第62届世界铸造会议宣读论文综述(有色金属部分)

详细介绍了第 62届世界铸造会议中有关有色合金铸造的 6篇宣读论文。“铝合金压铸的压力传递与铸件质量的关系”一文提出一种新的测量铝合金压铸型腔中压力传递的方法 ,搞清了压力传递、流速与铸件质量之间的关系 ,获得了本届会议的优秀论文奖。“挤压压铸和半固态铸造生产高质量、复杂的铸件”一文展示了应用压铸高技术 ,生产出力学性能极高的汽车用复杂压铸件。“监控金属型、压铸模温度的智能系统”一文提出的智能控温系统 ,测温可靠 ,能自动控制铸型温度 ,铸型中不需开冷却水孔道。“制造金属基复合材料的复合铸造工艺 (Hybrid)”一文介绍了一种挤压铸造和熔模铸造相结合生产金属基复合材料的新工艺。“喷铸法制取铝基SiCp增强复合材料的微观组织和磨耗特性”一文指出用喷铸法制取的铝基SiCp增强复合材料 ,具有很高的耐磨性能。“不同凝固条件下 ,Na ,Ca含量对加Sb变质的 3 5 6合金力学性能的影响”一文的作者通过大量试验 ,搞清了Na ,Ca的有害作用 ,指出 3 5 6合金的σb 与δ之间存在下列关系 :σb(MPa) =2 5 .87lgδ( % ) 12 8.85。     

Automatic generation algorithm of expected results for testing of component-based software system

ContextA component-based software (CBS) system is a typical example of a composite component, which is composed of two or more atomic components. In the test of a CBS system, it is necessary to automatically generate expected results because they are compared with the actual results.ObjectiveThis paper proposes an automatic generation algorithm of expected results for the testing of a CBS system.MethodThe algorithm analyzes Input/Output (I/O) relationships of a CBS system to identify inputs that influence its outputs. Then, the algorithm uses test cases of atomic components for each input and automatically generates expected results. To evaluate the proposed approach, we compare the proposed approach with the other I/O relationship based approach via two case studies which are the CBS systems for guide robot. The comparison shows the effectiveness of our approach.ResultsTo verify effectiveness of the proposed approach, we measure the cost of manual generation of expected results for each case study. The costs are from 0.001 to 0.015 in the first case study, and are from 0.590 to 0.998 in the second case study.ConclusionThis proposed approach reduces the time-consuming and error-prone task which manually generates expected results for the testing of a CBS system.     

Effective composite image detection method based on feature inconsistency of image components

This paper proposes an effective composite image detection method that uses the feature inconsistency of image components of the composite image to detect tampered regions. The composite image is first divided into image components. Next, the variance of the noise remaining after de-noising in each image component is calculated and used as a feature. Finally, tampered regions are detected using this feature based on a tampering detection rule. Experimental results show that the proposed method has good composite image detection performance.     

卫星信号模拟器CBOC中频信号设计与实现

GNSS卫星信号模拟器对于GNSS系统及用户接收机的研究和设计起着非常重要的作用。本文主要研究针对Galileo系统E1频点CBOC中频信号的产生方法及数字处理技术,在基于PCIE+DSP+FPGA+DAC架构的中频板卡上完成了与PC上位机通信、波形控制参数计算和更新、副载波生成、基带信号调制以及模拟中频信号的产生;最后给出了频谱、相关峰、定位误差等测量结果,验证了信号的质量和正确性。     

Nonlinear gliding stability and control for vehicles with hydrodynamic forcing

This paper presents Lyapunov functions for proving the stability of steady gliding motions for vehicles with hydrodynamic or aerodynamic forces and moments. Because of lifting forces and moments, system energy cannot be used as a Lyapunov function candidate. A Lyapunov function is constructed using a conservation law discovered by Lanchester in his classical work on phugoid-mode dynamics of an airplane. The phugoid-mode dynamics, which are cast here as Hamiltonian dynamics, correspond to the slow dynamics in a multi-time-scale model of a hydro/aerodynamically-forced vehicle in the longitudinal plane. Singular perturbation theory is used in the proof of stability of gliding motions. As an intermediate step, the simplifying assumptions of Lanchester are made rigorous. It is further shown how to design stabilizing control laws for gliding motions using the derived function as a control Lyapunov function and how to compute the corresponding regions of attraction.     

Progress of Phosphate-based Polyanion Cathodes for Aqueous Rechargeable Zinc Batteries

Aqueous rechargeable zinc batteries (ARZBs) are recently prevailing devices that utilize the abundant Zn resources and the merits of aqueous electrolytes to become a competitive alternative for large-scale energy storage. Benefiting from the unique inductive effect and flexible structure, the past five years have experienced a diversiform of phosphate-based polyanion materials that are used as cathodes in ARZBs. In this review, the most recent advances in the Zn²⁺ storage mechanisms and electrolyte optimization of the phosphate-based cathodes of ARZBs, which mainly focus on vanadium/iron-based phosphates and their derivatives are presented. Furthermore, in addition to significant progress on polyanion phosphate-based cathode materials, the design strategies both for electrode materials and compatible electrolytes are also elaborated to improve the energy density and extend the cycling life of aqueous Zn/polyanion batteries.     

Interfacial Proton Supply/Filtration Regulates the Dynamics of Electrocatalytic Nitrogen Reduction Reaction: A Perspective

As a promising energy carrier, ammonia synthesis by electrocatalytic nitrogen reduction reaction (eNRR) is a promising green and low-carbon ammonia synthesis strategy that can replace the traditional Haber–Bosch process. However, the development of eNRR processes is mainly severely constrained by competitive hydrogen evolution reaction (HER), and the corresponding strategies to inhibit this adverse side reaction to obtain high eNRR selectivity are still limited. In addition, for this complex reaction involving gas–liquid–solid three-phase interface and proton/electron transfer, it is great significance to analyze and summarize the existing inhibition HER strategies from the viewpoint of dynamics. In view of this, this work reviews proton supply/filtration regulation strategy in catalytic system, allowing a systematic survey of the literature focusing on interface membrane regulation (inorganic membrane and organic membrane), electrolyte regulation (metal-mediated strategy and electrolyte ion regulation strategy) and system device design (electrode structure design and electrolytic cell device design). Constructive catalytic system design guidance is also suggested to inhibit hydrogen evolution and improve NH₃ selectivity, aiming for scalable and economically feasible applications.     

Inorganic Filler Enhanced Formation of Stable Inorganic-Rich Solid Electrolyte Interphase for High Performance Lithium Metal Batteries

Lithium metal (LM) is a promising anode material for next generation lithium ion based electrochemical energy storage devices. Critical issues of unstable solid electrolyte interphases (SEIs) and dendrite growth however still impede its practical applications. Herein, a composite gel polymer electrolyte (GPE), formed through in situ polymerization of pentaerythritol tetraacrylate with fumed silica fillers, is developed to achieve high performance lithium metal batteries (LMBs). As evidenced theoretically and experimentally, the presence of SiO₂ not only accelerates Li⁺ transport but also regulates Li⁺ solvation sheath structures, thus facilitating fast kinetics and formation of stable LiF-rich interphase and achieving uniform Li depositions to suppress Li dendrite growth. The composite GPE-based Li||Cu half-cells and Li||Li symmetrical cells display high Coulombic efficiency (CE) of 90.3% after 450 cycles and maintain stability over 960 h at 3 mA cm⁻² and 3 mAh cm⁻², respectively. In addition, Li||LiFePO₄ full-cells with a LM anode of limited Li supply of 4 mAh cm⁻² achieve capacity retention of 68.5% after 700 cycles at 0.5 C (1 C = 170 mA g⁻¹). Especially, when further applied in anode-free LMBs, the carbon cloth||LiFePO₄ full-cell exhibits excellent cycling stability with an average CE of 99.94% and capacity retention of 90.3% at the 160th cycle at 0.5 C.     

Catalytically Induced Robust Inorganic-Rich Cathode Electrolyte Interphase for 4.5 V Li||NCM622 Batteries

Tailoring inorganic components of cathode electrolyte interphase (CEI) and solid electrolyte interphase (SEI) is critical to improving the cycling performance of lithium metal batteries. However, it is challenging due to complicated electrolyte reactions on cathode/anode surfaces. Herein, the species and inorganic component content of the CEI/SEI is enriched with an objectively gradient distribution through employing pentafluorophenyl 4-nitrobenzenesulfonate (PFBNBS) as electrolyte additive guided by engineering bond order with functional groups. In addition, a catalytic effect of LiNi_0.6Mn_0.2Co_0.2O₂ (NCM622) cathode is proposed on the decomposition of PFBNBS. PFBNBS with lower highest occupied molecular orbital can be preferentially oxidized on the NCM622 surface with the help of the catalytic effect to induce an inorganic-rich CEI for superior electrochemical performance at high voltage. Moreover, PFBNBS can be reduced on the Li surface due to its lower lowest unoccupied molecular orbital , increasing inorganic moieties in SEI for inhibiting Li dendrite generation. Thus, 4.5 V Li||NCM622 batteries with such electrolyte can retain 70.4% of initial capacity after 500 cycles at 0.2 C, which is attributed to the protective effect of the excellent CEI on NCM622 and the inhibitory effect of its derived CEI/SEI on continuous electrolyte decomposition.     

A Stable Polymer-based Solid-State Lithium Metal Battery and its Interfacial Characteristics Revealed by Cryogenic Transmission Electron Microscopy

Solid-state lithium metal batteries (SSLMBs) are a promising candidate for next-generation energy storage systems due to their intrinsic safety and high energy density. However, they still suffer from poor interfacial stability, which can incur high interfacial resistance and insufficient cycle lifespan. Herein, a novel poly(vinylidene fluoride‑hexafuoropropylene)-based polymer electrolyte (PPE) with LiBF₄ and propylene carbonate plasticizer is developed, which has a high room-temperature ionic conductivity up to 1.15 × 10⁻³ S cm⁻¹ and excellent interfacial stability. Benefitting from the stable interphase, the PPE-based symmetric cell can operate for over 1000 h. By virtue of cryogenic transmission electron microscopy (Cryo-TEM) characterization, the high interfacial compatibility between Li metal anode and PPE is revealed. The solid electrolyte interphase is made up of an amorphous outer layer that can keep intimate contact with PPE and an inner Li₂O-dominated layer that can protect Li from continuous side reactions during battery cycling. A LiF-rich transition layer is also discovered in the region of PPE close to Li metal anode. The feasibility of investigating interphases in polymer-based solid-state batteries via Cryo-TEM techniques is demonstrated, which can be widely employed in future to rationalize the correlation between solid-state electrolytes and battery performance from ultrafine interfacial structures.