purity (>99.9 %). The large and compact grains, low porosity and high phase purities of garnet ceramic electrolytes synthesized in this study ensure superior electrochemical performance. Particularly, Ga-doped cubic Li7La3Zr2O12 shows extremely low Ea values (0.17?0.18 eV) and record-high lithium ionic conductivities (>2 × 10?3 S cm-1 at 25 °C). 相似文献
54.
A size-dependent governing equation is derived to investigate the torsional static behaviors of two-dimensionally functionally graded microtubes based on the modified couple stress theory. The shear modulus is assumed to vary along the tube’s length direction according to an exponential distribute function, and varies along the tube’s radius direction according to a power-law function. A generalized differential quadrature method is developed to determine the rotational angle and shear stresses. Some illustrative examples are given to investigate the effects of applied torques, the length scale parameter and various material compositions on the torsional angle and shear stresses. 相似文献
55.
ABSTRACT Design and implementation of an effective dissemination programme for decentralised renewable energy system necessitate an accurate estimate of its utilisation potential. Hence, in this study, an attempt has been made to develop frameworks to estimate the utilisation potential of decentralised renewable energy systems in the state of Uttarakhand in India. Estimations imply large resource, technical and economic potentials of the domestic solar water heater, solar home system, solar lantern, family size biogas plant and improved biomass cookstove in Uttarakhand. With higher impact on the purchasing power of households, prevailing soft loan scheme has been found to be more appropriate than a capital subsidy for promoting the usage of decentralised renewable energy systems. 相似文献
56.
This paper presents a state-of-the-art survey of papers reported on the nature of a troublesome failure mode in bearings known as seizure. This mode of failure is thermally-induced and it occurs in both journal and rolling element bearings. To gain insight, particular attention is given to reported experimental observation, various mechanisms involved, and available prediction methodologies. 相似文献
57.
Shensong Wang Zheng Wu Jie Chen Jiangping Ma Jingshi Ying Shouchen Cui Shigang Yu Yongming Hu Jinhe Zhao Yanmin Jia 《Ceramics International》2019,45(9):11703-11708
In this work, the hydrothermally-synthesized sodium niobate nanowires were used to decompose Rhodamine B dye solution through the piezo-catalytic effect. With the sodium niobate catalyst, a high piezo-catalytic degradation ratio of ~80% was achieved under the excitation of vibration for the Rhodamine B dye solution (~5?mg/l). These active species in the catalytic process, hydroxyl radicals and superoxide radicals with the strong oxidation ability, were also observed, which confirmed the key role of piezoelectric effect for piezo-catalysis. The piezo-catalysis of sodium niobate nanowires provides a high-efficiency and reusable tool in application in depredating the dye wastewater. 相似文献
58.
《Current Opinion in Solid State & Materials Science》2020,24(1):100797
This paper reviews recent studies, that not only includes both experiments and modeling components, but celebrates a close coupling between these techniques, in order to provide insights into the plasticity and failure of polycrystalline metals. Examples are provided of studies across multiple-scales, including, but not limited to, density functional theory combined with atom probe tomography, molecular dynamics combined with in situ transmission electron miscopy, discrete dislocation dynamics combined with nanopillars experiments, crystal plasticity combined with digital image correlation, and crystal plasticity combined with in situ high energy X-ray diffraction. The close synergy between in situ experiments and modeling provides new opportunities for model calibration, verification, and validation, by providing direct means of comparison, thus removing aspects of epistemic uncertainty in the approach. Further, data fusion between in situ experimental and model-based data, along with data driven approaches, provides a paradigm shift for determining the emergent behavior of deformation and failure, which is the foundation that underpins the mechanical behavior of polycrystalline materials. 相似文献
59.
Synergistic flame retardant effects of activated carbon and molybdenum oxide in poly(vinyl chloride)
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Mengjiao Zhang Weihong Wu Shaorui He Xue Wang Yunhong Jiao Hongqiang Qu Jianzhong Xu 《Polymer International》2018,67(4):445-452
The synergistic effects of activated carbon (AC) and molybdenum oxide (MoO3) in improving the flame retardancy of poly(vinyl chloride) (PVC) were investigated. The effects of AC, MoO3 and their mixture with a mass ratio of 1:1 on the flame retardancy and smoke suppression properties of PVC were studied using the limiting oxygen index and cone calorimeter tests. It was found that the flame retardancy of the relatively cheaper AC was slightly weaker than that of MoO3. In addition, the incorporation of AC and MoO3 greatly reduced the total heat release and improved smoke suppressant property of PVC composites. When the total content of AC and MoO3 was 10 phr, PVC/AC/MoO3 had the lowest peak heat release rate and peak smoke production rate values of 173.80 kW m?2 and 0.1472 m2 s?1, which represented reductions of 47.3 and 59.9%, respectively, compared with those of PVC. Furthermore, thermogravimetric analysis and gel content tests were used to analyze the flame retardant mechanism of AC and MoO3, with results showing that AC could promote early crosslinking in PVC. Char residue left after heating at 500 °C was analyzed using scanning electron microscopy and Raman spectroscopy, and the results showed that MoO3 produced the most compact char, with the smallest and most organized carbonaceous microstructures. © 2017 Society of Chemical Industry 相似文献
60.
《The Electricity Journal》2020,33(7):106816
Using mean value theorem for integrals we show that the well-known LCOE definition is incorrect. 相似文献