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991.
Al_2O_3负载TiO_2光催化氧化剂的制备与性能试验 总被引:1,自引:2,他引:1
以钛酸四丁酯为钛源、Al2O3为载体,采用浸渍法制备了一系列TiO2/Al2O3复合氧化物光催化剂。以光催化降解甲醛为探针反应,考察了催化剂的光催化活性。并采用XRD、SEM技术对催化剂进行了表征。考察了催化剂的焙烧温度、钛含量、反应温度等因素对甲醛光催化降解率的影响。结果表明:400℃是制备TiO2/Al2O3光催化剂的最佳焙烧温度;在TiO2负载质量为5.0%的复合氧化物光催化剂催化效果最好,甲醛的降解率达到58.4%。随着反应温度的升高,复合氧化物光催化剂的催化性能下降,由25℃时的58.4%的甲醛降解率下降到50℃时的4.8%。 相似文献
992.
Mejía-Centeno Isidro Martínez-Hernández Angel Fuentes Gustavo A. 《Topics in Catalysis》2007,42(1-4):381-385
The use of low-sulfur fuel is known to improve the performance of the three-way catalytic converter (TWC). However, in this
work we report how low-sulfur operation of commercial TWC also favors formation of N2O and NH3 as by products. We found that low-sulfur rich operation above 300 °C increases the production of NH3, inhibiting the formation of N2O characteristic of high-sulfur operation. During lean operation, the production of N2O near the stoichiometric point is not significantly affected by the sulfur level. The large production of N2O observed during light-off is not affected by SO2 when the operation is lean, but under rich conditions N2O is produced up to 575 °C. The increased production of NH3 and N2O in TWC as a result of the introduction of low-sulfur gasoline is an area that requires further analysis because of its implication
upon public health in large urban settings. 相似文献
993.
A simple solid state technique for electrochemical micromachining of metal substrates using a metal ion conductor (Na-β″-Al2O3) was proposed. The fundamental solid electrochemical cell consists of a (anode) metal substrate (M = Ag, Cu, Zn, and Pb)/pyramidal Na-β″-Al2O3/Ag (cathode) system, where the contact diameter between M/Na-β″-Al2O3 was extremely small, on the order of a few micrometer. Under an applied electric field, the metal substrate was electrochemically oxidized to metal ions (Mn+) at the M/Na-β″-Al2O3 microcontact. These Mn+ ions migrated into the Na-β″-Al2O3. As a result of continuous electrolysis, the metal substrate was locally consumed at the microcontact, and thus solid state electrochemical micromachining was accomplished. As expected, the machining size or depth depended on the electrolysis conditions (current, operating time) and the apex configuration of pyramidal Na-β″-Al2O3. Moreover, the scanning of the Na-β″-Al2O3 pyramid during electrolysis produced a fine patterned metal substrate. In the present paper, solid state electrochemical micromachining was performed for several metal substrates, and its advantages and disadvantages vis-a-vis the conventional electrochemical micromachining method are discussed in detail. 相似文献
994.
Novel carbon supported Pt/SnOx/C catalysts with Pt:Sn atomic ratios of 5:5, 6:4, 7:3 and 8:2 were prepared by a modified polyol method and characterized with respect to their structural properties (X-ray diffraction (XRD) and transmission electron microscopy (TEM)), chemical composition (XPS), their electrochemical properties (base voltammetry, COad stripping) and their electrocatalytic activity and selectivity for ethanol oxidation (ethanol oxidation reaction (EOR)). The data show that the Pt/SnOx/C catalysts are composed of Pt and tin oxide nanoparticles with an average Pt particle diameter of about 2 nm. The steady-state activity of the Pt/SnOx/C catalysts towards the EOR decreases with tin content at room temperature, but increases at 80 °C. On all Pt/SnOx/C catalysts, acetic acid and acetaldehyde represent dominant products, CO2 formation contributes 1-3% for both potentiostatic and potentiodynamic reaction conditions. With increasing potential, the acetaldehyde yield decreases and the acetic acid yield increases. The apparent activation energies of the EOR increase with tin content (19-29 kJ mol−1), but are lower than on Pt/C (32 kJ mol−1). The somewhat better performance of the Pt/SnOx/C catalysts compared to alloyed PtSnx/C catalysts is attributed to the presence of both sufficiently large Pt ensembles for ethanol dehydrogenation and C-C bond splitting and of tin oxide for OH generation. Fuel cell measurements performed for comparison largely confirm the results obtained in model studies. 相似文献
995.
A novel semi‐interpenetrating (semi‐IPN) graft copolymer of 2‐hydroxyethyl methacrylate (HEMA) with chitosan (CS) has been prepared in the form of microspheres, using water‐in‐oil (W/O) emulsion technique. Microspheres were characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and X‐ray diffractometry (X‐RD) to confirm the crosslinking and polymorphism of indomethacin (IDM). The X‐RD and DSC techniques indicated a molecular‐level dispersion of IDM in the IPN matrix. Scanning electron micrographs (SEM) taken at the cross section of the microspheres have shown rough surfaces around the microspheres. The sustained release characteristics of the matrices for IDM, an anti‐inflammatory drug, were investigated in pH 7.4 media. Particle size and size distribution of the microspheres were studied by laser light diffraction particle size analyzer. The drug was released in a sustained manner for up to 12 h. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci, 2006 相似文献
996.
Electrocodeposition of Sm and Co on a Cu substrate was investigated in a molten LiCl-KCl-SmCl3 (0.5 mol.%)-CoCl2 (0.1 mol.%) system at 723 K. Phase of the deposited Sm-Co alloys could be controlled by electrolysis potential. SmCo3 was formed on a Cu substrate by potentiostatic electrolysis in the potential range of 0.20-0.90 V (vs. Li+/Li). Sm2Co17 was obtained in the potential range of 0.90-1.50 V. 相似文献
997.
Z. F. Zhang Z. M. Sun H. Hashimoto T. Abe 《Journal of the European Ceramic Society》2002,22(16):2957-2961
To synthesize Ti3SiC2 samples, pulse discharge sintering (PDS) technique was utilized to sinter elemental powders of Ti/Si/C with stoichiometric and off-stoichiometric ratios in a temperature range of 1200–1500 °C. The results showed that high purity Ti3SiC2 could not be obtained from the Ti/Si/C powder with molar ratio of 3:1:2, and Ti3SiC2 preferred to form at relatively low sintering temperature for a short time. When 5Ti/2Si/3C and 3Ti/1.5Si/2C powders were sintered for 15 min, the TiC content was respectively decreased to 6.4 and 10 wt.% at 1250–1300 °C. The corresponding relative density of the samples sintered from 5Ti/2Si/3C powder was calculated to be as high as 99% at the temperature above 1300 °C. It is suggested that low-temperature rapid synthesis of Ti3SiC2 would be possible through the PDS technique, provided that the composition of the starting powders should be adjusted to be off-stoichiometric ratio from 3:1:2. 相似文献
998.
Thomas M. Odell Chong-Hua Xu Paul W. Schaefer Barbara A. Leonhardt De-Fu Yao Xiang-De Wu 《Journal of chemical ecology》1992,18(12):2153-2159
Pheromone traps baited with (+)-disparlure,cis-7,8-epoxy-2methyocta-decane, captured males ofLymantria dispar, L. monacha, andL. mathura in northeastern People's Republic of China.L. dispar responded to the addition of olefin to (+)-disparlure-baited traps in a negative doseresponse manner. Observations on site and seasonal capture ofL. dispar andL. mathura are discussed.Lepidoptera: Lymantriidae. 相似文献
999.
The effect of preparation method on MnO
x
–CeO2 mixed oxide catalysts for methane combustion at low temperature was investigated by means of BET, XRD, XPS, H2-TPR techniques and methane oxidation reaction. The catalysts were prepared by the conventional coprecipitation, plasma and
modified coprecipitation methods, respectively. It was found that the catalyst prepared by modified coprecipitation was the
most active, over which methane conversion reached 90% at a temperature as low as 390 °C. The XRD results showed the preparation
methods had no effect on the solid solution structure of MnO
x
–CeO2 catalysts. More Mn4+ and richer lattice oxygen were found on the surface of the modified coprecipitation prepared catalyst with the help of XPS
analysis, and its reduction and BET surface area were remarkably promoted. These factors could be responsible for its higher
activity for methane combustion at low temperature. 相似文献
1000.