Organic‐acid‐catalyzed sol–gel route for preparing poly(methyl methacrylate)–silica hybrid materials

In this study, a series of organic–inorganic hybrid sol–gel materials consisting of a poly(methyl methacrylate) (PMMA) matrix and dispersed silica (SiO₂) particles were successfully prepared through an organic‐acid‐catalyzed sol–gel route with N‐methyl‐2‐pyrrolidone as the mixing solvent. The as‐synthesized PMMA–SiO₂ nanocomposites were subsequently characterized with Fourier transform infrared spectroscopy and transmission electron microscopy. The solid phase of organic camphor sulfonic acid was employed to catalyze the hydrolysis and condensation (i.e., sol–gel reactions) of tetraethyl orthosilicate in the PMMA matrix. The formation of the hybrid membranes was beneficial for the physical properties at low SiO₂ loadings, especially for enhanced mechanical strength and gas barrier properties, in comparison with the neat PMMA. The effects of material composition on the thermal stability, thermal conductivity, mechanical strength, molecular permeability, optical clarity, and surface morphology of the as‐prepared hybrid PMMA–SiO₂ nanocomposites in the form of membranes were investigated with thermogravimetric analysis, differential scanning calorimetry, dynamic mechanical analysis, gas permeability analysis, ultraviolet–visible transmission spectroscopy, and atomic force microscopy, respectively. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Measuring interdiffusion at an interface between two elastomers with tapping-mode and contact-resonance atomic force microscopy imaging

Despite the common use of tapping-mode atomic force microscopy to image composites or polymer blends, very few studies have focused on the measurement of the interdiffusion at an interface between two polymers in contact. In this study, we show how to assess the interphase between two polymers with two methods. First, stable and robust tapping conditions are established, and the problem of the phase contrast is discussed. Second, a contact-resonance method is presented: the tip in contact with the sample is electrostatically excited at its resonance frequency by a self-controlled oscillator. The gain and frequency images allow us to measure the interdiffusion width. Both methods (using high and weak mechanical solicitation) give the same assessment of the interdiffusion width. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

技术进步经济效益评价——中国长城铝业公司水泥厂产出增长中技术进步作用的评价

本文通过运用“生产函数法”、“增长速度方程”来定量分析技术进步在长城铝业公司水泥厂产出增长中的作用,从中找出该水泥厂生产经营过程中存在的问题及未来发展方向。     

TbFe磁性薄膜的磁力显微镜成像研究

利用磁力显微镜（MFM）对TbFe磁性薄膜进行了不同抬举距离（分别为60～780nm）的磁力成像研究．在实验中，比较了低抬举距离（100nm以下）磁力像中样品-针尖的互相干扰；同时发现在高抬举距离磁力像中，随着抬举距离的增大，出现了与高凸起形貌对应的图像衬度特征，并随抬举距离的变化也改变着位置与强度，一直到抬举距离为仪器的极限值780nm时，形貌干扰仍未消失，对其形成机制进行了分析．     

考虑次内力的桁架结构有限元分析

用有限元软件ANSYS对带式输送机栈桥的桁架结构进行了计算，结合实例着重探讨了考虑次内力时的桁架结构有限元分析在建模过程中需要解决的问题。     

波浪力计算中的一个新边界元方法

本文就波浪与结构物作用问题，提出了一个新的高阶边界元方法。较之Ｅａｔｏｃｋ Ｔｏｙｌｏｒ和Ｃｈａｕ的方法，本文在体内附助积分方程中应用了满足刚性水面条件和弱刚性底面条件的简单格林函数。计算速度相应地有所提高；漂浮结构的积分方程更为简洁；计算结果与Ｅａｔｏｃｋ Ｔａｙｌｏｒ和Ｃｈａｕ的方法具有几乎相同的精度和收敛速度。     

单线循环客运索道设计参数研讨(续三)

论证客运索道设计中的几个重要参数,建立抱索器钳口夹紧力计算公式,第一次给出钳口夹紧力与钢索金属断面积的比值,并进行了钢索弯曲应力计算公式的推导.     

考虑渗流力的基坑涌砂分析

本文根据基坑防渗帷幕周围的地下水渗流特征，分析了渗流力对基坑流砂的影响，提出了按涌砂安全系数进行防渗帷幕埋入深度计算的方法。     

冷弯型钢纵向变形的理论分析及计算

对冷弯型钢的纵向变形过程进行了力学分析，得到了变形微分方程，求得了转动角的理论公式，并对其变形形状进行了分析计算。     

Equilibrium Studies of the System'(Fe,Co)O'–(Fe,Co)3O4 by Solid-State emf Measurements in the Temperature Range 970 to 1370 K

The equilibrium reaction 3'(Fe, Co)O'( ss ) +1/2O₂ ( g ) ⇄ (Fe, Co)₃O₄( ss ) was studied in the temperature range 970 to 1370 K for seven different total compositions of molar ratios 0.5 < Fe/(Fe + Co) ≤ 1.0. The equilibrium pressures of oxygen were determined by using galvanic cells incorporating calcia stabilized zirconia as solid electrolyte and the Fe/Co ratios in the solid-solution phases by wavelength dispersive spectrometry microprobe analyses. The activities of 'FeO' in the cobaltowüstite phase were then derived from the experimental results obtained.