一种三站时差定位的布站优化算法

测量站的布站直接影响时差定位目标的定位精度.针对一定区域目标整体定位精度的优化,提出了一种三站时差定位的布站优化算法.以水平定位精度因子(HDOP)为定位精度的度量准则,建立布站优化问题的多目标规划数学模型,通过构造最小最大评价函数,求解模型的最优解,从而得到三站时差定位的最优布站.仿真给出了该布站优化算法对某种初始布站进行优化前后两种布站的HDOP分布图.由仿真结果可以看出,相对于初始布站,最优布站对目标区定位精度的提高较为明显,验证了这种布站优化算法的有效性.     

Synthesis of n‐butyl phenyl ether by tri‐liquid‐phase catalysis using poly(ethylene glycol)‐600 as a catalyst – analysis of factors affecting the reaction in a batch reactor

As the second part of a series of studies on the synthesis of n‐butyl phenyl ether (ROPh) by tri‐liquid‐phase catalysis, this work examines the factors affecting the reaction between n‐butyl bromide (RBr, organic substrate) and sodium phenolate (NaOPh, aqueous nucleophile) with poly(ethylene glycol)‐600 (PEG‐600) as a phase‐transfer catalyst. The reaction is performed in a batch reactor at 45–85 °C for 2 h while the agitation speed is fixed at 1000 rpm. Experimental results indicate that the individual mole fractions of NaOPh and PEG‐600 slightly affect the reaction, while the total amount of these components exerts significant influence. When the mole fraction of PEG‐600 is 0.5, the reaction rate and the conversion of RBr are the highest. No byproducts are formed in the course of the reaction. The system using a non‐polar organic solvent might obtain a higher conversion compared with a weakly polar one owing to a higher concentration of PEG‐600 in the third liquid phase. Furthermore, adding NaOH facilitates the reaction to obtain a higher reaction rate than adding other kinds of salt because the addition of a base results in the formation of a third liquid phase. The catalytic ability of PEG with average molecular weight of 600 gmol^?1 is far higher than that with average molecular weight of 200, 400 and 1000 because PEG‐600 possesses an appropriate chain length which can tightly associate with Na⁺ to form the complex of PEG‐600‐Na⁺OPh^? for reacting with RBr. In addition, this nucleophilic substitution reaction is found to be pseudo‐first‐order with respect to RBr. © 2001 Society of Chemical Industry     

梯形试体三向千斤顶直剪试验法

介绍一种研究岩体软弱结构面抗剪强度的新的试验方法---梯形试体三向千斤顶直剪试验法。工程实践证明 ,新方法是可行的 ,对类似工程地质条件下的抗剪强度研究具有参考价值     

再生混凝土常规三轴受压性能试验研究

进行了12个再生混凝土试件常规三轴受压试验考察围压值和取代率对再生混凝土破坏形态、应力-应变曲线、力学性能指标的影响。研究结果表明:常规三轴受压状态下,再生混凝土均为剪切破坏,破坏时有较明显的脆性;再生混凝土的峰值应力、峰值应变、弹性模量随围压值增大而显著提高但受取代率的影响不大;增大围压值能有效提高再生混凝土的延性性能和耗能能力。     

高精度动调陀螺寻北仪优化设计

陀螺的漂移和随机误差是影响动调陀螺寻北的主要因素。提出了三位置寻北方案,消除了陀螺漂移对寻北的影响。准备时间、采样时间、低力矩维持电压和堵转时间等参数设置会直接影响寻北时间和寻北精度。通过实验数据设置合理的参数可减小陀螺随机误差。实测结果表示寻北精度从0.2°提高到0.05°。     

一种基于WG序列的测距新方法

应用具有良好相关特性的伪随机序列可以提高雷达测距信噪比，有助于实现高效率低功率的目标探测。二相发射态结合雷达的非发射状态可以定义三态序列。文中介绍了三态序列的一些概念及其主要性质；讨论了Wolfmann-Goutelard(WG)序列的近完美周期自相关性；并基于三态序列相关函数的定义，应用WG序列生成的三态码^3WG,构造了一种适用于测距雷达的，具有良好性质的码序列测距方法。该方法可以替代m序列在测距中的作用。     

韧性材料复合型断裂启裂点与开裂方向的讨论

参照多种材料常规断裂结果的宏观分析，通过研究LY12材料在不同复合比载荷下的断裂试验结果，修正了一般断裂试验中认定裂纹启裂方向的方法，结合不同复合比下裂尖附近应力三维度场、主应力方向的计算分析，得到：在裂端的钝化变形区域、应力三维度的极大值处，对应于裂纹的启裂位置，即使韧性材料II型裂纹发生剪切断裂的情况下也是如此、裂纹的启裂方向在拉伸断裂时与启裂点最大拉应力方向有关，在翦切断裂时与启裂点最大剪应力方向有关。     

影响热硫化硅橡胶生胶质量的主要因素

讨论了三官能链节、端羟基、三甲胺和挥发分含量及摩尔质量分布对热硫化硅橡胶生胶质量的影响，以及控制和预防的方法。     

Synthesis and electroluminescent properties of a novel copolymer with short alternating conjugated and non‐conjugated blocks

A new electroluminescent copolymer [poly(1,5‐di(3,5‐dimethyloxystyrylene)naphthalene‐block‐tri(ethylene oxide)) (DSN–TEO)], containing alternating rigid, conjugated light‐emitting units and flexible tri(ethylene oxide) ionic conductive units, was synthesized via the Wittig reaction. The polymer has fairly good solubility in chloroform, tetrahydrofuran, toluene, etc, and excellent film‐forming ability. The decomposition temperature and the glass transition temperature were 409 °C and 42.2 °C, respectively. A light‐emitting diode (LED) device with configuration ITO/PEDOT–PSS/DSN–TEO/Ca(Al) and light‐emitting electrochemical cell (LEC) device with ITO/DSN–TEO + PEO (LiTf)/Al were prepared, and the photoluminescence and electroluminescence (EL) properties were investigated. Efficient blue‐green light emission (EL maximum emissive wavelength at 508 nm) was found with onset voltage at 6 V. The maximum light efficiency was 0.107 cd A^?1 at 20 V for LED, and the onset voltage 2.5 V and the maximum light efficiency was 4.2 cd A^?1 at 2.8 V for LEC, respectively. The response time of the LEC was less than 5 s. The EL efficiency of LEC device was improved by 44 as compared with the relative LED device. © 2003 Society of Chemical Industry     

应用1550nm光传输技术加快广电农网双改建设

1550nm光传输技术已成为广电网络传输的主流技术,用1550nm光传输系统组网有结构简单、应用方便、可靠性高、投资少等特点,是目前广电双网双改较理想的传输方案。根据1550nm光传输技术CIN指标的计算,前端和分前端以及光节点的实用组网方式,并结合EPON、EoC、IPQAM技术,为加快广电农网双改建设提供了理论和实践依据。