催化氧化法合成脂肪醇醚羧酸盐的研究进展

详细介绍了氮氧自由基催化氧化法和贵金属催化氧化法合成脂肪醇醚羧酸盐。氮氧自由基催化时,反应温度20～60℃,反应时间3～6 h,得到酸型产品。贵金属催化剂中,钯的催化活性比铂高。贵金属催化时,加入铅、铋等助催化剂,并以活性炭为载体,碱性条件下于50～90℃反应2～6 h,得到盐型产品。在适当的条件下,这两种方法均可使醇醚转化率达95％,选择性达90％以上。     

曙—区超稠油间歇蒸汽吞吐技术探讨

针对曙-区超稠油井进入高周期后产量递减，成本上升的矛盾，提出用间歇吞吐技术改善高周期蒸汽吞吐效果，通过对吞吐机理和现场实际资料统计的分析。对这项技术实施的条件及效果进行了探讨。结果表明，该项技术在高周期井实施效果较好。具有较好的推广前景。     

Synthesis,Functionalization, and Bioconjugation of Monodisperse,Silica‐Coated Gold Nanoparticles: Robust Bioprobes

Herein, we report an efficient process for preparing monodisperse Au@SiO₂ nanoparticles using homogeneous shaking and without the use of surface‐coupling silane agents or large stabilizers. The resulting pure‐silica surface of the Au@SiO₂ nanoparticles is very important for straightforward surface functionalization with different functional groups via well‐established silica surface chemistry. Subsequent covalent bioconjugation of the aldehyde‐functionalized Au@SiO₂ nanoparticles with various biomolecules is successfully employed to make robust nanoprobes for fast, colorimetric DNA and protein detection based on the sequence‐specific hybridization properties of DNA and the specific binding affinity between proteins, respectively.     

树状大分子/金属纳米复合物的制备与催化作用

综述了一类新的有机/无机杂化纳米材料———树状大分子/金属纳米复合物的制备及其催化作用。树状大分子/金属纳米复合物是以树状大分子为模板或稳定剂,通过还原树状大分子内或树状大分子间螯合金属离子制备。讨论了树状大分子/金属纳米复合物在水、有机溶剂、氟/有机两相溶剂和超临界CO2中的催化作用。     

石油天然气长输管线用钢新进展

本文介绍了１９９０年以来国外在石油天然气长输管线用钢方面的最新成果，以获得较低的强度和韧性匹配为目的经轧后加速冷却工艺后的钢的强度的预测和控制；具有优良抗氢致裂纹的含硼、微碳、低硫、Ｎｂ－Ｔｉ微合金化、Ｘ６５－Ｘ８０级管线钢的开发，满足于特殊性能要求的ＴｉＯ处理技术及Ｘ８０级ＴｉＯ细化晶粒钢、低硬度和低屈强比钢，以及复合板加工耐腐蚀钢管的生产。     

PD275kg／m全长热处理钢轨研制

以高碳低锰碳素热轧钢轨为热处理原料轨，采用双频电感应加热、压缩空气欠速淬火热处理技术研制的ＰＤ２７５ｋｇ／ｍ热处理钢轨，硬化层深度≥１５ｍｍ、组织为细珠光体；力学性能：σ０．２８１５￣９８０ＭＰａ、σｂ１１８５￣１３４０ＭＰａ、δ５１０％￣１５％，常温冲击韧性ａＫ１４￣３３Ｊ／ｃｍ＾２，断裂韧性ＫＩｃ平均值４５．５ＭＰａ·ｍ＾１／２。具有强度高，塑韧性好的综合性能。使用性能优良，寿命比同曲线的Ｕ７     

圆盘式高速金属冷锯机锯切功率的实验研究

对１６００圆盘式高速金属冷锯机进行了锯切功率的实验研究。对某厂四种有代表性的产品，用不同的进锯速度，实测每种条件下的锯切功率变化，和最大瞬时锯切功率与平均锯切功率之比。并以实测数据为基础，得出每种产品以进锯速度为自变量的平均锯切功率回归公式。这些工作，不仅可以为这种冷锯机锯切功率的理论研究提供依据，还可直接为使用和设计这种冷锯机给出具体参考数据。     

Stress concentration and fatigue of profiled reinforcing steels

Stress concentrations arise from profiles of ribbed reinforcing steel bars and in this study the results of calculated stress concentration factors (SCF), by using finite element method, are related to the fatigue test results. It is apparent that the degree of confinement of a ribbed bar embedded in concrete not only affects the magnitude of the ultimate bond stress but also the bond stress-slip relation. Thus the rib geometry or profile pattern is designed for optimum bond characteristics and not for fatigue considerations. However the rib geometry influences the fatigue performance through the SCFs arising from the root radius, width and flank angles of the profiles. It is shown that these latter factors have a significant influence on the fatigue behaviour of reinforcing steel bars.     

孟加拉HATHAZARI 132kV电缆回流线取舍探讨

针对孟加拉Hathazari 100MW重油发电机组EPC工程132kV电缆现场实际设计、采购和敷设情况,通过理论计算探讨回流线取舍问题。