The evaluation of the polarization resistance in a tubular electrode and its application to the hydrogen electrode reaction

An alternative method for the determination of the kinetic parameters involved in the elementary steps of the reaction mechanism of the hydrogen electrode reaction is proposed. It is based on the determination of the variation of the polarization resistance in a tubular platinum electrode with a laminar flow of electrolyte as a function of the activity of protons of the electrolyte solution. A theoretical expression that relates the experimental variables and the equilibrium polarization resistance is developed, which takes into account the current distribution along the electrode surface. The results are compared with others obtained previously, contributing to the verification of the kinetic mechanism through a completely different experimental procedure.     

基于ARM的便携式电机参数实时监测仪设计

针对三相电机参数监测问题,基于AT91SAM9261微处理器和嵌入式实时操作系统VxWorks,设计了一套便携式电机参数监测仪。监测仪以ATT7022B电能测量芯片和鉴相计数单元为核心,对三相电机的工作电压、电流及电机的转速转向参数进行实时监测与故障报警,并能在联网模式下通过以太网与上层监控主机通信,实现远程参数监测和多电机联网测量,保证系统安全的同时方便了伺服系统调试。     

基于光电和倾角检测的全天候太阳跟踪传感器设计

为提高双轴太阳跟踪系统的跟踪精度,设计了一种全天候太阳跟踪传感器。该传感器主要由外壳、接口电缆、9个光电探头、倾角传感器SCA100T—D02及相应电路组成。晴天时通过光电探头检测太阳的位置,阴雨天气时通过SCA100T—D02实时反馈太阳能电池板转动后的倾角,以修正和消除太阳跟踪系统进行视日运动轨迹跟踪时的机械误差。通过理论分析计算,确定了光敏电阻器在探头中的安装位置,传感器可感知高度角在-88.83°~88.83°范围内的太阳入射光线。经试验测试,传感器的倾角检测的最大相对误差为3.8%,能满足实际应用要求。     

并联式混合动力汽车模糊控制策略及优化研究

能源危机和环境污染是汽车工业的两大挑战,提高发动机的运行效率是关键。在建立发动机模型及电池SOC(state of charge)计算模型的基础上对并联式混合动力汽车(PHEV,parallel hybrid electric vehicle)的控制策略进行研究,设计了模糊控制策略来合理分配发动机、电机的输出转矩。并在此基础上,对传动系统参数进行优化,得到满足PHEV加速和爬坡性能的最小废气排放的传动系统参数。最后,对设计的模糊控制策略进行仿真,并与参数优化后的模糊控制策略进行对比。结果表明传动系统参数优化后,燃油经济性有所提高。     

水热合成法制备纳米TiO2晶须的表征及工艺研究

本文以TiCl4为原料，采用水热合成法制备金红石型纳米TiO2晶须，通过TEM和XRD对所制备的纳米TiO2晶须进行表征，确定了主要工艺参数。     

循环灰条件下1-甲基萘催化裂解的实验研究

热解气化过程中 ,促进焦油的裂解使之转化为高热值煤气 ,对高挥发分劣质煤和生物质燃料的清洁高效利用具有重要的意义 .在固定床反应器上 ,以石英砂和两种烟煤在循环流化床锅炉上燃烧形成的循环灰为床料 ,实验研究了焦油中含量较高的 1 -甲基萘的裂解反应 ,测定了反应动力学参数 .结果表明 ,与石英砂条件下相比 ,循环灰促进了 1 -甲基萘的裂解 ,反应活化能降低 ,裂解气体的总产率提高     

工艺参数对陶瓷注射成型的影响与分析

本研究通过改变注射温度，注射压力，保压压力等几个主要参数，对形状，体积不同的注射成型体，试条，圆柱及子部件进行了一系列注射工艺实验。相应地对成型体的密度，弯曲强度及烧结体的密度和强度进行测量，并从陶瓷注射成型混合物的流动行为，热物理特性方面对注射这一复杂过程进行分析，探讨工艺参数对成型过程的内在影响，从而确定合理的注射工艺条件。     

Kinetic study on the first stage during thermal degradation of polystyrene

The kinetic parameters of the first stage of polystyrene degradation have been investigated to elucidate the reaction mechanisms using the flow reactor system. The decrease in molecular weight of polystyrene was recorded at minute intervals over the temperature range 310°–390°C. Generally, the first and second stages were observed by thermogravimetric analysis (t.g.a.), however in the early stage of the degradation volatile yields of at least 5% occurred. Therefore, using t.g.a. analysis it is difficult to detect this earlier stage. It became evident that the first stage in the earlier part of the reaction could be detected by g.p.c. analysis. We have observed the hidden kinetic parameters of the nature of the first stage of the polystyrene degradation. The results indicate that the main chains were degraded randomly with the small quantitative volatile groups in the first stage and the rates of decrease in molecular weight in the first stage against reaction temperatures were evaluated as log k_s = 12.0 ? 41300/RT.     

考虑边界反射的河流离岸排放污染混合区计算方法

在等强度点源离岸排放条件下,从简化二维移流扩散方程的解析解出发,探讨了考虑两岸反射作用的中宽河流污染混合区的计算方法。给出了污染混合区边界形状曲线与量纲一方程的形式;采用迭代计算和试算比较法,给出了靠岸与离岸两种类型混合区各几何特征参数(坐标)、面积及面积系数与相对离岸距离的关系曲线,提出了以相对离岸距离a'作为判据的排放类型分区条件。给出了河流岸边、离岸与中心排放的分类判别准则:(1)当0≤a'≤a'1时,简化为岸边(近岸)排放类型;(2)当a'1a'a'2时,称为离岸排放类型;(3)当a'2≤a'≤0.5时,简化为中心排放类型,并给出了岸边排放类型与离岸排放类型的临界相对离岸距离a'1和中心排放类型与离岸排放类型的临界相对离岸距离a'2的表达式。通过回归分析,给出了中宽河流离岸排放类型混合区主要特征参数的实用计算公式,可作为中宽河流污染混合区范围计算和排污口位置优化设计的依据。