硅藻土对上海潮土和黄泥土耕作性能改良的试验研究

采用硅藻土对上海两种农业土进行改良试验研究,分析了不同硅藻土体积比对上海潮土和黄泥土稠度指标、水稳定性大团聚体含量和击实性能的影响。试验表明:塑、液限值与硅藻土含量相关系数为0.981*、0.971*,并且硅藻土对塑、液限的影响与土的粘性聚合体含量成反比;硅藻土可以明显增加两种土中粒径大于0.25 mm的大团聚体的含量;硅藻土可以显著提高两种土的最优含水率并降低最大干密度,且相关性系数分别为0.993*、-0.999**。由此说明,硅藻土可以提高上海农业土的疏松度和保水性能。     

Preparation and properties of PMMA modified silica aerogels from diatomite

Diatomite was used as raw material to prepare sodium silicate with a modulus of 3.1 by alkalidissolution method and the resulted sodium silicate solution was employed as a precursor. Methyl methacrylate monomers were introduced in wet gels through solution-immersion, and upon heating at 70 ℃, the mesoporous surfaces throughout the skeletal framework were coated with the polymer layer. PMMA modified silica aerogels were successfully synthesized via ambient pressure drying. The properties were investigated by FTIR, NMR, TGA, nitrogen adsorption-desorption, FESEM and nano-indentation, etc. Results indicate that with the increasing of PMMA incorporated into silica aerogels, the bulk density and the BET surface area increase, the porosity decreases. Through the observation of FESEM, it is found that the interconnecting pores and the big pores add, the pore size distribution expands from 5-17 to 28-150 nm. By comparison, the PMMA modified silica aerogels achieve a 52-fold increase in hardness and a 10-fold increase in modulus.     

碱金属在白云鄂博铁精矿还原中的催化作用研究

利用失重法对碳的气化反应、CO气体以及碳还原白云鄂博铁精矿进行了实验,使用矿相、XRD分析了还原后样品的相组成与显微结构。研究结果表明：加入催化剂后,碳的气化反应速率和铁精矿还原速率提高,且K2CO3和Na2CO3的催化效果明显优于CaCO3的催化效果。催化剂的加入有助于碳的活性提高,加速了碳的气化反应,从而促进了白云鄂博铁精矿还原反应进行。     

Kinetics study of leaching arsenic from Ni-Mo ore roasting in dust mixture of hydrochloric and sulfuric acids

The kinetics of leaching arsenic from Ni-Mo ore roasting dust was investigated. The effects including leaching temperature, particle size of the smelter dust, stirring speed, the coefficient β（the molar ratio of sodium chlorate to arsenic in the smelter dust） and the initial H＋ concentration on leaching arsenic were studied. The results indicate that the leaching of arsenic increases sharply with the decrease of particle size. The orders of reaction with respect to H＋ concentration and particle size are determinted to be 1.136 and 1.806, respectively. The leaching of arsenic reaches 99% under experimental conditions, the apparent activation energy is determined to be 11.157 kJ/mol, which is consistent with the values of activation energy for diffusion model The kinetics equation of leaching arsenic from the roasting dust could be expressed by a semi-empirical equation as 1-2/3η （1 -η）^2/3 = k0（c[H＋]）^1.136ro^-1.806 exp[（-11157 /RT）t].     

硅藻土涂层气孔率对大口径球铁管外表面凹陷缺陷的影响

本文主要从涂层结构 ,即涂层气孔的种类、数量论述其对大口径球铁管外表面凹陷缺陷的影响。从涂料雾化液滴大小、金属型温度、喷嘴距金属型内表面距离、喷嘴移动速度、涂料中膨润土含量、金属型转速等工艺参数来控制涂层气孔率 ,保证涂层透气性 ,从而消除凹陷缺陷     

云锡塘子凹矿体矿岩物理力学参数研究

通过对 31- 1#矿体矿岩物理力学参数的研究 ,对矿岩特性及稳固性进行了科学、合理地评价 ,为矿体开采过程中采矿方法的选择、采场结构参数的确定及回采过程中 ,地压的管理提供了科学依据 ,从而保证了矿山生产的安全可靠性     

Copper hydrometallurgy-current status,preliminary economics,future direction and positioning versus smelting

The heap leaching of oxide copper ores with copper cathode recovery by solvent extraction and electrowinning is now well established as a low-cost method of copper recovery. This technology has recently been applied successfully to mixed oxide and chalcocite ores, notably in Chile at Cerro Colorado, Quebrada Blanca and Zaldivar.Currently, there are significant development efforts underway to try to extend heap leaching to chalcopyrite ores.The success of heap leaching/SX/EW has also led to a revival in the development of hydrometallurgical processes to recover copper from chalcopyrite and other copper concentrates. The current status of copper hydrometallurgy is reviewed and the most commercially attractive potential applications are explored. The advantages and disadvantages of the hydrometallurgical treatment of chalcopyrite concentrates and its preliminary economics are compared with those for the current best practices in copper smelting and refining.     

萃取技术处理低品位铜矿的设计实践

介绍了溶剂萃取技术在铜冶金中的应用,依据半工业实验报告,设计并提供了处理低品位铜矿的萃取流程及工艺参数控制,并确定了其设备的大小。     

THERMODYNAMIC AND STRUCTURAL CHEMISTRY DISCUSSIONS FOR OXIDATIVE LEACHING OF Cu－Ni SULPHIDE ORE UNDER ATMOSPHERIC PRESSURE

ＴＨＥＲＭＯＤＹＮＡＭＩＣＡＮＤＳＴＲＵＣＴＵＲＡＬＣＨＥＭＩＳＴＲＹＤＩＳＣＵＳＳＩＯＮＳＦＯＲＯＸＩＤＡＴＩＶＥＬＥＡＣＨＩＮＧＯＦＣｕ－ＮｉＳＵＬＰＨＩＤＥＯＲＥＵＮＤＥＲＡＴＭＯＳＰＨＥＲＩＣＰＲＥＳＳＵＲＥ￥Ｗｕ，Ｗｅｎｊｉａｎ（Ｄｅｐａｒ...     

电场作用对提高微生物浸矿性能的影响

在排土场微生物强化浸出过程中,结合电场生物工程技术,以氧化亚铁硫杆菌为研究对象,提出利用电场作用提高微生物浸矿性能的方法,探讨电场作用对微生物生长代谢以及渗流特性的影响。结果表明：电场作用对氧化亚铁硫杆菌生长代谢的影响非常明显,适当的电场可有效强化其生长代谢能力,过高的电流会抑制氧化亚铁硫杆菌生长;电场作用下,排土场孔隙中微生物的渗流能力明显增强,微生物电动渗流效应在渗透率高排土场中尤为明显。