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51.
The early stages of corrosion of AISI 314, HK 40, and Alloy 800H have been studied in a strongly carburizing (aC=0.8), weakly oxidizing
atmosphere at 1098 K. Samples with electropolished and cold-worked surfaces were exposed for up to 400 min. at temperature, in a conventional corrosion rig or in a reaction vessel which was installed within an X-ray photoelectron spectrometer. The latter facility allowed the effects of the specimen heating rate and the rat of gas flow to be investigated. Examination of the corrosion products was accomplished with the aid of XPS, SEM, TEM, and conventional metallography. Initially, surface layers comprised of -Cr2O3, (Mn, Cr)3O4, and SiO2 formed, with layer structure, microstructure, and composition being functions of alloy composition and surface condition. Only on the cold-worked surfaces did a well-developed duplex oxide, consisting of an outer, Cr-rich oxide layer and an inner, SiO2 layer, form. In good agreement with the predicted value of 1.9 wt.%, between 1.4 and 2 wt.% Si in the alloy was required to form a complete SiO2 layer. After an incubation period, -Cr2O3 became unstable and transformed to M7C3; the carbides then grew by diffusion of metal from the alloy substrate. The presence of manganese, as (Mn, Cr)3O4, in the surface oxide influenced the mode of carbide growth, whereas the rate of carbide growth was severely suppressed by a continuous SiO2 layer which acted as a diffusion barrier both to metal and to carbon. It is argued that the SiO2 layer is most effective in reducing carburization when it is free from or contains very few structural defects. 相似文献
52.
Surface modification of spherical LiNi1/3Co 1/3 Mn1/3O2 with Al2O3 using heterogeneous nucleation process 总被引:1,自引:0,他引:1
To improve the cycle stability at high voltage and high charge/discharge rate, spherical LiNi1/3Co1/3Mn1/3O2 was coated with Al2O3 by using heterogeneous nucleation process, and the physical and electrochemical properties were studied. The SEM images show that there is a uniform coating on the modified spherical LiNi1/3Co1/3Mn1/3O2. The electrochemical tests indicate that the properties of LiNi1/3Co1/3Mn1/3O2 coated with 0.5% aluminum oxide are the best. The initial capacities are 150 and 173 mA.h/g at the rate of I C in the voltage range of 2.7-4.3 V and 2.7-4.6 V, respectively, and the discharge capacities maintain about 99% and 85% after 30 cycles, respectively. While those of the bare LiNi1/3Co1/3Mn1/3O2 are only 90% and 75%, respectively. The CV tests of LiNi1/3Co1/3Mn1/3O2 show that Al203-coating can restrain the oxide-reduction peak currents fading during the charge/discharge course. 相似文献
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整体锻造挤压辊是整个辊压机的关键部件,形状短粗,是大型粗短轴类零件的代表,锻透性较差;空洞型缺陷是造成产品合格率低的一个重要因素,必须消除.本文利用Deform-3D模拟软件,对两次镦拔新工艺应用于RP170-110挤压辊的第1次镦拔过程进行了理论验证.通过对镦粗后采用WHF法和FM法拔长过程的数值模拟结果进行对比,说明两次镦拔新工艺中的第1次镦拔工艺-镦粗 WHF法拔长能够在足够大的三向压应力状态下,在再结晶温度以上愈合孔洞型缺陷,提高了大型短粗轴类锻件的锻透性.8件锻件全部试制合格的结果也证明了两次镦拔新工艺第1次镦拔的合理性. 相似文献
55.
液态金属快速结晶的热力学驱动力 总被引:1,自引:0,他引:1
采用超高真空无容器悬浮熔炼技术使液态Fe和Ni的过冷度分别达200和235K,借助量热法测定出其比热各为48.6和40.5J·mol~(-1)·K~(-1).据此精确计算出深过冷Fe和Ni快速结晶的热力学驱动力△G_(LS),并与Turnbull模型和Dubey-Ramachandrarao模型的近似计算结果相比较,发现这两种近似模型在过冷度超过100K时均产生大于1%的偏差.进一步分析发现,△G_(LS)的计算偏差对深过冷液态金属中晶体形核率的影响极大,因此快速凝固研究中应尽可能精确计算△G_(LS). 相似文献
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亚微米碳化硅粉末的制备 总被引:1,自引:0,他引:1
采用硅酸乙脂和酚醛树脂为原料,合成了具有高混合度的C/SiO2混合物。高温碳热反应后,得到亚微米级的球状粉末,并且粉末粒度分布范围小。本文对碳热反应中一氧化硅的损失作了定量分析。结果表明,较高C/SiO2比导致较低一氧化硅损失和较高的碳化硅产量。在1500℃反应后,C/SiO2=3时,一氧化硅的损失达约20%。而当C/SiO2=5时,损失<5%。较高的C/SiO2比对碳化硅的形成速度有明显的促进作 相似文献
59.
Targeted Nanoparticle Thermometry: A Method to Measure Local Temperature at the Nanoscale Point Where Water Vapor Nucleation Occurs
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Arwa A. Alaulamie Susil Baral Samuel C. Johnson Hugh H. Richardson 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(1)
An optical nanothermometer technique based on laser trapping, moving and targeted attaching an erbium oxide nanoparticle cluster is developed to measure the local temperature. The authors apply this new nanoscale temperature measuring technique (limited by the size of the nanoparticles) to measure the temperature of vapor nucleation in water. Vapor nucleation is observed after superheating water above the boiling point for degassed and nondegassed water. The average nucleation temperature for water without gas is 560 K but this temperature is lowered by 100 K when gas is introduced into the water. The authors are able to measure the temperature inside the bubble during bubble formation and find that the temperature inside the bubble spikes to over 1000 K because the heat source (optically‐heated nanorods) is no longer connected to liquid water and heat dissipation is greatly reduced. 相似文献
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