离子交换法处理含Cr(Ⅵ)废水的研究

采用201×7强碱性阴离子交换树脂处理模拟含Cr(Ⅵ)废水,探讨了废水酸度、交换时间、浓度对Cr(Ⅵ)去除率的影响以及树脂再生所需的合适温度和再生剂浓度。结果表明,201×7强碱性阴离子交换树脂处理模拟含Cr(Ⅵ)废水,具有交换容量大、交换效果好、树脂再生条件较简单等优点。并对实际含铬废水进行了处理,废水中Cr(Ⅵ)的初始浓度为1 540 mg/L,处理量达52 BV(床体积)时,出水中Cr(Ⅵ)的浓度仍小于0.5 mg/L,达到国家排放标准。树脂交换容量约80 mg/g。用8%NaOH溶液,在50℃条件下进行再生效果较好,再生率大于95%,可实现树脂的重复使用。     

Rheology of oil in water emulsions with added solids

The effect of added solids on the rheology of oil in water emulsions was investigated. The range of the oil concentration, solids free basis, was (0-70%) and the solids volume fraction was (0-0.16). The solids mean diameter was 45 μm and it was about four times larger than the oil droplets. In the absence of added solids, non-Newtonian behaviour was observed for oil concentrations above 40%. The added solids increased the emulsion viscosity in a manner similar to the addition of solids to a homogeneous fluid. The rheological data of all the emulsion-solids mixtures investigated were correlated as relative viscosity versus solids volume fraction, where the relative viscosity is defined as the ratio of the emulsion-solids mixture viscosity to the solids-free emulsion viscosity. In the case of non-Newtonian systems, the emulsion-solids mixture viscosity and the solids-free emulsion viscosity were calculated at the same shear stress. The Barnea and Mizrahi viscosity correlation was found to fit the data well.     

关于低温低浊水混凝沉淀机理的探讨

文章介绍了低温浊水的水质特点，提出氧化剂对处理低温低浊水的作用。     

Urban water demand,climatic variation,and irrigation-water insecurity: interactive stressors and lessons for water governance from the Angat River basin (Philippines)

Climatic variation and intersectoral water competition increasingly challenge the effective provision of irrigation services. This article explores their combined effects on irrigation allocation from the Angat Reservoir (Philippines), where domestic water use in Metro Manila has overtaken regional irrigation as the dominant right-holder. Rules protecting Metro Manila’s large right to water ‘interact’ with dry spells to affect irrigation security in wet and dry seasons. Historically, irrigators were uncompensated because re-allocation’s cause was contested as (1) an unforeseeable climatic event (releasing domestic utilities of liability), or (2) produced by urban demand (requiring compensation). Trade-off rules must be prepared to navigate combinatory effects.     

上海地区不同商品粉煤灰水泥浆体的流变性能

采集了上海地区不同种类，等级和加工方式的7种商品粉煤灰，测定了种各种粉煤灰水泥浆体的流变性能，研究了商品粉煤灰品质与掺量对浆体流变参数的影响，并分析了影响浆体流变性能的粉煤灰主要品质因素。     

曝气生物滤池处理农村生活污水效率与微生物群落分析

以北京大兴区农村生活污水为处理对象,设计了4个反应柱,研究了3种填料结构、2种气水比条件下曝气生物滤池(BAF)对农村生活污水处理效率及微生物群落的影响。结果表明:(1)1~#、2~#、3~#柱气水比相同、填料结构不同,BOD5、CODCr和氨氮的去除率达到84.51%~96.49%;4~#柱与2~#柱填料结构相同,但气水比小,BOD5和CODcr处理效果差;4个柱TP的去除率低,需要强化除磷。(2)1~#、2~#、3~#柱OTU数量差异很小,说明微生物种类数量基本相同;2~#柱特有OTU数远大于4~#柱,说明填料结构相同条件下较大气水比有利于增加微生物种类。(3)1~#、2~#、3~#柱优势菌群主要有6种,在不同高度的优势菌群种类基本相同,但数量上有所差异;仅变形菌门中可能含有聚磷菌,这也是除磷效果差的原因之一。     

高分子破乳剂及其在大庆油田的应用实验

本文文综述了中老油田采出液性质的变化和高含水采出液的油水分离特性，探讨了聚醚型破乳剂和高分子破乳剂在高含水采出液状况下的适应性。通过理论分析和大庆两个联合站的现场实验证明，高分子破乳剂特别适用于高含水采出液的事实，并指出了其适应性和提出了其质量与适应性的评价方法。     

Preparation of microporous chlorinated poly(vinyl chloride) membrane in fabric and the characterization of their pore sizes and pore‐size distributions

Chlorinated poly(vinyl chloride) (CPVC)/poly(vinyl pyrrolidone) (PVP) membranes were prepared by using the solvent system tetrahydrofuran (THF)/n‐butyl alcohol (n‐BA) to investigate the possibility of pore size and pore‐size distribution control. The coagulation of CPVC/PVP solution was induced by the exposure to water vapor at 25 (±0.5)°C. The average pore diameter, d_p, and the size distribution of pores on the surface of the membrane were quantified through the image analyzer from the images visualized by field emission scanning electron microscope (FE‐SEM). Surface pore size and distribution of the prepared CPVC/PVP membrane were strongly affected by the relative humidity (RH) in the environment and the content of PVP used as an additive. Particularly, in the case of CPVC membrane without PVP, the mean pore size was 0.15–0.2 μm, depending on the RH. The pore distribution became broad with the increase of the RH. The membranes had open pores as confirmed by the hydraulic permeation experiment. In addition, the water flux and membrane resistance (R_m) were greatly affected by the composition of polymer solution and the RH. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1195–1202, 2002     

电石渣浆的综合治理与利用

介绍了综合治理电石乙炔法生产 PV C 时产生电石渣浆的工艺技术。采用电石渣浆废水全部 闭路循环回用工 艺,实现电石 渣浆上清液 的回收利用;同时以电石渣 代替熟石灰用 于环氧丙烷的生产。取得了显著的经济效益和社会环境效益。     

Complete Oxidation of Methane at Low Temperature over Pt Catalysts Supported on High Surface Area SnO2

The catalytic activity of Pt catalysts supported on high surface area tin(IV) oxide in the complete oxidation of CH₄ traces under lean conditions at low temperature was studied in the absence and in the presence of water (10 vol.%) or H₂S (100 vol.ppm). Their catalytic properties were compared to those of Pd/Al₂O₃ and Pt/Al₂O₃. In the absence of H₂S in the feed, Pt/SnO₂appears as a very promising catalyst for CH₄ oxidation, being even significantly more active under wet conditions than the best reference catalyst, Pd/Al₂O₃. Catalysts steamed-aged at 873 K were also studied in order to simulate long term ageing in real lean-burn NGV exhaust conditions. To this respect, Pt/SnO₂ is slightly less resistant than Pd/Al₂O₃. In the presence of H₂S, Pt/SnO₂catalysts are rapidly and almost completely poisoned, comparably to Pd/Al₂O₃and the catalytic activity is hardly restored upon oxidising treatment below 773 K. A synergetic effect between Pt and specific surface SnO₂sites active in CH₄oxidation is proposed to explain the superior catalytic behaviour of Pt/SnO₂.