Interfacial activity and rate of palladium(II) extraction with decyl pyridine monocarboxylates

Decyl isonicotiniate and decyl nicotiniate permit a rapid extraction of palladium(II) from its hydrochloride solutions. Decyl picoliniate is not a suitable extractant. 4-Octylphenylamine can act as a phase transfer catalyst when its concentration in the organic phase is at least 2·5 × 10^?4 M . It seems that the interfacial adsorption of pyridine carboxylates and of 4-octylphenylamine is not the decisive phenomenon in palladium(II) extraction. The negligible protonation of the pyridine-type extractants and the phase transfer catalysis explains well the quick extraction of palladium(II) with the commercial and highly hydrophobic extractant ACORGA CLX-50.     

抽余C_4烃中异丁烯催化逆流水合制叔丁醇

采用大颗粒离子交换树脂催化剂,在φ100mm×10m的反应器中进行了异丁烯催化逆流水合制叔丁醇的中间试验。考察了反应温度、水油体积比和抽余C4烃的流速等对异丁烯转化率的影响。试验结果表明,异丁烯催化逆流水合制叔丁醇的适宜操作条件为:反应温度80~90℃,水油体积比为4~5,抽余C4烃的流速为0.45~0.55mm/s。在此条件下,异丁烯的转化率可达88.8%。工业装置运转结果表明,异丁烯转化率大于75%。     

Air-Oxidation Behavior of a Cu60Hf25Ti15 Bulk Metallic Glass at 375–520 °C

The oxidation behavior of a Cu₆₀Hf₂₅Ti₁₅ bulk metallic glass was studied over the temperature range of 375–520 °C in dry air. The oxidation kinetics of the amorphous alloy generally followed the parabolic law at all temperatures, with an oxidation rate increasing with temperature. The oxidation rates of the amorphous alloy were much higher than those of polycrystalline pure-Cu, implying that the additions of Hf and Ti accelerated the oxidation reaction. The composition of the scales formed on the amorphous alloy was strongly temperature-dependent, since they consisted mostly of Cu₄O₃ and CuO with minor amounts of HfO₂ at T ≤ 450 °C, while mostly CuO with minor amounts of HfO₂ and Cu₂TiO₃ were detected at higher temperatures. In addition, nanocrystalline Cu₅₁Hf₁₄ and Cu₃Ti₂ phases were detected on the substrate after oxidation at T ≥ 450 °C, indicating the occurrence of phase transformation.     

Kinetics of methylamine conversion on a Pd catalyst in the presence of H2

The kinetics of disproportionation of methylamine to dimethylamine and ammonia in the presence of hydrogen have been investigated over a silica-supported palladium catalyst. At a fixed partial pressure of methylamine, the reaction rate generally increases with decreasing hydrogen partial pressure, approaching a limiting or maximum value at sufficiently low pressures of hydrogen. The existence of a maximum is supported by the observation that the presence of some hydrogen appears to be necessary for the reaction to proceed at a conveniently measurable rate. At a fixed hydrogen partial pressure, the reaction rate increases with increasing methylamine partial pressure. When the methylamine partial pressure is sufficiently low or the hydrogen partial pressure is sufficiently high, the reaction order with respect to methylamine can be somewhat higher than one. At such conditions, a mechanism involving a bimolecular reaction between two partially dehydrogenated methylamine molecules on the surface appears to make a significant contribution to the overall catalytic reaction.     

用EGS4分析9MeV行波直线加速器屏蔽系统

采用了国际上广泛使用的ＭｏｎｔｅＣａｒｌｏ模拟计算程序ＥＧＳ４对海关集装箱检测系统用加速器屏蔽系统进行了辐射模拟分析，与实际测试数据进行分析、比较，解释了特殊剂量分布的原因，提出了系统改进的参考方案。     

SiH_4－O_2体系LPCVD SiO_2薄膜的工艺及其应用

本文研究了ＳｉＨ４—Ｏ２体系ＬＰＣＶＤＳｉＯ２的工艺及设备。为了得到厚度均匀性好的薄膜，改进了反应气体的进气方式和装片舟的结构，获得了每炉１００片、直径为１００ｍｍ的硅片的膜厚不均匀性≤士５％的结果。     

MPEG-2／4AAC音频编码模块的验证

先进音频编码（AdvancedAudioCoding,AAC）以其多声道、多采样率、高压缩比、音质好等特点被广泛使用。文中首先介绍了MPEG-2／4AAC音频编码技术;接着基于MPEG-2／4AAC音频编码原理,开发了时钟复位、寄存器配置和音频数据收发的BFM模型,搭建了音频编码模块的RTL级虚拟验证平台,同时归纳了验证项;最后基于此验证平台和验证项,对设计进行了全面的仿真验证。实践证明该验证方法效率高、收敛快、覆盖率高,取得了较好的效果,为后续的FPGA平台验证和芯片应用提供了有力的保证。     

IPv6在矿井工业以太网中的应用研究

介绍了IPv6产生的背景和发展现状,阐述了IPv6应用于矿井工业以太网的发展趋势和研究方向,指出对于所有基于矿井工业以太网的硬件和软件的开发都应带有双协议栈,随着IPv6技术的成熟和普及再研发出只有IPv6协议栈的适用于煤矿的网络设备,如支持IPv6的防爆网络设备、组态软件以及相应的数据采集驱动设备、控制硬件等。