全文获取类型
收费全文 | 11654篇 |
免费 | 1501篇 |
国内免费 | 546篇 |
专业分类
电工技术 | 268篇 |
技术理论 | 1篇 |
综合类 | 788篇 |
化学工业 | 3023篇 |
金属工艺 | 1241篇 |
机械仪表 | 245篇 |
建筑科学 | 741篇 |
矿业工程 | 2275篇 |
能源动力 | 235篇 |
轻工业 | 803篇 |
水利工程 | 73篇 |
石油天然气 | 786篇 |
武器工业 | 26篇 |
无线电 | 306篇 |
一般工业技术 | 1006篇 |
冶金工业 | 1679篇 |
原子能技术 | 101篇 |
自动化技术 | 104篇 |
出版年
2024年 | 58篇 |
2023年 | 180篇 |
2022年 | 319篇 |
2021年 | 404篇 |
2020年 | 453篇 |
2019年 | 333篇 |
2018年 | 366篇 |
2017年 | 432篇 |
2016年 | 441篇 |
2015年 | 505篇 |
2014年 | 548篇 |
2013年 | 640篇 |
2012年 | 731篇 |
2011年 | 812篇 |
2010年 | 622篇 |
2009年 | 585篇 |
2008年 | 502篇 |
2007年 | 750篇 |
2006年 | 704篇 |
2005年 | 623篇 |
2004年 | 509篇 |
2003年 | 457篇 |
2002年 | 401篇 |
2001年 | 384篇 |
2000年 | 336篇 |
1999年 | 308篇 |
1998年 | 250篇 |
1997年 | 173篇 |
1996年 | 144篇 |
1995年 | 130篇 |
1994年 | 116篇 |
1993年 | 78篇 |
1992年 | 89篇 |
1991年 | 72篇 |
1990年 | 58篇 |
1989年 | 38篇 |
1988年 | 23篇 |
1987年 | 14篇 |
1986年 | 16篇 |
1985年 | 17篇 |
1984年 | 18篇 |
1983年 | 15篇 |
1982年 | 13篇 |
1981年 | 11篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1975年 | 4篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
72.
In this work, magnesia from natural brucite mineral has been used firstly for catalytic degradation of nitrobenzene and aniline
in presence of ozone. Compared with single ozonation, the catalytic ozonation accelerated markedly the degradation of nitrobenzene
and aniline. The influences of hydroxyl radical scavengers, pH values, and reaction temperatures on degradation were investigated.
It was found that the essential of catalysis was the homogeneous catalysis of hydroxyl ions in water, which accelerated the
generation of hydroxyl radicals. As a catalyst, magnesia from natural brucite has supplied an economical and feasible choice
for catalytic ozonation of nitrobenzene and aniline in industrial wastewater. 相似文献
73.
矿物材料化学加工与合成的研究现状和发展方向 总被引:1,自引:0,他引:1
从以矿物原料直接制备矿物材料、矿物材料的化学改性、特殊功能粉体的合成及粉体材料合成中新技术手段的应用等方面,论述了矿物粉体材料的研究进展。聚合物/黏土纳米复合材料,由于其特殊的功能,成为矿物材料改性的新方向;特殊功能粉体赋予材料许多优越的性能,其开发和研究已成为热点,特别是在电池材料、抛光材料、生物材料的研究方面;学科交叉为材料研制带来了又一次兴起,超声波、机械化学、微波和微波等离子体,由于其特殊的功效,解决了粉体制备过程中许多难题。新方法和技术所制得材料具有优越性能和特殊功能。 相似文献
74.
75.
Francisco Salmerón-Miranda Birgitta Båth Henrik Eckersten Johannes Forkman Maria Wivstad 《Nutrient Cycling in Agroecosystems》2007,79(2):125-139
The main objective of this field study was to estimate the total plant uptake of soil mineral N in maize (Zea mays L.) and common bean (Phaseolus vulgaris L.) grown in crop rotations under different N content in Nicaragua. Secondary objectives were to estimate the fraction of
the measured soil mineral N content taken up in this way, and to determine how the measured N in plant aboveground parts was
related to the total mineral N uptake. A large variation in N content was obtained by using data from fertilisation experiments.
Plant total N uptake was estimated as the residual N in a mass balance calculation of soil mineral N. Mineral N content in
the top 0–0.3 m soil layer in the field cultivations and in tubes isolated from root uptake, and N content in aboveground
plant parts were measured every 30 days. Estimated plant total uptake of soil mineral N varied considerably (2.5–14 g N m−2 30 day−1) over periods and N treatments. The range of variation was similar for maize and bean. The fraction of the soil mineral N
that was taken up by the plant daily varied more in maize (about 0.03–0.12 day−1) than in bean (about 0.05–0.08 day−1). Our results suggest that monthly changes in N in aboveground plant parts were linearly related to plant total N uptake
during the same period. Aboveground plant N constituted between about 55% and 80% of total uptake of soil mineral N in maize
depending on period within season, whereas for bean it was more constant and smaller (about 40%). 相似文献
76.
Fluorine-graphite intercalation compounds have been synthesized using high purity fluorine gas and high oxidation-state transition-metal fluorides, AgF3 and NiF3, at room temperature and at −78 °C. At room temperature, a mixture of stage 1 + 2 − 4 compounds with compositions, C4.2F to C14.6F were obtained. On the other hand, stage 2–4 compounds with compositions C5.6F to C14.2F were synthesized at −78 °C. The fluorinating ability of AgF3 and NiF3 has been shown more clearly at room temperature because a small amount of fluorine was intercalated/absorbed into graphite at −78 °C without catalysts. XPS spectra show that ionic, nearly ionic, semi-covalent and covalent fluorines coexist in the CxF samples, and that the covalency of CF bonding increases with decreasing stage number. 相似文献
77.
Lucian M. Rusnac Octavian Floarea Radu V. Vladea 《Journal of the American Oil Chemists' Society》1992,69(4):384-386
Continuous hydrogenation of industrially refined soybean oil with Harshaw Ni catalyst was achieved in a slurry column equipped
with Sulzer SMV motionless mixers. The influence of the operating parameters (temperature, pressure, catalyst concentration
and gas velocity) was investigated. The presumption that, in this equipment, the liquid-solid mass transfer limits the rate
of the process is in good agreement with the experimental data. 相似文献
78.
79.
It is shown that strongly basic anion exchangers AV‐17 and Varion‐AD in definite conditions are able to retain Cr(III)‐containing ions from Cr(III) sulfate solution. It is found that the sorption of Cr(III)‐containing ions on the polymers is essentially dependent on the pH, temperature, and Cr(III) sulfate concentration. The maximum temperature dependence of sorption was found to be about 60°C. The sorption isotherms are well described by Langmuir's equations. The sorption kinetics is determined by the diffusion of Cr(III)‐containing ions into polymer's phase. It is assumed that the Cr(III)‐containing ions are retained through formation, in polymer's phase, of the jarosite‐type mineral compounds: R4N[Cr3(OH)6(SO4)2], H3O[Cr3(OH)6(SO4)2], and K[Cr3(OH)6(SO4)2]. For comparison of sorptional capacities, the sorption of Cr(III)‐containing ions was determined on different cation and anion exchangers. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3978–3985, 2006 相似文献
80.
纳米级氢氧化镍制备及电化学性能研究 总被引:1,自引:0,他引:1
介绍了一种通过合成草酸镍,进而生成β型纳米氢氧化镍的新的合成路线,从而达到大幅度提高镍氢电池正极放电容量的目的。使用X射线衍射(XRD)分析产品的晶型结构。从产品谱图中可以得知:由于特征衍射峰的出现可以判定该产品为β型,且由于(001)峰的宽化可以初步判定其为纳米级。通过透射电镜(TEM)可以看出产品粒径和形貌的具体特征,即产品为针状,长度为100~200 nm,直径为10~20 nm。将纳米级氢氧化镍制成电极,经过充放电测试可以发现电容量约为400 mA.h/g,远远高于球形微米级氢氧化镍的放电容量。 相似文献