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991.
林明德 《现代塑料加工应用》2002,14(2):1-4
介绍了日本三菱油化公司(现为三菱化学公司)BC-8嵌段聚丙烯的开发经过及实际结构。近年结构分析结果发现BC-8嵌段聚丙烯并非嵌段物,而是由均聚聚丙烯、EPR(乙丙橡胶)以及聚乙烯(链上有少量丙烯单元但并非嵌段物)三者组成的高分子合金。 相似文献
992.
用无向网表示学校的平面图,设计了该平面图的存储结构,并应用最短路径算法实现了查询图中各景点的相关信息,以及查询图中任意两个景点间的最短路径的功能;应用克鲁斯卡尔算法构造该平面图的最小生成树,求出可以连通所有景点的最短路径。该系统为新生熟悉校园环境提供了方便。 相似文献
993.
实际工程中采集和处理的数据量特别大,这对传统数据库技术提出巨大挑战。针对传统关系型数据库存储速度慢、对硬件要求高的缺点,提出一种以NoSQL数据库为基础的大数据处理方法,打破了传统数据库的关系模型,数据以一种自由的方式存储,而不依赖固定的表结构。该方法主要是将经验模态分解并与NoSQL数据库技术相结合,应用于大型结构件的变形监测中,构建出一个基于NoSQL数据库系统的大型结构件变形监测系统。仿真结果表明,该方法可以实现大型结构件变形监测数据的实时处理,在计算收敛性、算法稳定性和处理速度上都优于传统数据库技术。 相似文献
994.
李志萍 《电脑编程技巧与维护》2014,(4):6-8,17
运用随机游走模型提出了一种基于维基百科的语义相关度的计算方法。维基百科中包含了丰富的链接结构,这些链接结构一定程度上能够反应词条之间概念上的相关性,以内容链接和外部链接关系来计算基于维基百科的语义相关度,并在WS-353数据集上进行了实验,取得了较好的准确性。 相似文献
995.
The role of Al in C-S-H: NMR, XRD, and compositional results for precipitated samples 总被引:2,自引:0,他引:2
X-ray diffraction, compositional analysis, and 29Si and 27Al MAS NMR spectroscopy of Al-substituted tobermorite-type C-S-H made by precipitation from solution provide significant new insight into the structural mechanisms of Al-substitution in this important and complicated phase. Al occurs in 4-, 5-, and 6-coordination (Al[4], Al[5], and Al[6]) and plays multiple structural roles. Al[4] occurs on the bridging tetrahedra of the drierkette Al-silicate chains, and Al[5] and Al[6] occur in the interlayer and perhaps on particle surfaces. Al does not enter either the central Ca-O sheet or the pairing tetrahedra of the tobermorite-type layers. Al[4] occurs on three types of bridging sites, Q3 sites that bridge across the interlayer; Q2 sites that are charge balanced by interlayer Ca+2, Na+, or H+; and Q2 sites that are most likely charge balanced by interlayer or surface Al[5] and Al[6] through Al[4]-O-Al[5,6] linkages. Although the data presented here are for relatively well-crystallized tobermorite-type C-S-H with C/S ratios ≤ 1.2, comparable spectral features for hydrated white cement pastes in previously published papers[30], [31] and [32] [M.D. Andersen, H.J. Jakobsen, J. Skibsted, Incorporation of aluminum in the calcium silicate hydrate (C-S-H) of hydrated Portland cements: a high-field 27Al and 29Si MAS NMR investigation Inorg. Chem. 42 (2003) 2280-2287; M.D. Andersen, H.J. Jakobsen, J. Skibsted, Characterization of white Portland cement hydration and the C-S-H structure in the presence of sodium aliminate by 27Al and 29Si MAS NMR spectroscopy, Cem. Concr. Res. 43 (2004) 857-868; M.D. Andersen, H. J. Jakobsen, J. Skibsted, A new aluminum-hydrate phase in hydrated Portland cements characterized by 27Al and 29Si MAS NMR spectroscopy, Cem. Concr. Res., submitted for publication.] indicate the presence of similar structural environments in the C-S-H of such pastes, and by implication OPC pastes. 相似文献
996.
We report a novel method of polyimide (PI) synthesis from prepolymers based on dianhydrides and diacetyl derivatives of aromatic diamines that facilitate the preparation of a melt processable mixture at 300 ± 10°C of the prepolymer and magnetic Nd‐Fe‐B alloy to provide PI‐bonded magnets with enhanced properties. It is shown that chemical structure of the prepolymers strongly influences viscosity behavior via crystallization of the oligoimide in the melt, leading to formation of PI with rigid‐rod like structure. This structural ordering of the prepolymers based on diacetyl derivative of diamine used in this study, if not controlled, leads to exponential increase of melt viscosity with time, making it practically impossible to prepare melt processable mixture of the magnetic particles and the PI prepolymers at elevated temperatures. The results obtained demonstrate that appropriate dianhydrides and diacetyl derivatives of diamines that do not lead to crystallization of oligoimides in prepolymer mixture can be used under controlled processing conditions to prepare melt‐processable PI‐bonded magnets containing rigid‐rod like PI structure that significantly increases thermal stability of the magnets. The temperature dependencies of the magnetic properties of the PI‐bonded magnets under conditions that they are likely to encounter during their service life were found to be remarkably similar to that of commercial thermoplastic magnets such as injection‐molded nylon magnets. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 478–485, 2006 相似文献
997.
998.
Ki Soo ParkMyung Hun Cho Sang Ho ParkKee Suk Nahm Yang Kook SunYun Sung Lee Masaki Yoshio 《Electrochimica acta》2002,47(18):2937-2942
Layered Li0.7[M1/6Mn5/6]O2 (M=Li, Ni) was synthesized using a sol-gel method. P2-Na0.7[M1/6Mn5/6]O2 precursor was first synthesized by a sol-gel method, and then O2-Li0.7[M1/6Mn5/6]O2 was prepared by an ion exchange of Li for Na in P2-Na0.7[M1/6Mn5/6]O2 precursor. From charge/discharge curves, it was seen that Li0.7[Li1/6Mn5/6]O2 has two plateaus similar to those observed from a spinel structure, but Li0.7[Ni1/6Mn5/6]O2 holds a single plateau as observed from a typical layered structure. It was considered that Li0.7[Li1/6Mn5/6]O2 undergoes a phase transformation from layered to spinel structure during the charge/discharge cycle, but Li0.7[Ni1/6Mn5/6]O2 maintains O2-layered structure after the cycles. Li0.7[Ni1/6Mn5/6]O2 was higher in discharge capacity and retention rate than Li0.7[Li1/6Mn5/6]O2. 相似文献
999.
Magorzata T. Kaczmarek Izabela Pospieszna-Markiewicz Maciej Kubicki Wanda Radecka-Paryzek 《Inorganic chemistry communications》2004,7(12):1247-1249
The one-step metal promoted reaction between salicylaldehyde and 4-methyl-1,3-phenylenediamine in the presence of lanthanum(III) or gadolinium(III) nitrate yields new salicylaldimine complexes containing N,N′-bis(salicylidene)-4-methyl-1,3-phenylenediamine as a result of the [2 + 1] Schiff base condensation. The crystal structure of the gadolinium complex reveals a dinuclear species with four unionized ligands coordinating in the monodentate and bridging bidentate fashion, using exclusively the oxygens as donor atoms with the nitrogen atoms not being involved in coordination. The coordination number of nine is achieved by involving three bidentate nitrate counterions in the coordination sphere. 相似文献
1000.
抗冲聚丙烯结构与性能研究 总被引:4,自引:2,他引:4
对部分国内外抗冲聚丙烯(PP)产品进行了微观形态和结构分析,研究其对材料宏观力学性能的影响。实验结果表明:抗冲PP是一个含有PP均聚物、丙烯与乙烯-丙烯两嵌段共聚物、乙丙橡胶(EPR)、聚乙烯均聚物等的多相体系。EPR的分子序列结构对聚合物抗冲击性能起主要作用。在序列结构中,丙烯、乙烯单体在分子链上的位置交换越频繁,抗冲击性能越得到提高。丙烯序列平均长度的增大对抗冲击性能有一定的削弱作用。 相似文献