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31.
Biodegradable multiblock poloxamers (BMPs) with gel duration of 8 h to several weeks were prepared by varying their molecular weights from 4000 to 40 000 g mol?1. The molecular weight of the BMP was controlled by changing the poloxamer to coupling agent ratio. Assuming a micelle packing model of the BMP gel, as in the case of a poloxamer gel, the micelle properties and critical gel concentration of BMPs were investigated on the basis of the scaling concept. The findings suggest that the control of molecular weight by hydrolyzable groups can be a facile approach to optimize the gel properties for biomedical applications. Copyright © 2005 Society of Chemical Industry 相似文献
32.
不饱和烃硅氢加成催化剂固载化研究进展 总被引:3,自引:2,他引:1
综述了各类负载过渡金属的催化剂体系及其在不饱和烃硅氢加成反应中的应用。负载过渡金属的催化剂具有良好的可回收性和选择性,研究主要集中在开发价廉、使用安全、环境友好和高催化性能的活性炭、氧化物或有机聚合物等负载过渡金属催化剂,并取得很好的结果。 相似文献
33.
The d.c. electrical conductivity of sodium vanadate, rubidium vanadate, cesium vanadate and their solid solutions sodium-rubidium
vanadate and sodium-cesium vanadate were studied by a two-probe method in the temperature range covering their transition
points. The electrical conductivity shows sharp change at the phase transition temperature of these materials. In NaVO3, RbVO3 and CsVO3, increase in d.c. conductivity is observed in the ferroelectric region while nonlinearities are observed above transition
temperatures. In solid solutions, the activation energy in the paraelectric state is higher than that in the ferroelectric
state and depends upon sodium concentration. 相似文献
34.
Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopy was used to characterize the ferroelectric behavior of a thin poly(vinylidene fluoride–trifluoroethylene) P(VDF–TrFE) copolymer. The lab-built GIRA-FTIR apparatus allowed the heating and corona poling process to be carried out whilst collecting the GIRA spectra of the thin polymer film. The Curie transition from the ferroelectric to paraelectric phase was confirmed from the abrupt change in intensity of the 849 cm−1 band in the RA-FTIR spectrum. It was found that the Curie temperature dropped dramatically when the film thickness was lowered to below a certain critical value of approximately 100 nm. The switching of the CF2 dipoles in the ferroelectric crystals after applying the external electric field could be determined by monitoring the change in the 849 cm−1 band intensity. For the 600 nm thick P(VDF–TrFE) film, the switching of the dipoles appears to occur almost instantaneously, while the kinetics of dipole switching of the 75 nm thick film were significantly retarded. The repeated switchability of the CF2 dipoles upon the application of a bipolar cyclic electric field was also confirmed. The bistability of the film due to remnant polarization was also confirmed from the absorbance of the 849 cm−1 band after removing the applied voltage during corona poling. 相似文献
35.
36.
Ali J. Koshkouei 《International Journal of Adaptive Control and Signal Processing》2008,22(9):859-874
Passivity with sliding mode control for a class of nonlinear systems with and without unknown parameters is considered in this paper. In fact, a method for deriving a nonlinear system with external disturbances to a passive system is considered. Then a passive sliding mode control is designed corresponding to a given storage function. The passivity property guarantees the system stability while sliding mode control techniques assures the robustness of the proposed controller. When the system includes unknown parameters, an appropriate updated law is obtained so that the new transformed system is passive. The passivation property of linear systems with sliding mode is also analysed. The linear and nonlinear theories are applied to a simple pendulum model and the gravity‐flow/pipeline system, respectively. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
37.
Manipulation of molecular orientation alignment in MCTLCPs (main-chain thermotropic liquid crystalline polymers) by pure shear at nano scale has been investigated for the first time using molecular dynamics (MD) simulation. Results indicate that high planar shear induces long-range uniform orientation ordering (liquid crystalline phase) of initially randomly orientated molecules of MCTLCP fluid confined in a nanochannel, which is confirmed by analyzing the orientation order parameter and the snapshots of MCTLCP liquid in a nanochannel under different shear rates. Insights into the origin of the phase transition phenomena are given at molecular level through investigating the thermodynamic density distribution of MCTLCP molecules in the nanochannel, suggesting that the energy shift due to a radical jump of system density affects both the magnitude and the orientation of the molecular ordering. Simulation results also show that there is a critical shear rate for transforming isotropic phase into liquid crystalline phase. The critical shear rate is dependent on the temperature of the MCTLCP system. Findings in this paper may present useful information for processing TLCP molecules at nano scale and the understanding of nanoflow. 相似文献
38.
39.
Sangkwon Jeong 《低温学》2004,44(4):241-248
This paper describes transient numerical modeling for thermal characteristic of vapor-cooled current leads under pulse operation. The transient thermal analysis considers the temperature difference between a helium gas flow and a copper lead with temperature dependent properties of helium gas, copper and stainless steel. The numerical analysis was validated by an experiment with commercially available 100 A vapor-cooled current leads. A proper overloading factor calculation and the effect of intermediate cooling are presented for the current leads under pulse operation, which can significantly reduce heat input to a cryostat. 相似文献
40.
Y. MURAKAMI K. TAKAHASHI R. KUSUMOTO 《Fatigue & Fracture of Engineering Materials & Structures》2003,26(6):523-531
ABSTRACT The fatigue crack growth behaviour of 0.47% carbon steel was studied under mode II and III loadings. Mode II fatigue crack growth tests were carried out using specially designed double cantilever (DC) type specimens in order to measure the mode II threshold stress intensity factor range, ΔKIIth. The relationship ΔKIIth > ΔKIth caused crack branching from mode II to I after a crack reached the mode II threshold. Torsion fatigue tests on circumferentially cracked specimens were carried out to study the mechanisms of both mode III crack growth and of the formation of the factory‐roof crack surface morphology. A change in microstructure occurred at a crack tip during crack growth in both mode II and mode III shear cracks. It is presumed that the crack growth mechanisms in mode II and in mode III are essentially the same. Detailed fractographic investigation showed that factory‐roofs were formed by crack branching into mode I. Crack branching started from small semi‐elliptical cracks nucleated by shear at the tip of the original circumferential crack. 相似文献