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81.
Spinel compound LiNi0.5Mn1.5O4 was synthesized by a chemical wet method. Mn(NO3)2, Ni(NO3)2·6H2O, NH4HCO3 and LiOH·H2O were used as the starting materials. At first, Mn(NO3)2 and Ni(NO3)2·6H2O reacted with NH4HCO3 to produce a precursor, then the precursor reacted with LiOH·H2O to synthesize product LiNi0.5Mn1.5O4. The product showed a single spinel phase under appropriate calcination conditions, and exhibited a high voltage plateau at about 4.6-4.8 V in the charge/discharge process. The LiNi0.5Mn1.5O4 had a discharge specific capacity of 118 mAh/g at about 4.6 V and 126 mAh/g in total in the first cycle at a discharge current density of 2 mA/cm2. After 50 cycles, the total discharge capacity was above 118 mAh/g. 相似文献
82.
83.
The first use of nickel foam (NF) as electrocatalytic negative electrode in a polysulfide/bromine battery (PSB) is described. The performance of a PSB employing NF and polyacrylonitrile (PAN)-based carbon felt (CF) as negative and positive electrode materials, respectively, was evaluated by constant current charge-discharge tests in a single cell. Charge/discharge curves of the cell, positive and negative electrodes show that the rapid fall in cell voltage is due to the drop of positive potential caused by depletion of Br2 dissolved in the catholyte at the end of discharge. Cell voltage efficiency was limited by the relatively high internal ohmic resistance drop (iR drop). Polarization curves indicated that both NF and CF have excellent catalytic activity for the positive and negative redox reactions of PSB. The average energy efficiency of the single cell designed in this work could be as high as 77.2% at 40 mA cm−2 during 48 charge-discharge cycles. 相似文献
84.
用工业废碱水处理反渗透法高含盐排放浓水 总被引:2,自引:0,他引:2
反渗透处理装置排放的浓水含盐量很高,如果不经处理直接排放势必对周围环境造成污染和水的浪费,氧化铝生产工艺废水中含有大量的碳酸钠、苛性碱等碱类物质,pH值达到13左右,回水量约2000m^3/h,用这些废水和反渗透浓水混合进行软化处理,降低浓水中的钙镁离子含量,并对难去除的硫酸盐进行稀释降低浓度,回用到蒸发循环水系统作为补充用水、氧化铝生产部分工艺用水、设备冷却用水,达到浓水回收再利用的目的。该方案实施后效果十分显著,回收反渗透浓水约60m^3/h,减少污水系统补充新水,降低生产用水费用约每年176万元。 相似文献
85.
介绍中间相沥青炭微球的制备方法和发展现状,分析了其在锂离子二次电池等方面的应用及国内外市场前景。 相似文献
86.
介绍了无汞锌粉中的杂质、析气量、锌粉形貌以及电池密封圈对无汞碱性电池高温贮存性能的影响,探讨了电池漏液的原因,提出了防止漏液的措施。 相似文献
87.
88.
89.
介绍了合成高纯无水的LiBF4和LiAsF6的新方法,并讨论了其合成条件,指出制备多孔状LiF和控制反应温度是合成的关键。 相似文献
90.
George Ting-Kuo Fey P. Muralidharan Cheng-Zhang Lu Yung-Da Cho 《Electrochimica acta》2006,51(23):4850-4858
An enhanced electrochemical performance LiCoO2 cathode was synthesized by coating with various wt.% of La2O3 to the LiCoO2 particle surfaces by a polymeric method, followed by calcination at 923 K for 4 h in air. The surface-coated materials were characterized by XRD, TGA, SEM, TEM, BET and XPS/ESCA techniques. XRD patterns of La2O3-coated LiCoO2 revealed that the coating did not affect the crystal structure, α-NaFeO2, of the cathode material compared to pristine LiCoO2. TEM images showed a compact coating layer on the surface of the core material that had an average thickness of about ∼15 nm. XPS data illustrated that the presence of two different environmental O 1s ions corresponds to the surface-coated La2O3 and core material. The electrochemical performance of the coated materials by galvanostatic cycling studies suggest that 2.0 wt.% coated La2O3 on LiCoO2 improved cycle stability (284 cycles) by a factor of ∼7 times over the pristine LiCoO2 cathode material and also demonstrated excellent cell cycle stability when charged at high voltages (4.4, 4.5 and 4.6 V). Impedance spectroscopy demonstrated that the enhanced performance of the coated materials is attributed to slower impedance growth during the charge-discharge processes. The DSC curve revealed that the exothermic peak corresponding to the release of oxygen at ∼464 K was significantly smaller for the La2O3-coated cathode material and recognized its high thermal stability. 相似文献