提高湿法烟气脱硫喷淋塔脱硫和除尘效率的探讨

分析了现代大型喷淋塔为提高脱硫与除尘效率在设计上所作的改进及存在的问题。通过一个曾经设计过的喷淋塔实例,结合烟气和吸收液两相逆向流动和两相间的化工传质过程,剖析了喷淋层覆盖率的实质,提出弱效喷淋覆盖和多重喷淋覆盖对喷淋塔脱硫和除尘效率的影响,给出喷淋覆盖率的选择、喷淋层和喷嘴布置的设计方法,对改善烟气脱硫和除尘效率均有明显效果。     

电絮凝法处理化工废水研究

利用电絮凝法处理某企业化工废水,以铝板作为电极板,研究了不同水力停留时间、初始pH、极板间距、电流强度以及温度等单因素对处理效果的影响.在单因素实验的基础上,再进行正交试验,最后进行验证.通过实验得到结果为氨氮去除效果在水力停留时间为4小时,pH=9.0,温度为57℃,电流1A达到最佳,去除率达到36.8%.COD的去除效果在水力停留时间为4小时,pH=6.7,温度为57℃,电流1A达到最佳,去除率达到32.3%;从而有效的达到了对高氨氮、高COD化工废水的预处理效果,方便后续处理设施的有效实施.     

改性钢渣除藻效果研究

对改性钢渣在机械搅拌条件下的除藻效果进行了研究,并分析了改性钢渣预处理与混凝联用工艺对藻类的去除效果和协同作用.实验表明,钢渣经改性后,既能有效地去除水中的藻类,又能降低藻的光合活性,抑制藻的生长;高温活化改性钢渣预处理与混凝联用工艺对藻类有很好的去除效果,其对叶绿素a的平均去除率达91.4％,远高于单纯的钢渣预处理和混凝工艺.这暗示了两者之间在除藻方面存在协同作用.     

多孔悬浮填料SBR工艺和传统SBR工艺的对比研究

为了改善某市污水厂出水水质,对常规SBR法工艺进行技术改造(将悬浮载体活性污泥法工艺应用到SBR工艺曝气池中)。对比平行实验期出水的COD、BOD5、NH4 -N、T-P等化学指标和生物相,检测是否达到预期效果。试验结果显示投加了悬浮填料的SBR池较普通的SBR池活性污泥系统内的生物种类、存在方式及基质的分配与传质方式都有明显的改善,表现出良好的耐水量和水质冲击的能力,出水的COD、BOD5、NH4 -N、T-P的去除率分别由原来的67.9%、81.6%、56.4%、62.5%提高到78.4%、88.9%、69.2%、74.2%。文中实验研究是针对变水位SBR工艺等间歇式曝气池,突破了悬浮填料工艺主要应用于恒水位连续式曝气池,这对于已建水厂的技术改进具有很强的实用性。     

Bioelectrochemical sulfate reduction enhanced nitrogen removal from industrial wastewater containing ammonia and sulfate

Low organic carbon-to-nitrogen ratio and existing sulfate (SO₄²⁻) in industrial wastewater limited nitrogen removal. Coupling SO₄²⁻ reduction with sulfide autotrophic denitrification provides a novel strategy. Herein, bioelectrochemical sulfate reduction was coupled with heterotrophic sulfate reduction to drive sulfide autotrophic denitrification. In this coupled system, total nitrogen (TN) removal efficiency was increased from ~25% to ~85% by inputting −45 mA electricity. With the help of supplying electrons to denitrification through SO₄²⁻ reduction, coulomb efficiency was improved to 61.5%. Also, bioelectrochemical sulfate reduction could improve sulfur recovery and thus increase TN removal efficiency. Furthermore, through tuning turnover numbers of SO₄²⁻, high TN removal efficiency can be obtained at various concentrations of SO₄²⁻. Moreover, main functional bacteria in this system were identified. Finally, ~75% TN removal efficiency was achieved with real wastewater in this system. Overall, this work offered a new approach for efficient nitrogen removal from industrial wastewater containing SO₄²⁻.     

Feasibility study of the ultrasonic vibration assisted drilling of Inconel superalloy

The ultrasonic vibration assisted drilling of Inconel 718 superalloy is studied in this paper. The tool holder of a machining center is retrofitted so that axial resonant vibration can be provided. Experimental results show that the chip size is reduced, and the variation of torque in drilling becomes smaller. These phenomena are particularly apparent at the final stage of a drill's usable life. It is also found that there is little improvement in drilling performance when the frequency of the ultrasonic vibration is varied. On the contrary, a drill's life is greatly increased when the vibration with a smaller amplitude is applied. But too large a vibration amplitude, such as over 12 μm in this study, could lead to negative effects. For the testing conditions, the frequency of 31.8 kHz and the amplitude of 4 μm result in the best drill life and quality of the drilled hole in this study. Under this condition a drill's life is prolonged by as much as 2.7 times of that without vibration assisted drilling process. Concerning drilling efficiency, it is found that by applying ultrasonic vibration assisted drilling, lifting of the drill for chip removal as commonly employed in conventional drilling of a high aspect ratio hole is not necessary, and saving of the working time is obtained.     

淬硬工具钢内圆表面磁性研磨加工实践与研究

磁性磨料研磨是一种较新的光整加工的方法，它是在S、N两极之间加入磁性磨料，磁性磨料吸附在磁极和工件表面上，并沿磁力线方向排列成有一定柔性的“磨料刷”，工件一边旋转，一边做轴向振动，以达到去除表层金属的目的，使工件表面粗糙度大大下降。本文介绍了磁性磨料研磨的加工原理，对工件在磁场中的受力情况进行理论分析。对淬硬工具钢(T8A)工件内圆表面进行磁性磨料研磨的加工试验．得出了不同的磁感应强度，不同加工间隙，以及不同研磨时间对加工表面粗糙度和研磨量的影响；从而得出了优化的磁性磨料研磨的加工参数：磁感应强度B=1．0—1．2T；加工间隙△=1-3mm；研磨时间t=4—5min。     

Nitrogen removal using recycled polystyrene bottles as biofilm media

The performance of an attached growth wastewater treatment process was investigated in an effort to improve nitrogen removal efficiency. Recycled Yakult (lactic acid fermentation drink) bottles made of polystyrene were used as a biofilm media. The use of Yakult bottles as a biofilm media has been attempted by numerous researchers in Japan for the removal of solids and organics. However, these studies focused only on the removal of solids and organics. This study extended their application to the removal of nitrogen for domestic sewage treatment. Yakult media was placed in a reactor with 70% apparent reactor volume in a conventional A/O process. The bottom of the Yakult media was removed, and randomly filled Yakult media were effectively able to reduce the flow in tanks, resulting in an increase in the contact time between pollutants and microorganisms. With higher HRT, the nitrogen removal efficiency was increased by up to 83% with 12 hr of HRT. Nitrification appeared to be the limiting factor of nitrogen removal at an HRT that is less than 12 hr, indicating that the Yakult process requires more retention time to achieve nitrification compared to other biofilm processes. The removal efficiencies of organics and solids were high regardless of the change of operational parameters. This article is based on a presentation in “The 7th Korea-China Workshop On Advanced Materials” organized by the Korea-China Advanced Materials Cooperation Center and the China-Korea Advanced Materials Cooperation Center, held at Ramada Plaza Jeju Hotel, Jeju Island, Korea on August 24–27, 2003.     

Thermal spray vitrification process for the removal of lead-based paint from steel structures: An applications note

Lead-based paints and primers have long been used to protect steel structures from corrosion, but are now recognized as environmental hazards. During lead-based paint removal via abrasive blasting, federal, state and local environmental requirements mandate the use of containment structures to prevent contamination of air, soil, or water. The thermal spray vitrification (TSV) process was developed and optimized in laboratory experiments to remove hazardous lead-based paint. TSV consists of thermal spraying a molten glass onto the painted surface. As the glass strikes the substrate, it reacts with the paint, and organic components are pyrolyzed, while lead ions are trapped on the glass surface. Quenching stresses in the glass cause it to crack and spall off the substrate. The resulting glass fragments are collected, and further remelted to completely immobilize lead (Pb) ions in the glassy iron (Fe) silicate matrix. The glass waste is thus rendered non-hazardous, as determined by the Toxicity Characteristic Leaching Procedure (TCLP). The TSV process was field tested on a fire hydrant, using minimal personal protective equipment and without using a containment structure. The lead-containing paint was removed, without producing hazardous waste, leaving de-painted surfaces suitable for repainting.     

High-throughput drilling of titanium alloys

Experiments of high-throughput drilling of Ti–6Al–4V at 183 m/min cutting speed and 156 mm³/s material removal rate (MRR) using a 4 mm diameter WC–Co spiral point drill were conducted. The tool material and geometry and drilling process parameters, including cutting speed, feed, and fluid supply, were studied to evaluate the effect on drill life, thrust force, torque, energy, and burr formation. The tool wear mechanism, hole surface roughness, and chip light emission and morphology for high-throughput drilling were investigated. Supplying the cutting fluid via through-the-drill holes has proven to be a critical factor for drill life, which can be increased by 10 times compared to that of dry drilling at 183 m/min cutting speed and 0.051 mm/rev feed. Under the same MRR of 156 mm³/s with a doubled feed of 0.102 mm/rev (91 m/min cutting speed), over 200 holes can be drilled. The balance of cutting speed and feed is essential to achieve long drill life and good hole surface roughness. This study demonstrates that, using proper drilling process parameters, spiral point drill geometry, and fine-grained WC–Co tool material, the high-throughput drilling of Ti alloy is technically feasible.