Modeling and analysis of rapid catalyst aging cycles

The primary mode of deactivation of automotive emission control catalysts is thermal aging, and it is well-known that high-temperature lean aging conditions are particularly detrimental. Since evaluating the long-term durability of automotive catalysts is costly and time-consuming, rapid catalyst aging cycles have been developed to mimic (in a reduced time) the catalyst deactivation under real-world driving conditions. One of the commonly used rapid catalyst aging tests is an exothermal aging cycle, which involves a combination of fuel-rich engine operation and supplemental air injection to generate high-temperature lean conditions within the catalyst bed. In this work, we use the previously developed transient three-way catalyst model to investigate the time evolution of the axial temperature profiles and exhaust air–fuel ratio (A/F) along the catalyst bed during the course of the exothermal rapid aging cycles. We find that the thermal front propagates downstream through the catalyst bed relatively slowly (compared to the concentration front) and this can limit the location within the catalyst bed and duration for high-temperature lean exposure. We also investigate how variations of some of the key system design and operating parameters can affect the extent and duration of high-temperature lean exposure. Finally, a simple analytical expression is developed which allows one to estimate the time it takes for the thermal front to travel through the catalyst bed. This time can be compared with the period of the lean A/F operation during the aging cycle to determine the location and duration of high-temperature lean exposure.     

On systems with shared resources and optimal switching strategies

Simple series systems of identical components with spare parts are considered. It is shown that the cumulative distribution function of a system failure time tends to be a step function as the number of components increases and resources can be shared. An example of ‘continuous resources’ is also described. The time-sharing strategy for standby systems is investigated. It is proved that an optimal rule for a system of standby components with increasing failure rates is the single switching performed at a=t/2, where t is the mission time.     

Prediction of Aging Characteristics in Natural Rubber Bearings Used in Bridges

Rubber bearings used in bridges are exposed to the air and easily attacked by oxygen, even at room temperature, and heat, light, dynamic strain, and liquids. It is usually known that the degradation of polymers often occurs as a nonuniform or heterogeneous process because aged rubber will prevent deterioration from progressing into the inner rubber bearing. Thermal oxidation tests were carried out on natural rubber (NR) blocks at different elevated temperatures using the modulus profiling method. The development of the heterogeneous property profiles in aged rubber bearings is revealed. The NR blocks display the features of a diffusion-limited oxidation and the properties change most significantly at the surface. However, in the interior region beyond the critical depth, NR does not change. The property variations at the block surface and the interior are quantitatively examined, based on which, the relations are clarified among property variation, temperature, aging time, and relative position inside a rubber bearing. An appropriate aging model is established, which is able to predict the aging characteristics in NR bearing.     

The silver sensory experience – A review of senior consumers’ food perception,liking and intake

It is commonly assumed that sensory impairments occurring with age negatively affect older people’s intake of foods in terms of both quality and quantity. This review discusses evidence published on the effects of age on sensory perception and the consequences for independently living seniors’ perception, liking and intake of food products. Because of anatomical changes in all the senses involved in human food perception, on average seniors perceive a lower flavour intensity than younger adults, are less sensitive to changes in the flavour profile of foods, and show a decreased ability to discriminate between different intensity levels of flavour and/or taste attributes. However, despite these differences in their sensory perception of foods, young adults and seniors seem to differ less in their initial hedonic appraisal of food products. Nonetheless, more research is needed to determine whether multisensory enrichment of foods across different modalities may lead to increased food liking in seniors both with and without olfactory impairment. Although limited, the current evidence suggests that sensory performance may be positively associated with BMI or body weight in specific senior populations. In addition, seniors fail to show a decreased appreciation of an eaten food, thereby increasing the risk of a monotonous diet. Taken together, these findings highlight the need for appropriate interventions and/or foods to improve and maintain adequate quantity and quality of food intake among independently living seniors, and especially those with low sensory performance. Such interventions should be holistic rather than focused on one modality and may also incorporate hedonic modulators such as past experiences, affective factors and external cues, e.g. brand names, labels or food packaging. In interventions and product development, segmentation of the senior consumer market is strongly advised to identify more homogeneous subgroups in order to deal with the large heterogeneity between independently living seniors. It is concluded that one size of the silver food experience will most likely not fit all senior consumers!     

Video game training to improve selective visual attention in older adults

The current study investigated the effect of video game training on older adult’s useful field of view performance (the UFOV® test). Fifty-eight older adult participants were randomized to receive practice with the target action game (Medal of Honor), a placebo control arcade game (Tetris), a clinically validated UFOV training program, or into a no contact control group. Examining pretest–posttest change in selective visual attention, the UFOV improved significantly more than the game groups; all three intervention groups improved significantly more than no-contact controls. There was a lack of difference between the two game conditions, differing from findings with younger adults. Discussion considers whether games posing less challenge might still be effective interventions for elders, and whether optimal training dosages should be higher.     

Examination of Interpenetrating Polymer Networks of Polyurea in Silicone Molds Arising during Vacuum Casting Processes

We present an in-depth investigation of the aging effects in silicone molds for vacuum casting processes. Their lifetime is limited to a few production cycles due to contamination with the diisocyanate component of polyurethane casting materials. Using thermogravimetric analysis measurements, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and helium-ion-microscopy the chemical and physical mechanisms of the aging process have been identified. It has been shown that a diffusion process of diisocyanate into the cavity surface leads to the formation of interpenetrating polymer networks of polyurea derivatives in silicone rubber. This has been proven by extracting and analyzing polyurea of low molecular weights from the silicone.     

A strategy for the risk-based inspection of pressure safety valves

The purpose of a pressure safety valve (PSV) is to protect the life and safety of pressure vessels in a pressurized system. If a weakened PSV fails to function properly, a catastrophic event might occur if no other protective means are provided. By utilizing the as-received test data and statistical analysis of the aging conditions of PSVs in lubricant process units, a risk-based inspection (RBI) system was developed in this study. First of all, the characteristics of PSV were discussed from the practical viewpoint of engineering inspection and maintenance. The as-received test data, which shows obvious PSV damage, will be separated from the data used in the following statistical analysis. Then, the relationship between the aging conditions and the corresponding PSV parameters was analyzed by using the statistical technique—analysis of variance (ANOVA). Finally, a strategy for semi-quantitative RBI is proposed. Also, a definitive estimated inspection interval for every PSV is suggested. The outcome indicated most of the risks result from a few PSVs, for which the corresponding inspection intervals will be shorter than the 2 years in accordance with relative standards and local government regulations.     

Heat treatment method for making high strength and conductivity Cu–Cr–Zr alloy

Abstract

In this paper, the heat treatment called ‘a two-step aging process’ with the feature of the first step aging at a low temperature for a long time and the second step aging at a higher temperature for a short time has been proposed. Applying this process, the Cu–Cr–Zr alloy possessing both high strength and high conductivity can be acquired due to the formation of numerous tiny particles precipitated fully out from Cu matrix.     

Effect of creep deformation on Z phase formation in Gr.91 steel

Abstract

In order to make clear the effect of creep deformation on Z phase formation in Gr.91 steel, creep interrupted tests were performed for 10?000, 20?000, 30?000, 50?000 and 70?000 h at 600°C under 70 MPa. The time to rupture was 80?736·8 h at 600°C under 70 MPa. Z phase was observed in the vicinity of prior austenite grain boundaries in the grip and gauge portions after creep deformation for 10?000 h and more. Number density of Z phase particles increased with increasing creep time in the grip and gauge portions. The number densities of MX carbonitrides particles in the grip and gauge portions clearly started to decrease after 30?000 h corresponding to increase in number density of Z phase. In the gauge portion, the number density of MX carbonitrides particles was almost the same as that of Z phase particles after creep rupture, meaning that a large number of MX carbonitrides particles were disappeared. The number density of Z phase particles in the gauge portion was 2·5 times of that in the grip portion after creep rupture. This indicates that creep deformation promotes the Z phase formation.     

铁体系催化剂制备方式对催化活性的影响

研究了加料顺序,陈化方式,陈化条件,对Fe(naph)_2—Al(i—Bu)_3——CH_2=CHCl体系催化丁二烯聚合活性的影响。结果发现按Bd+Fe+Cl+Al的加料顺序配制的催化剂的活性高于其它加料顺序;陈化方法不能提高催化剂的活性。