用φ20mm离心萃取器两步法制取高纯钇

本文研究了中钇富镧稀土的氧化物溶液在环烷酸中的萃取行为，测定了镧钇组成、温度变化与分离系数的关系；在Ｐ＿（５０７）体系中研究了ｐＨ值与分配比的关系；提出用环烷酸、Ｐ＿（５０７）两种萃取剂制备高纯钇的工艺流程。用８４台φ２０ｍｍ离心萃取器进行了一个月的台架试验，结果证明两种萃取剂有很好的互补性，在满足钇的纯度要求下有较高收率。离心萃取器具有易分相、体系存留量少、液流密闭性好等优点，它更适宜于粘度大、级数多、产品纯度要求高的体系。     

稀土混合物水溶液中囊泡的形成

依据柠檬酸的螯合作用和乙二醇的空间位阻效应，获得了稀土混合物囊泡。并利用ＩＣＰ、ＴＥＭ、ＦＳ等仪器对囊泡的性能进行了研究，最后对囊泡的形成机理进行了讨论。     

型煤发展的回顾与展望

煤炭科学研究总院建院以来型煤研究工作的进展状况、主要成果,并对几项工业型煤技术进行了概述和评价,还对今后型煤研究方向提出了建议。     

WTG420铁路罐车用钢的组织结构和力学性能分析

分析了ＷＴＧ４２０铁路罐车用钢的组织结构和力学性能。提出了冶炼与轧制的技术关键，其一，添加稀土元素改善钢中夹杂物；其二，采用控轧控冷使铁素体晶粒细化。     

焦化防砂室内实验研究

油井防砂工艺技术的研究与发展对疏松砂岩油藏的正常开采至关重要.焦化防砂是通过向地层内注入热空气使原油在高温下发生氧化裂解生成焦炭从而将地层砂固结的一种防砂新技术.为了对该项技术进行全面系统的理论分析与评价,设计并制作了一套焦化防砂实验装置,利用该装置进行了焦化防砂室内实验研究.焦化效果以岩样的抗压强度进行评价,实验结果表明,影响焦化后岩样抗压强度的主要因素为空气最高温度、处理时间和空气流量.此外,对焦化处理后的岩样所作的岩样组成分析揭示出,稠油胶结机理为氧化作用使部分油分和胶质变成沥青质,沥青质受到高度的缩合作用而成为高分子量的甲苯不溶物.由于新生胶质的氧化比原生胶质的氧化困难得多,因此适合焦化防砂的油层,其原油必须含有一定量的原生胶质和沥青质.     

脱苯工艺的节能改造

焦化厂富油脱苯工艺中，管式炉法较蒸汽法节能。本溪钢铁公司焦化厂产焦１８０万ｔ／ａ的装置，其富油脱苯工艺由蒸汽法改为管式炉法后，每年可节煤７０００ｔ。     

Modified oil agglomeration process for coal beneficiation. III. Grinding and agglomeration using different szego mill designs

The simultaneous grinding/agglormeration process has been used to beneficiate Minto coal. Experiments with the Szego Mill, a planetary ring-roller mill with grooved rollers, have given good results. Different roller ridge/groove sizes have been tested and favourable oil-coal-water ratios established. Ash removal is closely related to grinding performance. Very short mill residence times, of the order of 10 seconds, are sufficient for microagglomerate formation. Considerable equipment and operating cost savings are possible with the modified process.     

Chemical States of Lanthanum in Carbonized La2O3-Mo Thermionic Cathode Materials

The chemical reaction between lanthanum oxide and molybdenum carbide was studied by thermodynamic calcu-lation, thermal analysis and in-situ X-ray Photoelectron Spectroscopy. The theoretical results show that at the environment allowing for the evaporation of lanthanum, such as in high vacuum, La2O3 in the La2O3-Mo materials can be reduced to metallic lanthanum by molybdenum carbide (Mo2C). To confirm the conclusion, many analysis methods such as XRD, SPS, and TG-DTA were taken. The experimental results show that the chemical state of lanthanum changes during heat-ing. It was proved, for the first time, that reacted metallic lanthanum appears at the surface of this kind of material at high temperature.     

铸型尼龙改性的研究进展

铸型尼龙产品广泛地用于各种机械零件，改性后的铸型尼龙，可克服其自身的缺点，满足工业应用的要求。文章就我国近年来在铸型尼龙改性研究方面的情况及不同的改性方法做了详细的介绍。     

Influence of Lanthanum on Fluorescence Properties of Ag-BaO Thin Films

Ag-BaO thin films doped with lanthanum were prepared by vacuum deposition. Compared with the normal Ag-BaO thin film, there is almost no change with the shape and the peak site of the fluorescence spectrum; however, fluores-cence emission strength of the whole observation band(325 -600 nm)increases about 40%, and the increase of short wavelength range is more remarkable than that of long wavelength range, which we named “blue-stronger“ phenomenon. Analytic results show that, with the forming of intermetallic compounds between silver and lanthanum, the 4f-state energy levels lie just below the Fermi level within 5 eV. It is the energy exchange between the 4f energy levels and the conduction band that causes the increase effect of fluorescence emission, and it is the optical absorption cross section of 4f electron, which increases with the increase of energy of incidence photon, that gives rise to the “blue-stronger“ phenomenon.