Influence of volatile matter and deposited carbon on coke yield from coals

The relations between coke yields and the volatile matter content of 30 individual and 30 blended coals were investigated. Coke yields and deposited carbon related to volatile matter content can be expressed in the following equations: CY (%) = 97.89?0.86 VMch+VMc; and DC (%)= ?2.24+0.16 VMch; where: CY=real coke yield; VMch = volatile matter content of charging coal; VMc=volatile matter content of coke, and in the case of <2%; DC = deposited carbon. The test results show excellent correlation with practice.     

Some aspects of the analysis of coal by X-ray fluorescence spectroscopy

Bituminous coal samples from 84 distinct sources were analysed by conventional British Standards (BS) methods for phosphorus, sulphur, chlorine, ash and the ash-forming elements (calcium, silicon, aluminium, iron, sodium, magnesium, potassium, titanium and manganese). In most cases four determinations were made per element per source. Samples were crushed to ?212 μm (72 BS mesh) and pressed into aluminium cups at 20 t in^?2 (309 MPa) without binder or backing. Two pellets from each sample were analysed by wave-length dispersive X-ray fluorescence techniques, using a spectrometer equipped with a rhodium rube; the X-ray count took 60 s. The X-ray results were calibrated against the conventional results using multiple regression. The accuracy obtained was comparable with routine ‘wet chemical’ techniques. The X-ray technique is suitable for the routine determination of large numbers of samples.     

关于煤炭硫分分级的探讨

根据国家质量技术监督局的计划安排,国家标准GB／T15224－1994《煤炭质量分级》需要修订。本文主要讨论“煤炭硫分分级”方面的内容。     

Carbonization reactions of inertinite macerals in Australian coals

Widespread disagreement about the degree of reactivity of the inertinite group of macerais is related to variations in experimental conditions of assessment and failure to appreciate technological modifications imposed on similar macerals by dissimilar source materials and depositional conditions. This has resulted in the constant under-estimation of the coking potential of post-Carboniferous inertinite-rich coals by predictive methods developed for vitrinite-rich Carboniferous coals. Coking tests up to 1000 °C have been carried out on 20 coals of different rank in such a manner that coked portions of the samples could be correlated with their uncoked equivalents. It has been found that an inverse relationship exists between the level of precarbonization reflectance (PCR) of inertinite and the reflectance and bireflectance of its coke. The increase in the latter parameter is non-linear and involves a sudden jump which is taken as the boundary between reactive (high bireflectance) and non-reactive (low bireflectance) inertinite. In relation to coal rank a reactivity field for inertinite has been delineated which can be subdivided into two areas of high and moderate reactivity, respectively. On the whole, the proportion of reactive inertinite is larger than allowed for in most petrography-based coke stability calculations.     

煤焦油加工技术的探讨

煤焦油曾为近代有机化工作出了历史性贡献。我国煤焦油资源丰富,但尚未得到有效和合理利用。根据高温煤焦油的组成特点,对煤焦油的初馏、沥青加工利用和煤焦油产品的深加工技术进行了探讨,提出一些建议。此外还讨论了煤焦油加工企业的发展模式。     

煤岩配煤技术的发展与现状

煤岩学在炼焦配煤技术上的应用,使炼焦配煤手段更有效,使焦炭质量预测在生产上应用成为可能,为定性的经验配煤技术跃变到定量的科学配煤技术创造了条件。夏皮洛煤岩配煤技术是目前较好的配煤方法,其相关系数可达0.93;国内许多学者在煤岩配煤方面也做了大量研究工作,有些相关系数达0.98。目前虽然各种方法存在一定局限性,但随着计算机和图像处理技术的发展,煤岩学在指导配煤技术方面将有新的突破。     

关于煤化工前途的思考

对煤化工存在的问题做了分析,提出加大科研投入,获取自主知识产权,解决煤化工装置大型化、国产化,坑口气化,煤层气开发利用等煤化工重点问题,适合我国国情的煤化工将有良好的发展前景。     

煤的荧光特性与其工艺性能的关系研究

简述了煤中镜质组荧光产生的机理及荧光参数的测量方法,通过测定一系列煤的粘结性和10kg小焦炉结焦性试验,探讨了煤的荧光特性与其工艺性能的关系。煤的荧光参数与其反射率呈正的线性相关关系,与其挥发分含量呈负的线性相关关系;煤的粘结性、结焦性均与其荧光参数有关;当煤化程度相同、煤岩组成基本相同时,煤的荧光强度愈强,其结焦性能愈好。     

国内外型焦生产工艺及发展前景

介绍了国内外型焦技术的生产工艺、型煤碳化的过程和影响因素,以及国内目前几种碳化窑炉,通过对型焦和焦炭的对比分析,指出洁净型焦生产技术的优势必然会使它在未来具有巨大的发展空间。     

双阳煤在PKM气化炉试烧总结

介绍了在PKM气化炉中弱粘结性双阳煤的试烧情况,并给出了主要工艺参数控制范围。试烧结果表明:依兰煤中配入50%双阳煤,汽氧比6.0:1时,气化炉工况良好。