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141.
Waste combustion is an interesting alternative for waste management and energy recovery. Knowledge of the waste higher heating value (HHV) is important for judging it’s worth as fuel. This work introduces a new equation, based on thermochemical concepts, to calculate HHV from elemental composition. This equation is expressed in terms of mass percentages on a dry basis of carbon (%C), hydrogen (%H), oxygen (%O), nitrogen (%N), and sulfur (%S); the HHV is computed in MJ/kg. The equation is as follows: HHV=(1−(%H2O/100))(−0.3708(%C)−1.1124(%H)+0.1391(%O)−0.3178(%N)−0.1391(%S)). The thermochemical concept on which this expression is based involves a wide applicability. This equation neglects the inorganic carbon, hence it is not very adequate when there is a significant concentration of it. The predictions from this approach were contrasted against those proceeding from equations currently used in combustion technology, and also against bomb calorimeter data. The new equation is clearly competitive with respect to other formulations, and it can be very helpful for presenting a waste HHV value based on different derivation suppositions. 相似文献
142.
143.
Javier M. Grau JosM. Bisang 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1992,53(1):105-110
This paper describes the parameters that are important in the industrial practice of silver removal from photographic fixers. The experiments were performed under potentiostatic control using synthetic solutions. The current efficiency was analysed as a function of the cathodic potential taking into account the deposit quality. A cathodic potential of ?0.5 V against a saturated calomel electrode is recommended. The conditions to prevent the darkening of the electrodeposit were investigated. The determination of silver concentration in the solution was made by direct potentiometry. The results obtained with synthetic fixers were corroborated by making the silver deposition from commercial fixers in an electrochemical reactor with rotating cylinder electrode intercalated in an electrolytic flow circuit in order to simulate practical conditions. 相似文献
144.
振动采油工艺在稠油区的实验研究与应用 总被引:5,自引:2,他引:3
在天然地震的影响下,油井产量发生波动,使人们受到启示,从而引进了振动采油工艺技术。本文对振动增产的机理进行了探讨,指出振动增油机理在于加快地层中流体的流速;改变储集层内油、气、水的重新分布;改变岩石表面润湿性,有利于清除油层堵塞,提高渗透率。通过分析两个试验区的振动采油效果,总结出在不同扰动力、不同激振频率、不同振动周期下的增产效果和规律,对振动采油的实施具有一定的指导意义。 相似文献
145.
146.
醋酸甲酯在Cs_(1.5)PW/SiO_2催化剂上的水解反应 总被引:1,自引:0,他引:1
通过改变阳离子的种类与配比,制备了一系列SiO2负载的磷钨酸盐催化剂,考察了制备方法对催化剂性能的影响,采用傅里叶变换红外光谱、X射线衍射、X射线荧光光谱、环境扫描电子显微镜等方法对催化剂进行了表征,并考察了该系列催化剂对醋酸甲酯水解反应的活性。实验结果表明,Cs1.5PW/SiO2催化剂的活性最好,当Cs1.5PW负载量(质量分数)为30%时,Cs1.5PW的Keggin结构保持完好,没有硅钨酸阴离子形成,Cs1.5PW在SiO2载体上高度分散;在反应温度55℃、反应时间2h的条件下,醋酸甲酯的转化率为35.79%,约为均相磷钨酸催化剂的1.3倍。该催化剂重复使用4次后,醋酸甲酯的转化率稳定在25%;80℃下反应2h,与NKC-9磺酸树脂催化剂相比,醋酸甲酯的转化率提高了5.17%。 相似文献
147.
148.
149.
R.H. Ericksen 《Polymer》1985,26(5):733-746
Creep of Kevlar 29, Kevlar 49 and PRD 49-III fibres was investigated. The fibres exhibited transient creep and the strain-time relationship was represented by a logarithmic time law. The creep strain recovered with time when the load was removed. Upon reloading to the same creep stress the strain-time relationship was again logarithmic but the creep rate was reduced. Modulus measurements were made during the creep test and these showed that the modulus increased with time. This result indicated a crystallite rotation mechanism which could account for the experimentally observed creep strain. Creep in PRD 49-III fibres exhibited a small temperature dependence over the temperature range 20°C to 150°C. The apparent creep activation energy was consistent with the range of values reported for hydrogen bonding. This suggests one possible creep mechanism in which the combined action of stress and thermal activation causes rearrangement of intercrystalline bonds in the crystallite boundaries resulting in boundary creep. Boundary creep allows crystallite rotation which produces the macroscopic creep strain. Boundary creep is discussed in terms of the fibre morphology and a model of delayed elasticity. 相似文献
150.
Emmanuel O. Egbogah Richard A. Dawe 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1985,35(3):132-144
Recent studies have suggested the possibility of spontaneous emulsification as a mechanism for enhanced oil recovery (EOR). The discussions have, however, remained essentially qualitative. A study was therefore undertaken to estimate quantitatively the contribution of spontaneous emulsification as an EOR mechanism. The tests were conducted on several bulk liquid/liquid systems as well as by displacement experiments in unconsolidated synthetic sand packs. Spontaneous emulsification was found to be a mechanism for EOR: the estimated extra contribution to EOR due to this mechanism was found to be significant in laboratory scale displacement experiments. Tertiary recovery was always greater when spontaneous emulsification was evident than otherwise. Results of tests on bulk liquid/liquid systems indicate that the occurrence or absence of spontaneous emulsification can be correlated with the values of ‘partition parameter’. It may be concluded that higher oil recoveries may be achieved in chemical EOR processes where interface mass transfer (and the accompanying spontaneous emulsification) occurs. The evaluation of efficiency of residual oil mobilisation through the capillary number theory (with and without spontaneous emulsification) is also discussed. Displacement tests with spontaneously emulsifying systems showed that residual oil left behind a conventional waterflood was mobilised in a range of capillary numbers much less than that which applies to low-tension waterfloods. 相似文献