Water: A key resource in energy production

Water and energy are the key resources required for both economic and population growth, and yet both are increasingly scarce. The distribution of water takes large amounts of energy, while the production of energy requires large amounts of water in processes such as thermal plant cooling systems or raw materials extraction. This study analyzes the water needs for energy production in Spain according to the energy source sector (electricity, transportation or domestic) and process type (extraction and refining of raw materials or thermal plant use). Current and future water needs are quantified according to energy demand and technology mix evolution. Hypothetical scenarios that simulate the risks of promoting specific energy policies are also analyzed. Results show that the combination of energy resources used in Spain is projected to be more than 25% more water consumptive in 2030 than in 2005 under ceteris paribus conditions. Renewable energies are mixed in terms of their consequences on the water supply; wind power can reduce water withdrawal, while the biofuels production is a water-intensive process.     

Biochemical Conversion of Microalgae Biomass into Biofuel

Biofuel production via microalgae is a promising and sustainable alternative to replace the typical fossil fuel that is the main contributor to the global warming. However, for a cost‐effective biofuel production, further advanced research is still needed for large‐scale operation. This article is a tutorial review on conversion processes of microalgae into biofuel, with emphasis on biochemical conversion. The following topics are discussed: (i) microalgae biomass and its composition, (ii) thermochemical conversion, (iii) chemical conversion, and (iv) biochemical conversion. In addition, various aspects of anaerobic digestion, digester designs, and effects of operating conditions on the production of methane, bioethanol, and biohydrogen are discussed. The general kinetics of biomass conversion into biofuel is presented. This study suggests, if that biomass contains less than 50 % moisture, then it is recommended to use the direct combustion method; otherwise, biochemical conversion is the most suitable process to biofuel production.     

Analysis and comparison of single period single level and bilevel programming representations of a pre-existing timberlands supply chain with a new biorefinery facility

This research investigates the economic impact of a new biorefinery on an established timberlands system. This paper proposes that a single level model does not adequately represent the interactions in the supply chain. The timberlands system has two major decision makers: harvesters and manufacturers. Bilevel models are two-level turn-based models with each level representing a decision maker. The two levels are interconnected, but neither has control over the decisions of the other. The leader makes an initial decision, and the follower reacts; the leader can anticipate the follower's reaction. To demonstrate the value of this more complex representation, a single period bilevel and a single period single level model were formulated for a representative case study. The separation of objective functions in the bilevel problem yielded decisions different from those of the single level formulation. It was concluded that the bilevel model may more accurately represent the real system.     

Ethanol absorption from CO2 using solutions of glycerol and glycols

CO₂ stripping during fermentation is a possible way of increasing the production of ethanol in distilleries. Ethanol, water, and carbon dioxide are the main compounds in the exiting gas mixture. To date, few studies have proposed the use of absorption to recover ethanol from this mixture or have considered different absorbents for this purpose. This work evaluates different absorbent solutions used to recover ethanol vapor from CO₂ gas. Glycols and glycerol can provide easier separation of ethanol than water, with lower distillation energy demand. A statistical experimental design was used to compare the mass transfers of ethanol from the gas phase to the liquid phase, using solutions of glycerol, ethylene glycol, and diethylene glycol. High concentrations of these substances did not favor the absorption of ethanol. The best results were achieved with 25% absorbent solutions, which offered better options than water for the recovery of ethanol from CO₂ gas in absorption columns and could increase the productivity of first generation bioethanol production.     

A review of the current state of biofuels production from lignocellulosic biomass using thermochemical conversion routes

The rapid increase in energy demand, the extensive use of fossil fuels and the urgent need to reduce the carbon dioxide emissions have raised concerns in the transportation sector. Alternate renewable and sustainable sources have become the ultimate solution to overcome the expected depletion of fossil fuels.The conversion of lignocellulosic biomass to liquid(BtL) transportation fuels seems to be a promising path and presents advantages over first generation biofuels and fossil fuels. Therefore, development of BtL systems is critical to increase the potential of this resource in a sustainable and economic way.Conversion of lignocellulosic BtL transportation fuels, such as, gasoline, diesel and jet fuel can be accomplished through various thermochemical processes and processing routes. The major steps for the production of BtL fuels involve feedstock selection, physical pretreatment, production of bio-oil, upgrading of bio-oil to transportation fuels and recovery of value-added products. The present work is aiming to give a comprehensive review of the current process technologies following these major steps and the current scenarios of biomass to liquid facilities for the production of biofuels.     

Optimal coupling of a biomass based polygeneration system with a concentrated solar power facility for the constant production of electricity over a year

In this paper we address the integration of a polygeneration system based on biomass with a concentrated solar power facility for the constant production of electricity over a year long. The process is modelled as a superstructure embedding two different gasification technologies, direct and indirect, and two reforming modes, partial oxidation or steam reforming followed by gas cleaning and three alternatives for the syngas use, water gas shift reactor (WGSR) to produce hydrogen, a furnace for thermal energy production and an open Brayton cycle. We couple this system with a concentrated solar plant that uses tower technology, molten salts and a regenerative Rankine cycle. The problem is formulated as a multi-period mixed-integer non linear programming problem (MINLP). The optimal integration involves the use of indirect gasification, steam reforming and a Brayton cycle to produce 340 MW of electricity at 0.073 €/kWh and 97 kt/yr of hydrogen as a credit.     

Two stage stochastic bilevel programming model of a pre-established timberlands supply chain with biorefinery investment interests

This work studies the supply allocation problem, using a Stackelberg game, for an established timberlands supply chain with an additional decision of new biorefinery investments. In a timberlands system, harvester and manufacturer decision makers have separate objectives to maximize their respective profits. This interaction is represented with a turn based Stackelberg game. The harvesters decide first on the quantity harvested, and the manufacturers decide on how much to utilize. This game is modeled with a bilevel mathematical program. The novel feature of this paper's bilevel formulation is the inclusion of parametric uncertainty in a two stage model. The first stage problem involves logistical decisions around biorefinery investments, such as location and capacity, while the second stage problem involves a bilevel timberlands model with parameter uncertainty. Studying this problem formulation revealed interesting insights for solving multiperiod problems with bilevel stages as well as the decision maker's behavior for the timberlands model.     

Good or bad bioethanol from a greenhouse gas perspective – What determines this?

The purpose of this study is to describe how the greenhouse gas (GHG) benefits of ethanol from agricultural crops depend on local conditions and calculation methods. The focus is mainly on the fuels used in the ethanol process and biogenic GHG from the soils cultivated. To ensure that “good” ethanol is produced, with reference to GHG benefits, the following demands must be met: (i) ethanol plants should use biomass and not fossil fuels, (ii) cultivation of annual feedstock crops should be avoided on land rich in carbon (above and below ground), such as peat soils used as permanent grassland, etc., (iii) by-products should be utilised efficiently in order to maximise their energy and GHG benefits and (iv) nitrous oxide emissions should be kept to a minimum by means of efficient fertilisation strategies, and the commercial nitrogen fertiliser utilised should be produced in plants which have nitrous oxide gas cleaning. Several of the current ethanol production systems worldwide fullfill the majority of these demands, whereas some production systems do not. Thus, the findings in this paper helps identifying current “good” systems, how today’s “fairly good” systems could be improved, and which inherent “bad” systems that we should avoid.     

Energy use in the rural areas of India: setting up a rural energy data base

Aggregating and forecasting demand are crucial parts of energy planning. While a large number of energy consumption surveys have been conducted in the past in the rural energy sector of India, the lack of sufficient data and its compilation, coupled with doubt about the quality of data, has made the task extremely difficult. This paper summarizes our recent effort to compile, computerize and analyze data from 638 village energy consumption surveys covering over 39,000 households, carried out by different organisations between 1985 and 1989. The details of the level of information provided in the survey reports, area of survey, land use pattern, asset ownership, etc., of the collated studies are presented. Results based on the analysis of the energy consumption data compiled are then discussed. The national average for rural domestic thermal energy consumption (excluding water and space heating) estimated through this work (629 kcal or 2.63 MJ per capita daily) is much similar to the rural domestic thermal energy requirement assumed in most energy planning exercises in India in the past. The useful thermal energy consumption varies from 325 to 1065 kcal/cap/d (1.36-4.46 MJ/cap/d) in the East Coast Plain and Hills and the Eastern Himalayan Regions, respectively. Reconfirming the predominance of firewood, the data reveals that the contribution of firewood to the domestic thermal energy consumption has remained at about 58% over the last three decades; dungcake and agricultural residues contribute almost equally in the remaining share. At the national level, our estimates indicate that at least 180 million tonnes of firewood, 40 million tonnes of dungcakes and 30 million tonnes of agricultural residues were consumed in the rural sector for meeting the domestic thermal energy requirement in 1991. The paper also compares the estimates with those based on other surveys in India.     

Effects of HZSM-5 crystallite size on stability and alkyl-aromatics product distribution from conversion of propanal

The conversion of propanal on large (2–5 µm) and small (0.2–0.5 µm) crystallite HZSM-5 at 400 °C and atmospheric pressure has been studied. Improved catalyst stability was observed on small crystallites due to faster removal of products with the shorter diffusion path length, reducing the formation of coke precursors. As previously shown, C₉ aromatics are the initial aromatics produced from propanal via aldol condensation followed by cyclization and these have less opportunity to crack to lighter aromatics on the small crystallites. Thus, a higher ratio of C₉/(C₈+ C₇) aromatics was observed on the small crystallites. The main isomer of the C₈ aromatic products observed on small crystallites was the initial cracking product of the C₉ aromatics, and thermodynamically preferred, meta-xylene, while the shape-selective preferred para-xylene was the predominant product on large crystallites. The higher internal diffusion rate of the para isomer results in greater shape selectivity with the longer path of the large crystallite zeolite. It is concluded that the use of smaller crystallite HZSM-5 improves results for production of alkyl aromatics from light oxygenates at mild conditions that may prove useful for bio-oil upgrading.