Evaluation of some assumptions used in multizone airflow network models

Multizone airflow network models assume that in a zone air temperature and contaminant concentrations are uniform, and air momentum effects are neglected. These assumptions could cause errors for airflow with strong buoyancy, large contaminant concentration gradient, or strong momentum. This study has found the correlations of the errors and some dimensionless air parameters. The assumption of uniform air temperature is acceptable when the dimensionless temperature gradient is smaller than 0.03. The assumption of uniform contaminant concentration is valid if the corresponding Archimedes number for the source zone is greater than 400. The assumption of neglecting air momentum effect is reasonable when the jet momentum effect is dissipated before reaching an opening in downstream.     

Assessment of contaminant diffusivities in building materials from porosimetry tests

Recent studies have shown that surface and gaseous contaminant interactions may play an important role in indoor air quality. Modeling is an important tool to improve our knowledge about the phenomena involved and define appropriate ventilation strategies. However, data for sorption isotherms and diffusion in building materials remain woefully lacking. This paper deals with the latter point. It aims at investigating a methodology based on an analysis of the material porosity first and then the application of Carniglia's mathematical model to determine the effective diffusivity of gaseous species in building materials. This methodology, whose main principles are presented in the first part of the paper, was applied to seven commonly found materials. Mercury intrusion porosimetry (MIP) tests, and the calculations using Carniglia's model, reveal typical total porosities and tortuosity factors for these materials. The analysis of pore size distributions (PSDs) also draws one's attention to the possible differences in the pore structures that may exist between two samples of the same type of material and the differences in the effective diffusivities of contaminants that may result from them. The computed effective diffusivities were subsequently compared to data from experiments carried out in the frame of the EC project MATHIS. An agreement was obtained, thus validating Carniglia's methodology - a methodology that offers many practical advantages compared to diffusion-cell methods.     

Effects of contaminant metal ions on precipitation recovery of rare earth elements using oxalic acid

Solution equilibrium calculations were performed in this study to understand the impact of contaminant metal ions on the precipitation efficiency of selected ra...     

Cleaning AFM colloidal probes by mechanically scrubbing with supersharp “brushes”

Contamination control of atomic force microscope (AFM) tips (including standard but supersharp imaging tips and particle/colloidal probes) is very important for reliable AFM imaging and surface/interface force measurements. Traditional cleaning methods such as plasma, UV–ozone and solvent treatments have their shortcomings. Here, we demonstrate that calibration gratings with supersharp spikes can be employed to scrub away contaminants accumulated on a colloidal sphere probe by scanning the probe against the spikes at high load at constant-force mode. The present method is superior to traditional cleaning methods in several aspects. First, accumulated lump-like organic/inorganic material can be removed; second, removal is non-destructive and highly efficient based on a “targeted removal” strategy; third, removal and probe shape/morphology study can be completed in a single step (we report, to our best knowledge, the first evidence of the wear of the colloidal sphere during force measurements); and fourth, both colloidal/particle probes and standard but supersharp AFM imaging tips can be treated.     

Evaluation of the antimicrobial activity of aqueous extracts from dry Vaccinium corymbosum extracts upon food microorganism

As blueberries are rich in phenolic compounds, which possess a demonstrated antimicrobial activity, it may be interesting to further elucidate its real potential and properties. As such, the main goal of this work was to evaluate the potential antimicrobial activity of Vaccinium corymbosum dry fruits and leaves aqueous extracts against several contaminants/pathogenic microorganisms while at the same time assessing the effect of V. corymbosum over lactic acid bacteria.     

Laser induced breakdown spectroscopy for contamination removal on engine-run thermal barrier coatings

A method for cleaning thermal barrier coatings (TBCs) contaminated during engine operation has been developed using laser ablation. Surface contamination on the turbine blades hinders nondestructive remaining life evaluation using photoluminescence piezospectroscopy (PLPS). Real time monitoring of the removed material is employed to prevent damage to the underlying coating. This method relies on laser induced breakdown spectroscopy (LIBS) to compute the cross correlation coefficient between the spectral emissions of a sample TBC that is contaminated and a reference clean TBC. The ablation process is stopped when the LIBS signal indicates the presence of the underlying TBC. It is shown that it is possible to remove targeted contaminants and cease ablation at top surface of the TBC. Subsequent microscopy images and PLPS measurements indicate that the integrity of the TBC has been maintained during the removal of surface contaminants.     

Analytical Solutions and Simulation Approaches for Double Permeability Aquifers

In this paper we develop analytical solutions for 1D unsteady flow in an infinite double permeability aquifer. Two asymptotic cases are considered: the near-hydraulic-equilibrium-state and the far-hydraulic-equilibrium-state. It is demonstrated that for both cases the equation for the piezometric head can be expressed in leading order, as the classical solution of the simple permeability medium, to which correction terms are added. On the basis of these findings the accuracy of the simulations using conventional approaches (i.e. MODFLOW, MT3D codes) is discussed, while decision tools for the choice of the adequate double continuum model are also provided.     

A CFD Analysis of Ventilation Effectiveness in a Partitioned Room

A numerical model has been developed to investigate the contaminant removal and air freshness in a ventilated two-zone enclosure. The average contaminants and the distributions of air age in each zone under variable positions of door, supply and exhaust are compared. The correlation between the average contaminants and each of the main parameters, such as door location, supply and exhaust positions etc., are presented, and the average air ages in both zones are illustrated against door position. It is found that the average air age in the upstream zone is less affected by the door position than that in the downstream zone, and that the door position near the side-walls seems to give better air circulation. It is also concluded that the supply and door positions affect the concentration in the upstream zone significantly, while the exhaust location does not seem to influence the average concentration in either the upstream or the downstream zone.     

Experimental study of ventilation performance and contaminant distribution of underfloor ventilation systems vs. traditional ceiling-based ventilation system

Ventilation performance and pollutant distribution in a traditional ceiling-type ventilation system, a top-return (TR)-type and a floor-return (FR)-type underfloor ventilation systems were performed in a controlled experimental room. Tracer gas method was utilized to determine the age of air and the contaminant removal effectiveness. Tobacco smoke was also introduced to study the particle-phase pollutant distribution. The TR system delivered conditioned air more efficiently in the occupied zone and exhibited higher gaseous contaminant removal effectiveness. It also showed the lowest smoke particle concentration compared with the other two systems. The FR system showed better ventilation performance over the mixing system at the space that was close to the floor supply outlet and at the lower height level. The FR system was less effective than the TR system in removing buoyant tobacco smoke particles at the upper part of the room indicating its highly localized characteristics. Differences in experimental conditions between the present and the previous studies and their effects on the experimental results are discussed. In general, the experimental data suggested that both types of the underfloor ventilation systems have the potential of improving air quality at the breathing zone over the ceiling-based mixing system with suitable designs. PRACTICAL IMPLICATIONS: This study shows the possibility of improving indoor air quality using underfloor ventilation systems compared with the traditional ceiling-based ventilation system. However, different configurations of the underfloor ventilation system show various ventilation characteristics. The engineers should consider these features when implementing an underfloor ventilation design. The top-return (TR) configuration improves indoor air quality by creating a displacement-like flow pattern while the floor-return (FR) configuration shows highly localized ventilation characteristics. The FR configuration improved the indoor air quality at spaces near the floor diffusers and up to certain heights.     

Geographically distributed classification of surface water chemical parameters influencing fate and behavior of nanoparticles and colloid facilitated contaminant transport

The current production and use of nanomaterials in consumer products have increased the concern about the possibility that these enter the rivers during their entire life cycle. Further, many aquatic contaminants undergo partitioning to the ubiquitous aquatic colloids. Here is presented the development of a set of European water types for environmental risk assessment of chemicals transported as nanovectors as is the case of environmental fate of manufactured nanoparticles and colloid-bound contaminants.