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81.
天然气中甲烷和乙烷直接转化制乙烯 总被引:4,自引:1,他引:3
天然气中的甲烷和乙烷可以同时在Na2WO4-Mn/SiO2催化剂上得到活化生成乙烯。在甲烷转化率为20%时,原料甲烷氧化偶联反应生成C2+的选择性为~80%,原料乙烷反应的转化率为~85%,选择性为~70%。 相似文献
82.
通过对相变增韧陶瓷及一种可切削玻璃-陶瓷动态疲劳(恒应力速率)试验中高应力速率区断裂应力下降现象的理论分析,发现这种现象与材料的阻力特性(R-curve)密切相关。确立的σ_f-σ理论关系能够很好地描述整个应力速率区间内的动态疲劳试验结果。高应力速率区σ_f-σ在双对数坐标下为负斜率直线,直线斜率为(m为阻力曲线KR=k(△a)~m的指数),断裂主要由材料阻力行为控制;低应力速率区,σ_f-σ在双对数坐标下为正斜率直线,直线斜率为 (n为应力腐蚀指数),断裂主要由材料应力腐蚀行为控制。建立了测定材料阻力特性的一种新方法,分别用这种方法及压痕/弯曲方法对一种可切削玻璃-陶瓷的阻力特性进行了实验测定,两种方法所得结果有很好的一致性。 相似文献
83.
Daniela M. Nevskaia Maria Luisa Rojas Cervantes Antonio Guerrero Ruíz Juan de Dios Lpez Gonzlez 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):249-256
Adsorption of Triton X-100 on various silica substrates has been investigated. A number of solids, including a natural quartz, this quartz washed with HCl acid and subsequently heated at 1273 K; two aerosils and one Kieselgel silicas were studied. These solids exhibit surface areas in the range of 5 to 430 m2 g?1. All the Triton adsorption isotherms display an S-shape at the adsorption temperatures studied (298 and 308 K). It has been found that the pretreatments of natural quartz (by water washing, impurities removed by acid and/or high temperature calcination) affect considerably the amounts of TX-100 adsorbed. Measurements of surface composition have been made by X-ray photoelectron spectroscopy (XPS) with particular emphasis on the presence of impurities and on the number of OH groups at the surface of the samples. The nature of the surface hydroxyl has also been studied by infrared spectroscopy. Furthermore, the specific number of hydroxyl groups on the surface of the silica samples has been determined by thermogravimetric analysis. Finally an attempt to correlate solid surface characteristics with adsorption isotherms has been developed. 相似文献
84.
85.
矿业可持续发展理论及应用 总被引:11,自引:0,他引:11
在简要回顾我国矿业发展现状及其在环境破坏污染和资源浪费损失的基础上,提出矿业可持纽发展的概念与内涵,论述矿业可持续发展的动态2特征,并就如何实施矿业可持结发展战略进行了思考。 相似文献
86.
用强度系列成象法获取或显示高动态范围图象 总被引:1,自引:0,他引:1
提出一种适合于高动态范围图象的获取和显示的强度系列成象法。改变输入图象的强度,微机控制的图象采集系统进行记录得到一组磁盘文件,形成强度图象系列。基于记录的系列图象,可以进行信息提取、变换和显示等操作。基于获得的图象系列,提出一种剪贴操作进行快速的非线性图象变换。给出对光学功率谱处理的一个实例,它相当于进行锯齿形的非线性变换。 相似文献
87.
A batch reactor may be combined directly with a distillation column by distilling off the light component product in order to increase the reactor temperature or to improve the product yield of an equilibrium reaction. The same amount of the light product should be removed as the amount being formed by the reaction at any time. A linearized model has been developed which describes the process behaviour satisfactorily for control analysis purposes. The controllability of a combined batch reactor/batch distillation column is found to depend strongly on the operating conditions and on the time during the run. In general, controlling only the reactor temperature (one-point bottom control) is difficult since the set-point has to be specified below a maximum value in order to avoid break-through of an intermediate component in the ditillate. This maximum value may be difficult to know a priori. For the example considered in this study, control of both reactor temperature and distillate composition (two-point control) is also found to be difficult due to large interactions in the column. As with one-point bottom control, the reactor temperature has to be specified below a maximum value. However, energy can be saved since the heat duty can be decreased with time. Controlling the temperature on a tray in the column (one-point column control) is found to give good performance for the given process with no loss of reactant and a high reactor temperature, although no direct control of the reactor temperature is obtained. 相似文献
88.
María P. Albano Liliana B. Garrido 《Journal of Materials Synthesis and Processing》2002,10(4):211-218
Si3N4powders coated with 6 wt% Y2O3and 4 wt% Al2O3were prepared by coprecipitation. The resulting powders were dispersed in water at different pH values and with addition of various amounts of ammonium polyacrylate (NH4PA) to produce 32 vol% slips. The influence of the amount of NH4PA solution added and pH on the rheological properties of 32 vol% coated Si3N4slips were studied. In addition, the sintered density of cast samples was determined and related to the degree of slip dispersion. The adsorption of the NH4PA on the coated particle surface was rather high and the surface became saturated near 0.86 mg/m2at pH 9.2. High NH4PA concentrations (1.7–3 wt%) were necessary to obtain well dispersed 32 vol% coated Si3N4slips at pH 9.2. The best stabilization was obtained with the addition of 2.3 wt% NH4PA; in this condition, the viscosity reached a minimum value of 35 mPa.s at 100 s–1. The slip viscosity increased with increasing pH from 9.2 to 10.2. Slips with low viscosities gave a more dense packing of cast samples and consequently higher sintered density values. 相似文献
89.
90.