吉林省部分地区食品中铅、镉污染状况分析

通过监测吉林省2001～2004年6个地区食品中铅、镉含量,了解铅、镉的污染状况,并提出铅、镉可能的污染来源.按照国家标准方法GB/T5009对样品进行前处理,采用石墨炉原子吸收光谱法检测铅、镉含量.2001年～2004年共监测13类917份食品中铅、镉含量,铅超标率为9.49%,镉超标率在6.24%.结果显示目前食品中铅、镉污染不严重,但由于各类食品中铅、镉都有检出,说明存在不同程度的积累,对人体健康存在潜在的威胁。     

石墨炉原子吸收法测定嘉陵江活鱼中的铅和镉

采用浓硫酸-高氯酸对嘉陵江北碚段鲫鱼、草鱼、白鲢不同组织器官进行消解处理,结合石墨炉原子吸收分光光度法测定鱼组织器官中铅、镉的含量,并对测定结果进行了分析。此种方法快速、高效,精密度高。     

Studies on sorption of Cd(II) on Tata chromite mine overburden

Chromite mine overburden containing iron as oxide/hydroxide, a waste material generated in chromite mines was used as sorbent for cadmium. The iron content of material was 43.75% with a specific surface area of 50.8m(2)/g. Batch experiments were conducted to study the sorption behavior of Cd(II) on this material. The variable experimental parameters were: time, pH, temperature, Cd(II) and sample concentration. The point of zero charge (PZC) of the overburden sample was experimentally determined as 6.48 which shifted to a pH of 7.8 when the sample was equilibrated with 100 mg/L Cd(II) solution. Maximum loading capacity of the overburden sample was found to be approximately 19 mg Cd/g of material. It was observed that within 30 min the sorption attains equilibrium. Hence, the sorption data generated at 30 min with various initial Cd(II) concentrations and temperatures were taken to evaluate the thermodynamic parameters, i.e., DeltaG degrees , DeltaH degrees and DeltaS degrees . The DeltaG degrees values reflect the feasibility of the metal removal from aqueous solution. The negative values of DeltaH degrees confirmed the exothermic sorption of cadmium and the positive DeltaS degrees values suggested the increased randomness at the solid-solution interface. The sorption data fitted well to both the Langmuir and Freundlich isotherm models indicating a monolayer sorption. The value of Freundlich parameter 'n' (n is indicative of sorption intensity) lying between 1.46 and 1.59 shows that the surface of the sorbent is heterogeneous in nature.     

Novel 2D Zn-porphyrin metal organic frameworks revived CdS for photocatalysis of hydrogen production

The main challenge of photocatalysis is how to improve the coefficient of utilization and conversion rate for solar energy. Herein, we report a composite photocatalyst related to a novel porphyrin metal organic frameworks (MOFs), in which cadmium sulfide nanoparticles (CdS NPs) are grown in situ on the surface of two-dimensional (2D) zinc porphyrin nanosheets (Zn-TCPP NSs) by hydrothermal method. Interestingly, Zn-TCPP NSs and CdS NPs form a Type II heterojunction structure, which reduces the photogenerated electron-hole recombination rate of CdS. Moreover, in the near-infrared region, the photo-excited electrons generated by Zn-TCPP NSs are transmitted to CdS NPs, so that cadmium sulfide can realize both visible light and near-infrared light for photocatalytic hydrogen production. The Zn-TCPP NSs not only has excellent light absorption capacity, but also has a unique frame design that effectively reduces the recombination rate of photoinduced electron hole pairs, thus improving the conversion rate of solar energy. As expected, the photocatalytic performance of the porphyrin MOFs modified materials is significantly enhanced compared to CdS NPs. The hydrogen production rate of the Pt@CdS NPs/Zn-TCPP NSs(C-Z-T) composite material in the visible light region is about 15.3 mmol g^?1 h^?1, which is 11 times for Pt@CdS NPs. Furthermore, the Pt@CdS NPs/Zn-TCPP NSs(C-Z-T) also has a considerable hydrogen production rate in the near-infrared region, such as 200 μmol g^?1 h^?1 at 600 nm, 90 μmol g^?1 h^?1 at 765 nm and 20 μmol g^?1 h^?1 at > 800 nm.     

In-situ synthesis of ternary heterojunctions via g-C3N4 coupling with noble-metal-free NiS and CdS with efficient visible-light-induced photocatalytic H2 evolution and mechanism insight

The two-dimensional (2D) graphitic carbon nitride (g-C₃N₄) nanosheets based composites are prepared in the form of the NiS/g-C₃N₄, CdS/g-C₃N₄ and CdS/NiS/g-C₃N₄ using a facile and reliable method of chemical deposition. The TEM and HRTEM images demonstrated a spectacular representation of the 2D lamellar microstructure of the g-C₃N₄ with adequately attached CdS and NiS nanoparticles. The changes in crystallinity and the surface elemental valence states of composites with the incorporation of two metal sulphides are studied, which confirmed the formation of composites. The photocatalytic response of the composites was estimated by photodegradation of Rhodamine B (C₂₈H₃₁ClN₂O₃–RhB), and the ternary composite CdS/NiS/g-C₃N₄ samples exhibited the superior photocatalytic performance. Further, the free radical capture and electron paramagnetic resonance (EPR) spectroscopy experiments identified the main active species that contributed to the photocatalytic reaction. Besides, the samples’ photocatalytic performance was evaluated by photocatalytic hydrogen production. The stability of the performance-optimized composite was determined by employing cyclic experiments over five cycles. The CdS/NiS/g-C₃N₄ showed the highest efficiency of hydrogen production i.e. about 423.37 μmol.g^?1.h^?1, which is 2.89 times that of the pristine g-C₃N₄. Finally, two types of heterojunction structures were proposed to interpret the enhanced photocatalytic efficiency.     

Direct Z-Scheme NiWO4/CdS nanosheets-on-nanorods nanoheterostructure for efficient visible-light-driven H2 generation

Exploiting efficient catalysts is of interest for solar-driven water splitting. Herein, a novel NiWO₄/CdS nanosheets-on-nanorods direct Z-Scheme heterostructure was developed by using a facile in-situ approach. The optimized NiWO₄/CdS heterostructure shows a H₂ evolution rate of 26.43 mmol g^?1 h^?1 exceeding that of bare CdS by more than 75 folds. Systematic investigations reveal the nanostructures with numerous active sites, intimate contact interface, and enhanced charge separation rate synergistically account for the outstanding performance of the NiWO₄/CdS. Moreover, the band structures were detailedly analyzed and the tentative photocatalytic mechanism was proposed, which could contribute to deeply understanding the catalytic process and guide the synthesis of the efficient heterostructure. These findings and strategies may have great significance in promoting the development of highly efficient and low-cost photocatalysts.     

The effect of titanium dioxide-supported CdSe photocatalysts enhanced for photocatalytic glucose electrooxidation under UV illumination

The wetness impregnation method was used to synthesize 0.1% CdSe/TiO₂ photocatalysts with different atomic molar ratios (90–10, 70–30, 50–50, and 30–70). These catalysts were characterized by XRD, SEM-EDX and mapping, TEM-EDS, UV–VIS spectroscopy, fluorescence spectroscopy, XPS, TPR, TPO, and TPD analyses. Cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) analyses were performed to examine the photocatalytic activity for photocatalytic fuel cells (PFCs) in glucose solution in the dark and under UV illumination. The characterization analyses revealed that anatase TiO₂ formed the catalyst and electronic structure and surface properties changed when doped with metal. The photocatalytic glucose electrooxidation (PGE) results demonstrate that the 0.1% CdSe(50-50)/TiO₂ catalyst has higher photocatalytic activity, stability, and resistance than other catalysts both in the dark (2.71 mA cm^?2) and under UV illumination (7.20 mA cm^?2). These results offer a promising new type of photocatalyst for PFC applications.     

Sawdust--a green and economical sorbent for the removal of cadmium (II) ions

The ability of sawdust (treated and untreated) waste, a waste material derived from the commercial processing of cedrus deodar wood for furniture production, to remove/preconcentrate Cd(II) ions from aqueous solution was determined. Sorption was found to be rapid (approximately 97% within 8 min). The binding of metal ions was found to be pH dependent, optimal sorption accruing at around pH 4-8. Potentiometric titrations of sawdust revealed two distinct pK(a) values, the first having the value similar to carboxylic groups (3.3-4.8) and second comparable with that of amines (8.53-10.2) with the densities 1.99 x 10(-4) and 7.94 x 10(-5), respectively. Retained Cd(II) ions were eluted with 5 ml of 0.1 mol l(-1) HCl. Detection limit of 0.016 microg ml(-1) was achieved with enrichment factors of 120. Recovery was quantitative using sample volume of 600 ml. The Langmuir and D-R isotherm equations were used to describe partitioning behavior for the system at different temperatures. Kinetic and thermodynamic behavior of sawdust for Cd(II) ions removal was also studied.     

Heavy metal exposure in patients suffering from electromagnetic hypersensitivity

Background

Risks from electromagnetic devices are of considerable concern. Electrohypersensitive (EHS) persons attribute a variety of rather unspecific symptoms to the exposure to electromagnetic fields. The pathophysiology of EHS is unknown and therapy remains a challenge.

Objectives

Heavy metal load has been discussed as a potential factor in the symptomatology of EHS patients. The main objective of the study was to test the hypothesis of a link between EHS and heavy metal exposure.

Methods

We measured lead, mercury and cadmium concentrations in the blood of 132 patients (n = 42 males and n = 90 females) and 101 controls (n = 34 males and n = 67 females).

Results

Our results show that heavy metal load is of no concern in most cases of EHS but might play a role in exceptional cases.

Conclusions

The data do not support the general advice to heavy metal detoxification in EHS.     

Prevalence and predictors of exposure to multiple metals in preschool children from Montevideo, Uruguay

The extent of children's exposure to multiple toxic metals is not well described in many developing countries. We examined metal exposures in young children (6-37 months) from Montevideo, Uruguay and their mothers (15-47 years) participating in a community-based study. Hair samples collected from 180 children and their mothers were analyzed for: lead (Pb), cadmium (Cd), manganese (Mn), and arsenic (As) concentration using inductively coupled plasma-mass spectrometry (ICP-MS). Median metal levels (μg/g) were: Pb 13.69, Mn 1.45, Cd 0.17, and As 0.09 for children and Pb 4.27, Mn 1.42, Cd 0.08, and As 0.02 for mothers. Of the child and maternal samples, 1.7% and 2.9% were below the limit of detection (LOD) for Cd, and 21.3% and 38.5% were below the LOD for As, respectively. Correlations between maternal and child levels ranged 0.38-0.55 (p < 0.01). Maternal hair metal levels were the strongest predictors of metal concentrations in children's hair. Girls had significantly lower As levels than boys (p < 0.01) but did not differ on other metals. In addition, in bivariate logistic regressions predicting the likelihood that the child would be exposed to multiple metals, hemoglobin < 10.5 g/dL (OR = 2.12, p < 0.05), blood lead (OR = 1.17, p < 0.01), and the mother being exposed to two or more metals (OR = 3.34, p < 0.01) were identified as significant predictors of increased likelihood of multiple metal exposure. Older child age (OR = 0.96, p < 0.05), higher maternal education (OR = 0.35, p < 0.01), and higher number of household possessions (OR = 0.83, p < 0.01) were significantly associated with decreased likelihood of multiple metal exposure. Preschool children in Uruguay are exposed to multiple metals at levels that in other studies have been associated with cognitive and behavioral deficits. Sources of exposure, as well as cognitive and behavioral consequences of multiple metal exposure, should be investigated in this population.