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11.
Stefanos E. Kavargiris Andreas P. Mamolos Constantinos A. Tsatsarelis Anna E. Nikolaidou Kiriaki L. Kalburtji 《Biomass & bioenergy》2009,33(9):1239-1250
An energy analysis, in conventional and organic vineyards, combined with ethanol production and greenhouse gas emissions, is useful in evaluating present situation and deciding best management strategies. The objective of this study was to evaluate the differences in the energy flow between organic and conventional vineyards in three locations, to calculate CO2, CH4 and N2O-emissions based on the used fossil energy and to explore if wine industry wastes can be used to extract bioethanol. The data were collected through personal interviews with farmers during 2004–2005. Eighteen farmers, who owned vineyards about 1 ha each, were randomly selected to participate in this study [(3 conventional and 3 organic) × 3 locations]. The means averaged over all locations for fertilizer application, plant protection products application, transportation, harvesting, labor, machinery, fuels, plant protections products and tools energy inputs, total energy inputs, outputs (grapes), outputs (grapes + shoots), grape yield, man hour, pomace and ethanol from pomace were significantly higher in conventional than in organic vineyards, while the opposite occurred for the pruning. Means averaged over two farming systems for harvesting, tools energy inputs, energy outputs (grapes), grape yield, pomace and ethanol from pomace were significantly higher at location A, followed by location C and location B. Finally, for irrigation, the means averaged over the two farming systems were significantly lower at location C. Greenhouse gas emissions were significant lower in organic than in conventional vineyards. The results show a clear response of energy inputs to energy outputs that resulted from the farming system and location. 相似文献
12.
《International Journal of Hydrogen Energy》2020,45(36):18241-18249
Bioethanol is an eco-friendly biofuel due to its merit that makes it a top-tier fuel. The present study emphasized on bioethanol production from hydrogen-rich syngas through fermentation using Sacharomyces cerevisiea. Syngas fermentation was performed in a tar free fermenter using a syngas mixture of 13.05% H2, 22.92% CO, 7.9% CO2, and 1.13% CH4, by volume. In the fermentation process, effects of various parameters including syngas impurity, temperature, pH, colony forming unit, total organic carbon and syngas composition were investigated. The yield of bioethanol was identified by Gas chromatography-Mass spectrometry analysis and further, it was confirmed by Nuclear magnetic resonance (1H) analysis. From GC-MS results, it is revealed that the concentration of bioethanol using Saccharomyces cerevisiae was 30.56 mmol from 1 L of syngas. Thus, hydrogen-rich syngas is suited for bioethanol production through syngas fermentation using Saccharomyces cerevisiae. This research may contribute to affordable and environment-friendly bioethanol-based energy to decrease the dependency on fossil fuels. 相似文献
13.
《International Journal of Hydrogen Energy》2020,45(21):11923-11942
Hydrogen fuel cells (H2–FCs) are promising devices for pollution-free and efficient power production. Renewable H2 from biomass is often produced through catalytic ethanol steam reforming (ESR), which requires a steam/ethanol molar ratio of at least three. The bioethanol obtained by biomass fermentation contains large amounts of water and can be directly subjected to ESR without complex purification steps. However, a wide spectrum of impurities is present in such bioethanol samples, thus complicating the ESR process. Acetic acid, fusel alcohols, ethyl acetate, and sulfur components have been reported as important bioethanol impurities, and also as the main precursors of carbon deposits on the ESR catalyst. On the other hand, amines, methanol, and aldehydes, which are minor bioethanol impurities, have been reported to enhance the H2 production. This review seeks to define alternatives to reduce the above negative impurities and increase the positive ones during biomass pretreatment and fermentation. Additionally, ESR catalysts are reviewed to identify the features that make them more resistant to deactivation. The combination of strategies to control the impurities during biomass pretreatment, fermentation, purification and the development of highly resistant catalysts may allow processes to produce H2 from biomass with a low carbon footprint, rendering H2–FCs an environmentally friendly technology for power production. 相似文献
14.
《International Journal of Hydrogen Energy》2020,45(33):16409-16420
Hierarchical-Beta zeolites have been hydrothermally synthesized by adding a new gemini organic surfactant. The used gemini surfactant play the role of a “pore-forming agents” on the mesoscale, on the same time, providing alkaline environment for the system. With this hierarchical Beta zeolite as the core support, we successfully prepared a shell layer of Ni-containing (22 wt%) petal-like core-shell-like catalyst and applied it to bioethanol steam reforming. At the reaction temperature of 350 °C–550 °C, the conversion rate of ethanol and the selectivity of hydrogen were always above 85% and 70%. After reaction of 100 h on stream at 400 °C, there were not obvious inactivation could be observed on NiNPs/OH-MBeta catalyst. 相似文献
15.
Recent European Directives promoted the development of biofuels, requesting mandatory limits to their emissions ot greenhouse gases (GHG). Second-generation biofuels based on lignocellulosic biomass are prime candidates but their GHG emissions are variable and uncertain. Agro-ecosystem modeling can capture them and the performance of biofuel feedstocks.This study aimed at optimizing feedstock supply for a bioethanol unit in France, from agricultural residues, annual and perennial crops. Their productivity and environmental impacts were modelled on a regional scale using geo-referenced data on soil properties, crop management, land-use and future weather data. Several supply scenarios were tested. Cereal straw was the most efficient feedstock but had a low availability, and only miscanthus could meet the bioethanol plant's demand. Sorghum combined poor yields and high GHG emissions compared by miscanthus and triticale. A mix of three biomass sources used less than 3% of the regional agricultural land while abating GHG emissions by 60%. 相似文献
16.
The abundance of low-cost feedstock and the cost-effective technology are of great importance for reinforcing industrialization of bioethanol for fuel use as sustainably-sourced and eco-friendly energy. This paper describes improved techniques that increase the root productivity of cassava (Manihot esculenta Crantz) and its conversion to bioethanol by the energy-saving technology being developed in Thailand. The productivity of cassava roots can be significantly increased from 22 to 60 tons/ha simply by applying yield improved varieties and good cultivation practices; important ones are soil plowing, high stake quality, weed control, good planting and harvesting period, land conservation with organic fertilizers and water irrigation. Currently, the world production of cassava is around 220 million tons per annum with the average yield of 12 tons/ha and the total acreage of 18.5 million ha. If the root productivity increases, for instance, by 5 tons/ha, around 90 million tons of roots are produced which can be converted to 15,000 ML of ethanol by Simultaneous Saccharification and Fermentation (SSF) process, a current production process of which cooked and enzymatically-liquefied cassava materials are subjected to saccharifying enzymes and yeasts in concert. The promising energy-saving technology for converting cassava chips to ethanol has also been introduced at a pilot scale by using a granular starch hydrolyzing enzyme in an uncooked process. 相似文献
17.
The combustion of bioethanol in boilers has been analyzed and compared with conventional liquid fuels. The study includes an experimental evaluation of combustion performance as well as the estimation of the impact of replacing gasoil by ethanol on the thermal efficiency of an industrial boiler.Several works have been dedicated to the study of fuel substitution in internal combustion engines, being the use of gasoil-bioethanol blends in engines a common practice. However, very few studies have addressed the characterization of switching of conventional liquid fuels by bioethanol in boilers.Combustion tests demonstrate significant differences between bioethanol and gasoil flames. Soot, NOx and SO2 emissions are significantly lower with ethanol, whereas this fuel can produce higher amounts of CO than gasoil if the burner is not properly adapted. The experimental tests have demonstrated that both the burner and boiler operation should be readjusted or modified as a result of the change of fuel in industrial boilers. If thermal input is to be kept constant, nozzles of larger capacities must be used and the air feeding rate needs to be significantly modified. Also, the flame detector may have to be replaced and the fuel feeding system should be revised due to the enhanced tendency of ethanol to cavitation. Using the same thermal input may not guarantee keeping the same steam production, but some parameters of boiler operation should be modified in order to avoid reductions in the capacity of the boiler when switching from gasoil to bioethanol, such as gas recirculation fraction, steam cooling systems and percentage of oxygen in the exhaust gases.The feasibility of burning bioethanol in gasoil boilers has been analyzed, and the results confirm that fuel switching is technically possible and offers some advantages in terms of pollutants reduction. 相似文献
18.
How are biofuels to be certified as produced in a sustainable and responsible fashion? In the global debate over this issue, one party to the proceedings seems rarely to be mentioned—namely the commodities exchanges through which a global biofuels market is being created. In this contribution, I propose a solution to the problem of sustainability certification through a biofuels futures contract equipped with ‘proof of origin’ documentation. The proposal does not call for any radical break with current practice, extending existing certification procedures with a requirement for the vendor to provide documentation, probably in barcoded form, of the history of the biofuel offered for sale, including plantation and biorefinery where the biofuel was produced and subsequent blendings it may have undergone. The proposal is thus compatible with the blending practices of large global traders, whose activities are the source of the difficulties of other approaches to certification. It is argued that if such a sustainable futures contract for bioethanol (in the first instance) were to be introduced, then it would likely trade at a premium and become the primary vehicle for North–South trade in biofuels. 相似文献
19.
In recent years the focus on sustainable biofuel production from agricultural residues has increased considerably. However, the scientific work within this field has predominantly been concentrated upon bioresources from industrialised and newly industrialised countries, while analyses of the residues from most developing countries remain sparse. In this study the theoretical bioenergy potentials (bioethanol and biogas) of a spectrum of West African agricultural residues were estimated based on their compositions. We analysed 13 of the most common residues: yam peelings, cassava peelings, cassava stalks, plantain peelings, plantain trunks, plantain leaves, cocoa husks, cocoa pods, maize cobs, maize stalks, rice straw, groundnut straw and oil palm empty fruit bunches. The yam peelings showed the highest methane and bioethanol potentials, with 439 L methane (kg Total Solids)−1 and 0.61 L bioethanol (kg TS)−1 based on starch and cellulose alone due to their high starch content and low content of un-biodegradable lignin and ash. A complete biomass balance was done for each of the 13 residues, providing a basis for further research into the production of biofuels or biorefining from West African agricultural residues. 相似文献
20.
This work presents a design methodology for a hybrid energy system based on multiple renewable power sources and bioethanol. The new concept of generation consists on having multiple power sources such as a PEM fuel cell system fed by the hydrogen produced by a bioethanol reformer and wind-solar sources working all together supervised by the energy management system. The necessary heating for the bioethanol reforming reaction can be provided by the renewable sources to enhance the efficiency of the hydrogen production. It is worth noting that, from the power balance as well as backup point of views, the hybrid system is equipped with energy storage devices. An optimal sizing methodology integrated with the energy management strategy is proposed here for designing the overall hybrid system. The suggested approach is based on genetic algorithms, using historical climate data and load demands over a period of one year. Several simulation results are given to show the methodology performance in terms of loss of power supply probability (LPSP), costs and bioethanol consumption. 相似文献