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941.
目的 对钩体黄疸出血群赖株LipL4 1基因进行克隆、表达及鉴定。方法 采用高保真PCR ,从我国钩体黄疸出血群赖株基因组中扩增全长LipL4 1基因片段 ,并构建原核表达系统。结果 所克隆的LipL4 1基因核苷酸和氨基酸序列与已发表LipL4 1基因序列 (GenbankL4 6 794 )同源性分别为 96 2 5 %和 98 87% ;所表达的目的蛋白经Westernblot证实为具有良好免疫反应性的广谱抗原。结论 可作为研制基因工程疫苗的候选抗原 相似文献
942.
The impedance rise that results from the accelerated aging of high-power lithium-ion cells containing LiNi0.8Co0.15Al0.05O2-based positive and graphite-based negative electrodes is dominated by contributions from the positive electrode. Data from various diagnostic experiments have indicated that a general degradation of the ionic pathway, apparently caused by surface film formation on the oxide particles, produces the positive electrode interface rise. One mechanistic hypothesis postulates that these surface films are components of the negative electrode solid electrolyte interphase (SEI) layer that migrate through the electrolyte and separator and subsequently coat the positive electrode. This hypothesis is examined in this article by subjecting cells with LiNi0.8Co0.15Al0.05O2-based positive and Li4/3Ti5/3O4-based negative electrodes to accelerated aging. The impedance rise in these cells was observed to be almost entirely from the positive electrode. Because reduction products are not expected on the 1.55 V Li4/3Ti5/3O4 electrode, the positive electrode impedance cannot be attributed to the migration of SEI-type fragments from the negative electrode. It follows then that the impedance rise results from mechanisms that are “intrinsic” to the positive electrode. 相似文献
943.
Adsorption properties of copolymers of acrylamide and mesaconic acid (CAME) in aqueous Basic Blue 12 (Nile blue chloride) solution have been investigated. Chemically crosslinked CAME hydrogels with various compositions were prepared from ternary mixtures of acrylamide (A), mesaconic(ME) acid, and water by free radical polymerization in aqueous solution, using a multifunctional crosslinker such as ethylene glycol dimethacrylate (EGDMA). Dynamic swelling tests in water was applied to the hydrogels. Weight swelling ratio (S) values have been calculated. Sorption of Basic Blue 12 (BB 12) onto CAME hydrogels was studied by batch sorption technique at 25°C. In the experiments of the sorption, L type sorption in the Giles classification system was found. Some binding parameters such as initial binding constant (Ki), equilibrium constant (K), monolayer coverage (n), site‐size (u), and maximum fractional occupancy (Ô) for CAME hydrogels‐BB 12 binding system were calculated by using Klotz, Scatchard, and Langmuir linearization methods. Finally, the amount of sorbed BB 12 per gram of dry hydrogel (q) was calculated to be 2.28 × 10?6–7.91× 10?6 mol BB 12 per gram for hydrogels. Sorption % was changed range 16.09–58.86%. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 405–413, 2006 相似文献
944.
本文介绍发不同牌号高密度聚乙烯和聚碳酸酯对HDPE/PC共混物性能的影响结果。同时以PE接枝马来酸酐和自PE接枝烯丙基双酚A醚及PE接枝烯丙基双酚A作为增容剂,研究了不同增容剂、PC含量和增容剂含量对HDPE/PC共混物力学和热性能的影响。 相似文献
945.
Jose E. Herrera Ja Hun Kwak Jian Zhi Hu Yong Wang Charles H. F. Peden 《Topics in Catalysis》2006,39(3-4):245-255
The advantages of the atomic layer deposition (ALD) method for preparation of tungsten, vanadium, titanium, and molybdenum
oxide catalyst supported on mesoporous silica are discussed, with emphasis on the importance of synthesis conditions on dispersion,
structure and activity of the resulting materials. A suite of complementary techniques such as DRS-UV/Vis, BET, 1H-NMR, XRD, and TEM were used to study the structural properties of the supported metal oxides, and probe reactions such as
2-butanol dehydration and ethanol partial oxidation were used to demonstrate the potential advantages of the ALD-prepared
catalysts. Specifically, highly dispersed oxides of titanium, molybdenum, and tungsten oxide on mesoporous silica were synthesized
using the ALD method. It is also demonstrated that attainment of high dispersions of vanadium oxide on mesoporous silica requires
the presence of at least a single layer of titanium oxide due to the well-known poor interaction between vanadia and silica.
The highly dispersed catalysts prepared here by ALD methods exhibited superior catalytic performance relative to those prepared
using conventional incipient wetness impregnation. 相似文献
946.
金属—橡胶硫化粘接复合体剥离破坏行为的研究 总被引:4,自引:0,他引:4
本文分析了对橡胶分子链特性、部分交联弹性聚合物材料的粘弹行为及金属──橡胶硫化粘接体剥离过程中聚合物分子链的应力分布状况和剥离破坏模型,认为粘着一滑动(Stick—slip)模型剥离破坏并非是橡胶类材料的固有特征,而是由于金属──橡胶硫化粘接过程中的分子取向交联和部分交联弹性材料多个凯尔文(Kelvin)模型粘弹行为的综合结果.同时指出单从剥离试验的结果难以表征金属——橡胶硫化粘接复合作的粘接效果. 相似文献
947.
948.
Al(OH)3是LDPE/EVA主要的阻燃,消烟填充剂。研究了不同粒度,表面处理及填充量的Al(OH)3对LDPE/EVA的氧指数(OI),烟密度等级(SDR)和物理机械性能的影响。 相似文献
949.
Thermal analysis of montmorillonites modified with quaternary phosphonium and ammonium surfactants 总被引:2,自引:4,他引:2
The thermal stability of seven organically modified montmorillonites (‘organoclays’) has been investigated using differential thermal analysis, differential scanning calorimetry, and thermogravimetry in conjunction with X-ray diffractometry. Six organoclays were synthesised by replacing the interlayer inorganic cations, initially present, with quaternary phosphonium and ammonium surfactant cations. The samples modified with tetrabutylphosphonium (TBP), and butyltriphenylphosphonium (BTPP) ions have an appreciably higher thermal stability than the octadecyltrimethylammonium (ODTMA)-modified clays. Thus, in the case of TBP- and BTPP-modified montmorillonites, the onset temperature of decomposition is close to 300 °C. Samples modified with hexadecyltributylphosphonium (HDTBP) ions have a lower onset temperature of decomposition of 225 °C. In comparison, the onset temperature for ODTMA-montmorillonites (obtained at different concentrations of ODTMA-bromide) ranges from 158 to 222 °C, being highest where the concentration of intercalated surfactant is lowest. The onset temperature for a commercial alkylsilane-treated quaternary ammonium-modified organoclay (S-BEN N-400FP) is 207 °C. The basal spacing of the TBP- and BTPP-modified clays is 1.7–1.8 nm, indicating a monolayer arrangement of quaternary phosphonium ions in the interlayer space, while the value of 2.5 nm for HDTBP-montmorillonite indicates a more open structure. The ODTMA-modified samples have basal spacings ranging from 1.9 to 2.1 nm, indicative of a bilayer to pseudo-trilayer arrangement. The exceptionally high basal spacing of 3.4 nm for the S-BEN N-400FP organoclay might be due to interlayer penetration of organosilane hydrolysis products during synthesis. The thermal properties of organoclays are apparently related to the nature of the surfactants and their arrangement in the interlayer space of montmorillonite. 相似文献
950.
M. J. Kappers M. Vaarkamp J. T. Miller F. S. Modica M. K. Barr J. H. van der Maas D. C. Koningsberger 《Catalysis Letters》1993,21(3-4):235-244
The adsorption of carbon monoxide on a non-acidic Pt/K-LTL catalyst has been studied by diffuse reflectance and transmission IR spectroscopy. The CO spectrum is strongly dependent on the experimental conditions. Adsorption on the small Pt clusters in the presence of water gives linear-CO bands between 2060 and 1990 cm–1 and a bridging-CO band around 1800 cm–1. In the absence of water, the linear bands are red shifted to about 1940 and 1720 cm–1, respectively. The frequency shift is attributed to an ion-dipole interaction between adsorbed CO and support cations. The ion-dipole interaction is screened by the adsorbed water leading to a smaller red shift in the CO stretching frequency. 相似文献