NO emission characteristics in counterflow diffusion flame of blended fuel of H2/CO2/Ar

Flame structure and NO emission characteristics in counterflow diffusion flame of blended fuel of H₂/CO₂/Ar have been numerically simulated with detailed chemistry. The combination of H₂, CO₂ and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of CO₂. A radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. The detailed chemistry adopts the reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions. All mechanisms including thermal, NO₂, N₂O and Fenimore are taken into account to separately evaluate the effects of CO₂ addition on NO emission characteristics. The increase of added CO₂ quantity causes flame temperature to fall since at high strain rates a diluent effect is prevailing and at low strain rates the breakdown of CO₂ produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the contribution of NO production by N₂O and NO₂ mechanisms are negligible and that thermal mechanism is concentrated on only the reaction zone. As strain rate and CO₂ quantity increase, NO production is remarkably augmented. Copyright © 2002 John Wiley & Sons, Ltd.     

Modeling and assimilation of root zone soil moisture using remote sensing observations in Walnut Gulch Watershed during SMEX04

Soil moisture status in the root zone is an important component of the water cycle at all spatial scales (e.g., point, field, catchment, watershed, and region). In this study, the spatio-temporal evolution of root zone soil moisture of the Walnut Gulch Experimental Watershed (WGEW) in Arizona was investigated during the Soil Moisture Experiment 2004 (SMEX04). Root zone soil moisture was estimated via assimilation of aircraft-based remotely sensed surface soil moisture into a distributed Soil-Water-Atmosphere-Plant (SWAP) model. An ensemble square root filter (EnSRF) based on a Kalman filtering scheme was used for assimilating the aircraft-based soil moisture observations at a spatial resolution of 800 m × 800 m. The SWAP model inputs were derived from the SSURGO soil database, LAI (Leaf Area Index) data from SMEX04 database, and data from meteorological stations/rain gauges at the WGEW. Model predictions are presented in terms of temporal evolution of soil moisture probability density function at various depths across the WGEW. The assimilation of the remotely sensed surface soil moisture observations had limited influence on the profile soil moisture. More specifically, root zone soil moisture depended mostly on the soil type. Modeled soil moisture profile estimates were compared to field measurements made periodically during the experiment at the ground based soil moisture stations in the watershed. Comparisons showed that the ground-based soil moisture observations at various depths were within ± 1 standard deviation of the modeled profile soil moisture. Density plots of root zone soil moisture at various depths in the WGEW exhibited multi-modal variations due to the uneven distribution of precipitation and the heterogeneity of soil types and soil layers across the watershed.     

各国核电厂场外应急计划的比较

本文分析和比较了各国核电厂的应急计划,特别是场外应急的干予水平和应急计划区,讨论了我国干予水平、核电厂应急计划区和香港核应急计划几个实际问题。     

Visualization and quantification of the mechanical deformation induced by an electrical field in poly(ethylene naphthalene 2,6‐dicarboxylate) (PEN) films

An optical nondestructive strain measurement technique was performed to analyze the mechanical deformation induced by an electrical field within the insulating materials. Poly(ethylene naphthalene 2,6‐dicarboxylate) (PEN) films were then subjected to constant electrical fields right up to their electrical breakdown. The experimental technique made it possible to follow the various stages of the mechanical behavior of PEN in real time. The final breakdown occurred in the observation zone and the related mechanical deformation was captured. A “margarita” structure was observed with a hole at the center. The experimental results indicated that the level of the induced‐mechanical deformations depended on the local environment. We defined two different zones representing the inside and the outside of the damaged area. The induced‐deformations were larger in the damaged zone. It was also observed that deformations increased when the sample had a lower degree of crystallinity. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Antimicrobial finishing of regular and modified polyethylene terephthalate fabrics

An effective two-stage method has been developed for imparting antimicrobial properties to regular polyethylene terephthalate (R-PET), polyethylene glycol modified polyethylene terephthalate (PEG-M-PET), R-PET/Cotton blend (R-PET/C) and PEG-M-PET/Cotton blend (PEG-M-PET/C) fabrics. The method consists of partial hydrolysis of the fabrics to create carboxylic groups in PET macromolecules followed by subsequent reaction with dimethylalkylbenzyl ammonium chloride (DMABAC) under alkaline conditions. The reaction conditions such as pH, reaction temperature and time, carboxylic content, and DMABAC concentration were studied. Characterization of the finished fabrics was carried out through scanning electron microscopy (SEM) and Fourier transform infrared spectra (FTIR). All the modified PET fabrics showed excellent antibacterial activity towards Gram-positive (Bacillus mycoides), Gram-negative (Escherichia coli), and nonfilamentous fungus (Candida albicans). The achieved antimicrobial functions on the PET fabrics are durable in repeated laundering processes. Even after laundering 10 times the fabrics could still provide more than 85% of its antimicrobial activity against B. mycoides, E. coli, and C. albicans. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

江苏复杂断块高含水单元改善水驱效果的技术对策

在分析高含水开发单元特点的基础上,针对该阶段剩余油的品位、分布和油水关系极为复杂、挖潜难度大的技术难点,提出了适合江苏复杂断块油田高含水开发单元改善水驱开发效果的思路和工作程序、技术对策,并在真武油田高含水开发单元进行了实际应用,取得了良好的效果.     

一种T形高压输电线路故障测距新方法

对T形线路的故障测距，现有方法都是先判断故障支路，再将3端线路等效成2端线路进行测距。但在 T节点附近短路，尤其是经高阻短路时，现有的测距方法由于无法正确判别故障支路而存在一定范围的测距死区。针对上述缺陷，分别假设故障发生在某一支路，由假定正常的2段支路端的电压、电流推算求得 T节点电压和注入假定故障支路的电流，从而分别求得3个故障距离。经证明，求得的3个故障距离有且仅有1个在0和对应支路总长度之间，该距离就是真实的故障距离，故障发生在对应支路上。该方法无需事先判别故障支路即可测距，在 T节点附近经高阻故障时无测距死区。其测距精度理论上不受过渡电阻和故障类型影响，无需故障前数据，且对滤波无高要求。EMTP仿真结果表明该方法正确、有效，测距精度高。     

Precipitation behavior of σ phase in fusion zone of dissimilar stainless steel welds during multi-pass GTAW process

The purpose of this study is to investigate the precipitation characteristics of σ phase in the fusion zone of stainless steel welds at various welding passes during a tungsten are welding (GTAW) process. The morphology, quantity, and chemical composition of the δ-ferrite and σ phase were analyzed using optical microscopy (OM), a ferritscope (FS), a X-ray diffractometer (XRD), scanning electron microscopy (SEM), an electron probe micro-analyzer (EPMA), and a wavelength dispersive spectrometer (WDS), respectively. Massive δ-ferrite was observed in the fusion zone of the first pass welds during welding of dissimilar stainless steels. The σ phase precipitated at the inner δ-ferrite particles and decreased δ-ferrite content during the third pass welding. The σ and δ phases can be stabilized by Si element, which promoted the phase transformation of σ→ϱ+λ₂ in the fusion zone of the third pass welds. It was found that the σ phase was a Fe−Cr−Si intermetallic compound found in the fusion zone of the third pass welds during multi-pass welding.     

Surface tension as a limiting factor for aerobic n-alkane biodegradation

A new mathematical model for n-alkane biodegradation in crude oil, heavy oil and paraffinic mixtures is described. The pattern of n-alkane degradation as a function of the inverse of hydrocarbon chain length reported in this paper can be considered as general behaviour for many aerobic n-alkane biodegradation processes. A new interpretation of n-alkane biodegradation as a function of surface tension, is given. A mathematical expression was obtained starting from the degradation values of n-alkane and relative surface tension, which is a parameter independent of fermentation conditions. An interesting parameter, b, was identified which represented the accelerating conversion factor for n-alkane biodegradation. The findings suggested that the n-alkane biodegradation. The findings suggested that he n-alkane biodegradation rate may be affected by the fermentation condition (agitation, aeration, etc.) and by the strain of microorganism, while the behaviour pattern of n-alkane degradation was essentially linked to the substrate characteristics (molecular structure, molecular weight and density).