Effect of pickling process on removal of oxide layer on the surface of ferritic stainless steel

Oxide layer formed on stainless steel surface can result in a decrease in surface quality. Thus, it must be removed. In this paper, we investigated the effect of different pickling processes on removal of the oxide layer. Ferritic stainless steel was used as raw material. After it received annealing treatment, the components and structure of the oxide layer formed on its surface were studied. Then, the annealed stainless steel was pickled in hydrochloric acid solution system and mixed acid solution system, respectively. Results are as follows. The oxide layer on stainless steel surface has a thickness of 15–35?μm. With increase in hydrochloric acid concentration in hydrochloric acid pickling solution, the weight loss rate of stainless steel increases and is always greater than that in mixed acid pickling system. In addition, the surface of the stainless steel pickled in hydrochloric acid is smoother than that pickled in mixed acid. Furthermore, compared with channels in the oxide layer created during mixed acid pickling, those created during hydrochloric acid pickling are more, leading to shorter removal time. These results are important for increasing the pickling efficiency and improving the surface quality of stainless steel.     

Continuous reduction of the oxide scale of hot-rolled steel strip in hydrogen

The continuous reduction in the oxide scale of hot-rolled steel strip in H₂–N₂ atmosphere was simulated in laboratory. Scale specimens were reduced in 20% H₂–N₂ or 50% H₂–N₂ atmosphere. The sample weight losses were measured after soaking at 550, 700 and 800°C. In both atmospheres, specimen reduced at 700°C showed the minimum weight loss after soaking for 240?s. At 700 and 800°C, higher hydrogen concentration accelerated the reaction in the beginning of soaking, but had little effect once the dense-reduced iron layer formed. While at 550°C, the reduced iron kept growing in porous structure and the weight loss rate increased significantly in higher H₂ concentration.     

多功能酸洗缓蚀剂缓蚀效果的研究

对威海翔宇环保科技股份有限公司研发的多功能酸洗缓蚀剂进行了盐酸酸洗、H_2SO_4酸洗、硝酸酸洗缓蚀实验,实验结果表明,多功能酸洗缓蚀剂在盐酸酸洗、H2SO4酸洗、硝酸酸洗过程中对碳钢、16mn钢都有很好的缓蚀效果,加药浓度不同,缓蚀效果不同。多功能酸洗缓蚀剂的加药浓度一般在3‰~5‰,10%的盐酸酸洗的缓蚀率可达到98.8%、10%的H_2SO_4酸洗的缓蚀率可达到99.8%、10%的硝酸酸洗的缓蚀率可达到77%以上。     

几种钢材表面的少酸化除鳞设备

长期以来多采用酸洗技术对热轧板、卷和浸镀件等表面进行除鳞处理,这一方面会降低产品的表面质量和性能;另一方面会对操作人员和设备造成损害且污染环境。随着国家对环境保护的重视,国内外均对除鳞工艺进行了研究,探索最新的技术和工艺。综合以往的研究,介绍了几种钢材表面的少酸除鳞技术,以及SCS、EPS、GSPS无酸除鳞技术,指出除鳞工艺的发展方向为少酸或无酸的机械式处理工艺和以磷酸代替盐酸的新工艺。     

热轧酸洗商品卷生产工艺选型

本文介绍了热轧酸洗商品卷的产品特点及应用,分析了连续酸洗、推拉酸洗以及无酸酸洗三类典型热轧酸洗生产工艺的生产特点、产品规格、技术参数以及应用场景。通过对以上三种生产工艺的分析和比较,可对今后热轧酸洗生产工艺选型提供参考,钢铁企业可以根据自身热轧原料、产品定位、资金状况等情况进行生产工艺选型。     

钢材酸洗废液资源化与无害化技术

钢材酸洗废液是国内产量较大的危险废物之一。作者对近年来国内酸洗废液综合利用及处理技术的研究成果作了回顾与分析，根据生产实践反映出来的问题，指出开发具有资源化与无害化酸洗废液处理新技术是必要的．同时提出深化研究及开发新技术中需要着重考虑的问题。为得到更多的经济及环境效益，尤其是在工艺的灵活性以及提高产品附加值等方面需要进一步深化。     

邯钢光伏支架用热镀锌S390GD(S450GD)+Z产品的开发

环保节能领域光伏支架用有锌花镀锌产品是邯钢市场开发的重点,但用户对其表面质量、力学性能、耐蚀性能和变形延展性有较高的要求。从热轧备料,酸洗工艺,热镀锌退火温度及锌层控制等方面阐述了开发光伏支架用热镀锌S390GD(S450GD)+Z产品的质量保证措施。通过降C、增Mn的化学成分设计,板坯出炉温度1 100～1 150℃、粗轧压下率40%～45%、终轧温度(850±20)℃、卷取温度降至(580±20)℃ 的热轧工艺优化,保证了热轧原料强度。通过酸液温度、酸洗速度、缓蚀剂添加量的优化,以及热镀锌退火温度、锌液成分的优化改进,实现了锌花结晶均匀性控制,产品质量满足用户要求。     

钢铁材料表面酸洗清洁生产展望

随着现代工业的发展,钢铁构件的需求日益增大。钢铁构件由于自身表面性质活跃,在加工、运输及储存过程中不可避免地形成锈蚀层。钢铁材料的锈蚀既对材料的使用性能及寿命造成不良影响,又导致材料的巨大浪费。为了提高钢铁构件的使用性能及寿命,需要进行表面处理及防护,但处理之前必须清除表面锈蚀层。工业酸洗是清除锈蚀层的重要方法之一,由于酸洗液腐蚀性强,在钢铁材料表面锈蚀层溶解后,不可避免地存在着“过酸洗”的现象,由此引起钢铁材料的浪费及产生过多的污染物,如酸雾和酸洗废液等。分析了钢铁材料表面酸洗污染物产生的源头,并从“缓蚀剂添加、工艺参数选择、酸洗设备改进”等3个因素,总结了提高工业酸洗清洁生产水平的策略,分析了相关的影响因素,提出以“源头控污”为核心的酸洗清洁生产的概念,最后指出了提高酸洗清洁生产水平所需要考虑的问题。     

冷轧薄板连续酸洗线的活套分析

对唐山钢铁股份有限公司冷轧薄板厂连续酸洗线的活套储量、带钢运行速度和时间的变化规律进行了详细分析和合理设定，确保了带钢酸洗生产能以较高速度连续运行。     

酸洗过程中的缓蚀剂

通过对近十年来酸洗缓蚀剂的研究工作的介绍与分析,结合清洁生产的要求及定量化计算数据,明确指出酸洗缓蚀剂在酸洗废液减量化的意义,并对进一步研究与开发绿色酸洗缓蚀剂提出值得重视的几个问题。