模具液流悬浮加工区流场仿真研究

根据Navier-Stocks方程和流体运动的连续性方程,建立了聚氨酯工具头/工件加工区压力场及速度场的理论模型。以FLUENT 6.3为计算平台进行仿真,结果表明流体动压力和速度最大值出现在聚氨酯工具头/工件的最小间隙区域,且随间隙变小梯度变化增大,在工具头边缘处存在压力侧漏现象,由于这一现象,导致在局部边缘处速度的增加。     

部分糊化玉米淀粉浆液的性能

以玉米淀粉为原料,采用蒸汽升温法制备部分糊化淀粉浆液。运用光学显微镜、粒度分析仪、差示热分析仪、X射线衍射仪等对原淀粉和用蒸汽升温法于不同温度下制备的部分糊化淀粉浆液的形态结构、颗粒大小、膨胀势、糊化度、结晶度等进行了测试和比较。结果表明:随着制备温度的提高,部分糊化淀粉浆液的偏光十字逐渐消失,结晶度下降,而糊化度、粒径、膨胀势逐渐增大;64℃时制备的稳定性较好的部分糊化淀粉浆液的大部分偏光十字消失,但仍有结晶峰存在,糊化度为72.22%。     

浆式反应器控制阶段的确定

根据宏观动力学的原理，讨论了浆式反应器的各种控制阶段，给出了确定步序、减小各种阻力的措施。     

黄浆水液态深层发酵制醋工艺的研究

以白酒生产中间产物黄浆水为原料,结合液态深层发酵酿醋工艺,成功开发出风味独特的食醋.试验使用15L自吸式发酵罐补料分批培养,实验结果表明:在分割量35％时,周期24h以内,酸度高达7.6g/100mL,醋酸产率90％以上;成品醋不挥发酸比例25％.处理后各项指标均达到优级老陈醋标准,实现了黄浆水的综合利用,具有良好的实用价值和现实意义.     

Antioxidant effects of reduced water produced by electrolysis of sodium chloride solutions

Antioxidant vitamins and enzymes such as superoxide dismutase, catalase and glutathione peroxidase are considered to function as scavengers against reactive oxygen species and to provide protection against reactive oxygen species, including free radicals. Although antioxidants such as L-ascorbic acid, d-catechin and quercetin dehydrate show superoxide dismutation activity, using reduced water produced in the cathode side by electrolysis as a solvent instead of 2 mM NaC1 solution of the same pH level as the reduced water increased the superoxide dismutation activity of these antioxidants. Moreover, neither the reduced water nor its electrolyte solution showed any superoxide dismutation activity by itself. On the other hand, the reduced water was able to decrease hydrogen peroxide levels. It has been found that the behaviour of H₂ in reduced water, which was activated by a platinum electrode, differed from that of H₂ introduced by bubbling of hydrogen gas. The former decreased H₂O₂, whereas the latter did not. These results suggest strongly that the increase in superoxide dismutation activity, with a proton donor such as L-ascorbic acid, is due to an increase in the dissociation activity of water while the scavenging activity for H₂O₂ is due to activated dissolved H₂ in the reduced water.     

宣州硫酸厂30kt＼a料浆法磷铵装置的完善扩能

概述了宣州硫酸厂３０ｋｔ／ａ料浆法磷铵装置投产后暴露的问题及采取的技改完善措施。通过投资不大的各项技术改造,使装置从初投产时的班产３０多吨,扩能至班产６０吨,经济效益显著。     

高纯氰化金钾的电解制备法

介绍了一种先进的高分子聚合物膜电妥制备高纯氰化金钾工艺及纯化工艺。     

新庄孜选煤厂XJN-14型机械搅拌式浮选机工业性试验与分析

对XJN-14型浮选机的粗选-精选浮选流程进行了工业性试验,并对试验结果进行了分析,指出针对浮选系统存在着处理量过大的问题,可增加浮选机并及时监控加压过滤机的滤液浓度加以解决。     

Decomposition of hydriodic acid by electrolysis in the thermochemical water sulfur–iodine splitting cycle

Although several technologies, such as reactive distillation and catalytic membrane reactor, have been proposed to improve HI conversion efficiency, they still experience several challenges for the application in HI section. In this study, an electrochemical cell was employed for hydriodic acid decomposition under the presence of iodine. Several commercial proton-exchange membranes (PEMs), namely, Nafion 117 and Nafion 115, were used as separators for the electrochemical cell. Anodization of iodide anion occurred at the graphite electrode in the anode compartment. Hydrogen was generated by the reduction reaction of hydrogen cations, which migrated from anolyte to catholyte. In electrolysis experiments, PEM showed good performance in terms of high transport number of proton and low iodine permeation. Several parameters, such as operating temperature, HI molarity, and I₂ molarity in anolyte, which affected current efficiency, iodine permeance, and electric resistance of test cell, were investigated. High operating temperature and I₂ molarity in anolyte enhanced the permeability of iodine, which had several negative influences on electrochemical cell performance. Although current efficiency was negatively affected by increasing temperature and I₂ molarity, it still remained above 0.85 in the range of 30 °C–75 °C. Ohmic resistance, which is a component of cell resistance, offered by PEM was investigated with Nafion 117 and 115. Apart from graphite plates, activated carbon papers were adopted as electrodes to reduce the overpotentials due to their high specific surface characteristic.