一种有机硫类絮凝剂DTC的合成及性能评价

讨论了由有机伯胺或仲胺和CS2合成二硫代氨基甲酸盐DTC的反应及副反应,简介了合成工艺。根据红外光谱确认了由三乙烯四胺合成的二硫代氨基甲酸盐（以下简称DTC）的结构。以含原油350 mg/L、含悬浮固体55.1 mg/L,含Fe^2＋10.0 mg/L的模拟污水为实验水样,考察了该DTC的絮凝性能,在40℃、pH=6-7、沉降时间30分钟条件下DTC的适宜加量为20 mg/L,此时污水含油量为9.0 mg/L;使用DTC的适宜pH范围在4-8,pH=6为最佳值,适宜温度范围为10-45℃,温度高于45℃时DTC可发生热分解;DTC的除油效果随污水中Fe^2＋浓度增大而改善。在含油89.1 mg/L、含悬浮固体55.1 mg/L、含Fe^2＋13.2 mg/L的油田污水中,DTC的除油率最高,远高于常用絮凝剂PFS,PAC,CPAM,HPAM和PAM。当污水中不含Fe^2＋时,DTC无絮凝除油效果。讨论了DTC在Fe^2＋参与下的絮凝过程。图5表1参8。     

壳聚糖和粉煤灰对间甲酚的吸附处理

用壳聚糖和粉煤灰对含间甲酚的废水进行吸附处理,考察了壳聚糖的用量、振荡时间、振荡速度以及粉煤灰与壳聚糖的混合比对处理效果的影响.结果表明:在常温下,对于初始质量浓度为56 mg/L的间甲酚,当壳聚糖用量为3 g/L,以170 r/min的转速吸附振荡0.5 h,去除率可达到88%以上;在上述条件下,加入质量比4:1的粉煤灰与壳聚糖混合物5g/L时,间甲酚的去除率可达到91%.     

高效铣环在胜科1井事故处理中的应用

胜科1井是中国石化的一口重点科学探井,在钻至井深5001m时因井眼缩径发生了卡钻事故。由于井底存在直翼扩大器、PDC钻头等含有硬质合金的落鱼,普通铣鞋无法完成套铣打捞作业,为此,专门设计了一种高效铣环。该铣环的切削元件选用了一种硬度达93.2 HRA的钛合金,经铣槽镶焊在本体上;本体选用了40CrNiMo厚壁管材,并进行了调质处理;连接螺纹选用了双级梯形同步螺纹。在胜科1井的应用表明：切削元件的强度满足了切削扩大器切削翼和PDC钻头胎体的需要,其齿形、布齿方向和出刃高度设计合理,提高了切削速度;本体性能高,切削元件焊接性能较好;双级梯形同步螺纹有效增加了连接部位的强度,具有较高的上扣扭矩,承受冲击载荷能力强。高效铣环在该井的成功应用,为今后同类型井的事故处理提供了借鉴。     

高青樊107联合站污水处理技术应用研究

根据胜利油田樊107区块低渗透油藏注水开发的需要，开展了高青樊107联合站污水处理技术研究，与辽宁华孚环境工程‘有限公司联合研发了一套适合樊107区块注水水质指标的污水处理工艺设备。结合高青樊107区块的地质特点、注水水质指标要求，介绍污水处理室内试验研究、工艺流程、工艺设备选型、现场试验、存在问题和整改措施。     

胜科1井钻井事故的预防与处理

胜科1井设计井深7 000 m,完钻井深7 026 m。在该井钻井过程中,针对上部大尺寸钻头破岩效率低、大井眼井壁稳定性差、大段盐膏层、膏岩层的塑性蠕变和塑性流动造成井眼复杂、超深井高温高压给钻井液性能的控制和水泥浆调控等带来的一系列技术难题,制定了一整套预防井下事故和复杂情况的技术措施,从而确保了该井的钻探成功。该井在钻井过程发生了2次断钻具事故和1次卡钻事故,根据超深井的特点,采取了较为稳妥的处理措施,同时,有针对性地研制了高效铣环和PDC钻头专用打捞器,3次事故处理均获得了成功,共耗时38.5 d。详细介绍了该井所采取的预防和处理钻井事故的技术措施,可为其他超深井的钻井施工提供一定的借鉴。     

Influence of the Preheat Treatment on the Microstructure and Properties of X37CrMoV5-1 Steel

The technological properties of the hot-work tool steels depend on their microstructural quality induced by the production process and the heat treatment. One of the frequently applied methods to improve microstructure is preheat treatment. The treatment of carbonitriding X37CrMoV5-1 steel has been investigated in fluidized bed furnaces. Thickness and phase composition have been conducted using optical microscopy Neophot 32 and scanning microscopy, JEOL 5400, after etching in nital.     

节能降耗提高矿山效益

节能降耗是每一个矿山提高经济效益的有效途径。我们采取提高球磨机处理能力，降低单耗；利用“分时计价”政策，采用“避峰作业”；使用新设备等措施节能降耗，提高矿山经济效益。     

论普通型胶辊表面不处理的合理工艺参数

论述了普通胶辊表面不处理的性能特点和存在问题，技术措施和合理工艺参数，提高了成纱条干水平，减少缠绕和磨损。     

化学成分和固溶温度对1Cr17Mn9Ni4N不锈钢组织和性能的影响

为提高1Crl7Mn9Ni4N钢固溶处理后的力学性能(特别是钢的强度)，研究了化学成分及固溶处理温度对其组织和性能的影响。结果表明，1000—1125℃固溶处理后，该钢的组织为单相奥氏体。在标准成分范围内，随着镍、锰含量的增加，该钢的强度降低，塑性有所改善。氮明显提高该钢的强度。根据试验结果，每增加0．01％的氮钢的室温强度可提高大约5MPa，且塑性基本上不受影响。当合金成分(质量分数，％)控制在C0．08—0．12、Crl6．5—17．5、Ni3．5—4．2、Mn8．0—9．0、N0．22—0．28时，1Crl7Mn9Ni4N钢经1050—1100℃固溶处理后强度较高、塑性好，室温强度σ0．2和σb可分别达到400MPa和800MPa。     

Intensive filial therapy with child witnesses of domestic violence: A comparison with individual and sibling group play therapy.

The rationale for utilizing filial therapy as a treatment intervention with child witnesses of domestic violence while residing with their mothers in a shelter facility is explored and the effectiveness of an intensive 12-session filial therapy parent training group, conducted within 2-3 weeks, is described (n=11; aged 4-10 yrs). Results of analysis of covariance revealed that child witnesses in the experimental group significantly reduced behavior problems prevalent in child witnesses and significantly increased their self-concept as compared to child witnesses in the non-treatment comparison group. In addition, t-test results showed that mothers who facilitated treatment of the experimental group scored significantly higher after training on both their attitudes of acceptance and their empathic behavior. Comparative analysis revealed that intensive filial therapy as facilitated by the children's mothers was as effective in reducing behavior problems as was intensive individual play therapy and intensive sibling group play therapy as facilitated by professionally trained therapists. (PsycINFO Database Record (c) 2010 APA, all rights reserved)