Relationship of structure and enhanced photocatalytic activity of S-scheme BiOCl/g-C3N4 heterojunction for xanthate removal under visible light

Constructing heterojunctions is an excellent way to enhance the photocatalytic property of semiconductors. Herein, a range of S-scheme BiOCl/g-C₃N₄ heterojunctions with varying mass ratios were designed using a facile hydrothermal route, and their photocatalytic ability was assessed by degrading the ethyl xanthate (EX) under visible light (λ > 400 nm). The results showed that the degradation efficiency of BiOCl/g-C₃N₄-0.1 heterojunction for EX was up to 91.2 % within 180 min, and its apparent rate constants (K_app) were 4.3 and 11 times greater than those of BiOCl and g-C₃N₄, respectively. The experimental and characterization results revealed that the excellent photocatalytic property was ascribed to the construction of S-scheme heterojunctions. Such structure not only enhanced the visible light response but also facilitated the efficient separation of photoinduced carriers with the S-scheme transfer route, retaining strong redox-capable holes and electrons to participate in surface reactions. Furthermore, the cycling experiments indicated that the fabricated photocatalysts have great recyclability and stability. Based on the results of active substance capture, the S-scheme charge transfer model was proposed and the photodegradation mechanism of EX was reasonably elucidated. Overall, this work offers some theoretical direction for the design and construction of S-scheme heterojunctions with superior visible-light-driven photocatalytic performance.     

Identification and quantification of different vapours using a single polymer chemoresistor and the novel dual transient temperature modulation technique

This paper presents a novel signal processing technique for a square wave temperature modulated carbon black/polymer composite sensor. The technique consists of only two mathematical operations: summing the off- and on-transients of the conductance signals, and subtracting the steady-state conductance signal. The technique has been verified through its application to a carbon black/polyvinylpyrrolidone composite chemoresistor. Identification of water, methanol and ethanol vapours was successfully demonstrated using the peak time of the resultant curves. Furthermore, quantification of those vapours was found to be possible using the height of the peak heights, which was linearly proportional to concentration. The technique does not require zero-gas calibration and thus is superior to previously reported techniques.     

两性田菁胶在处理高浓度印染废水中的应用

研究了以聚合硫酸铁(PFS)为主凝剂、两性田菁胶(ASG)为助凝剂处理高浓度印染废水的各种影响因素。实验结果表明：PFS和ASG分别以2000mg／L和100mg／L的复配浓度、pH值接近中性时混凝效果为最佳，CODCr去除率达到80％，色度与浊度去除率均达99％以上。     

三唑类化合物分子结构与防治小麦锈病活性关系的研究

本文用多元线性回归分析、逐步线性回归分析、主成分回归分析和偏最小二乘分析方法研究了三唑类化合物结构与防治小麦锈病活性的关系，并建立了构效关系式。对该系列化合物结构的变化对其生物性的影响作了一定的探讨。提出了设计高活性化合物的可能结构要求，并将研究结果用于实际化合物的设计中，取得了初步结果。     

A New Grade Carbon Black Produced by Thermal Plasma Process

This paper presents a new route about producing carbon black,by wich the natural gas cracking is carried out in the absence of oxygen thanks to an electric energy supply externally given by a plasma jet.The carbon black produced by this process has a narrow size distribution and a small average diameter of 38nm as well as a highly branched aggregate.The higher DBP value of 1.40ml/g shows it should be a high structure carbon black.The FTIR spectra shows that there are lots of aromatic c-c bonds and a large amount of nitrogen-coutaining functional groups on the carbon blacks surface,such as-NH,-CN as we3ll as -CH,-OH,-COOH groups.     

超滤膜法城市污水深度处理中水回用中试试验研究

以高碑店污水处理厂二级出水为处理对象，建立日产中水500t的超滤中试试验装置，研究膜法城市污水深度处理中水回用的工艺和操作条件，考察所能达到的技术经济指标，掌握放大规律，为万吨级工业装置和系统的设计提供基础数据．试验装置连续运行了约2500h，膜性能稳定，产水水质达到生活杂用水标准(CJ．25．1—89)。     

中空纤维膜无泡供氧过程的传质性能研究

使用中空纤维膜向液相系统中供氧时，无肉眼可见的气泡产生．与传统的泡式供氧相比，这种新颖的膜式无泡供氧具有传氧效率高、无泡沫产生和能耗低等优点，特别适宜应用于发酵、活性污泥废水处理和动物细胞培养等生物反应和人工控制的生命过程中．本文对中空纤维膜无泡供氧过程的传质机理、传质阻力、传质方程和影响传质系数的操作参数等传质性能进行深入探讨，并提出了“边界层压缩”模型，以解释在无泡供养中传质系数随压力变化的原因．     

黑体空腔式中间包钢水连续测温系统与应用

描述了黑体空腔式钢水连续测温系统的理论基础、结构原理、校验方法、测试结果分析和现场应用情况。该测温系统的测温偏差≤±3℃,测温管寿命可达15～25h(取决于钢种和工艺等),测温成本比现行的快速热电偶实际消耗略低,系统运行稳定可靠,并取得显著的综合效益。