纯剪切应变状态下天然橡胶元件的疲劳损伤特性

应用有限元分析与计算技术研究了橡胶元件实现纯剪切状态的设计要求,并计算了其5种疲劳损伤评价参数;通过加载扭转角位移实测了环形橡胶剪切试件的纯剪切疲劳损伤寿命,观察了该试件的疲劳失效位置和裂纹扩展方向;建立了疲劳损伤评价参数与纯剪切疲劳损伤寿命的幂函数模型。结果表明,环形橡胶剪切试件的内径与其厚度及高度的比值均约为10时,承载后可近似实现纯剪切应变状态;以转矩下降率25%为失效标准时,填充炭黑天然橡胶试件的纯剪切疲劳损伤寿命与其角位移、对数主应变、应变能密度、柯西主应力及剪切应变均存在较强的幂函数关系;环形橡胶剪切试件的裂纹扩展方向与其轴线方向成约45°角,且裂纹的产生位置为试件的应变集中区域。     

Melt Rheological Behavior and Creep Response of EVA/TPU Blends: Exploring the Effect of Electron Beam Irradiation and Peroxide Cross-linking

The present study focuses on the variation of the melt rheological characteristics and the creep behavior of both electron beam-cross-linked and peroxide-cured ethylene vinyl acetate/thermoplastic polyurethane blends. The variation of complex viscosity, complex modulus, storage modulus, and loss modulus was evaluated over a wide range of frequency and strain amplitude using rubber process analyzer and the effect of radiation dose and peroxide concentration was investigated in detail. The creep study using dynamic mechanical analyzer shows that the creep behavior of the blends significantly improves after cross-linking and the creep compliance gradually decreases with the increasing radiation dose and peroxide content. An attempt was also made to pursue a comparative rheological and creep study among the peroxide-cured, electron beam-cross-linked and the coagent-treated dynamically vulcanized samples.     

Cyclic creep response of adhesively bonded steel lap joints

The viscoelastic nature of polymeric adhesives means that the effect of fatigue frequency has to be treated cautiously. However, this subject has received limited attention and very few studies can be found. Therefore, this work aims at investigating the cyclic creep response of adhesively bonded steel lap joints. Load-controlled fatigue tests were performed with shear stresses of 9.1, 7.4, and 6.3 MPa, which are typically low cycle fatigue stresses. Only during the last 20% of fatigue life can we observe an increase in the cycle hysteresis area due to the decrease of the shear stiffness caused by the failure mechanisms. Under fatigue load, the maximum/minimum strain curves exhibit a shape being similar to that of the steady creep curves, in which occurs a second stage with nearly constant strain rate, independently of the number of cycles and increasing with the load range. A linear relationship between the log cyclic creep rate and the log of the number of cycles to failure was observed, indicating that fatigue behaviour is strictly related to cyclic creep.     

Effect of rotation extrusion and molecular weight on ductile failure of polyethylene pipes under hydrostatic pressure

ABSTRACT

In this study, two kinds of polyethylene (PE) with different molecular weight were processed into the pipes via rotation extrusion and the failure behaviours under hydrostatic pressure as well as molecular relaxation were investigated. The experimental results showed that the high molecular weight PE exhibited slower relaxation behaviour with higher relaxation activation energy to facilitate the formation of shish-kebab under flow field, while for the low molecular weight one, the stretching molecules easily relaxed back coil state and spherulites were prone to form. Therefore, the low molecular weight PE pipes via convention and rotation extrusions had similar isotropic spherulite morphology and short failure times. In the case of high molecular weight PE, during the convention extrusion, polymer melts flowed along the axial direction to induce the alignment of shish-kebab accordingly, which went against to the hoop stress in hydrostatic pressure. With the rotation of mandrel and die, the direction deviated from the axis so that PE pipe exhibited better resistance to the hoop stress. The failure time was 182?h, 264% longer than the convention-extruded one. Accordingly, a new strategy to prepare high hydrostatic pressure PE pipe under cooperative effects of rotation extrusion and long molecular relaxation time was proposed.     

Effect of Pressure Cycling on Fracture Energy of Polyurethane/Aluminum Adhesive Bonds

An experimental study was conducted to investigate the effect of pressure-cycling on adhesive bond fracture energy of polyurethane/aluminum adhesive bond joints. Initially, two types of peel tests were conducted to characterize adhesive bond strength and challenges associated with pre-mature polyurethane cracking and failure during these tests are discussed. A modified double cantilever beam (MDCB) specimen configuration was specially designed and opening-mode loading conditions were employed to determine the interfacial adhesive bond energy (G_C). The test specimens were pressure-cycled in water-filled tanks for 1 to 4 weeks with an increment of 1 week. The G_C of pressure-cycled specimens was compared with both control and water-soaked samples (without pressure-cycling). The results indicated that pressure-cycling decreased G_C values to those of the control and water-soaked samples: hence, prolonged pressure-cycling could be problematic to polymer/metal adhesive bonds of hardware installed outboard of submarine pressure hulls.     

An Analytical Model for Compressive Creep Behavior of HDPE Used in Plastic Pipe Manufacturing

The creep behavior of high-density polyethylene has been studied by low compressive creep tests, and empirical results were analyzed and compared with analytically predicted results. The tests are performed upon ASTM standard specimens at various stress levels in the linear region. After these analyses, a mathematical model is derived and used to predict creep strain for long periods of time from the strain-time data obtained at different stresses over a time interval of 24 h.     

A micromechanics study of competing mechanisms for creep fracture of zirconium diboride polycrystals

A micromechanics model was developed to simulate creep fracture of ceramics at high temperatures and material properties pertinent to zirconium diboride (ZrB₂) were adopted in the simulation. Creep fracture is a process of nucleation, growth, and coalescence of cavities along the grain boundaries in a localized and inhomogeneous manner. Based on the grain boundary cavitation process, creep fracture can be categorized into cavity nucleation-controlled and cavity growth-controlled processes. On the other hand, based on the deformation mechanism, the separation between two adjacent grain boundaries can be categorized into diffusion-controlled and creep-controlled mechanisms. In this study, a parametric study was performed to examine the effects of applied stress, cavity nucleation parameter, grain boundary diffusivity, and applied strain rate on cavity nucleation-controlled versus growth-controlled process as well as diffusion-controlled vs. creep-controlled mechanism during creep fracture of ZrB₂.     

Experimental study on high temperature performances of silica-based ceramic core for single crystal turbine blades

Silica-based ceramic cores are widely utilized for shaping the internal cooling canals of single crystal superalloy turbine blades. The thermal expansion behavior, creep resistance, and high temperature flexural strength are critical for the quality of turbine blades. In this study, the influence of zircon, particle size distribution, and sintering temperature on the high-temperature performance of silica-based ceramic cores were investigated. The results show that zircon is beneficial for narrowing the contraction temperature range and reducing the shrinkage, improving the creep resistance and high-temperature flexural strength significantly. Mixing coarse, medium and fine fused silica powders in a ratio of 5:3:2, not only reduced high temperature contraction, but effectively improved the creep resistance. Properly increasing the sintering temperature can slightly reduce the thermal deformation and improve the high-temperature flexural strength of the silica-based core, but excessively high sintering temperature negatively impacts the creep resistance and high-temperature flexural strength.     

Creep behaviour of an Al–Si–Al2O3 composite based on phase evolution at 1300oC

An Al–Si–Al₂O₃ composite was prepared with corundum, aluminium powder and silicon powder. A creep test was carried out at 1300°C under 0.2 MPa for 50 h in air. The results show that the Al–Si–Al₂O₃ composite performs a low constant creep rate and remain until the end of the 50-h test. This is attributed to the in-situ formation of the tough non-oxide reinforcements, whisker-like (AlN)_x(Al₂OC)_1-x solid solution and granular β-SiC, by reactions of Al and Si during creep test. The whisker-like (AlN)_x(Al₂OC)_1-x solid solution and granular β-SiC reinforcements are evenly filled in the pores, which play the role of bridging and pinning reinforcement, forming a strong network structure with corundum aggregates. Moreover, these non-oxide phases are not wetted by the liquid phases, which impel the liquid phase shrinks in the network structure in isolation during creep test. Thus, the adverse effect of the liquid phase on the high-temperature strength of the composites is eliminated, so the composites with strong network structure quickly get a stationary low-creep state. A creep mechanism model is established.     

Properties of super heat-resistant silicon carbide fibres with in situ BN coating

An in situ BN coating was prepared on the surface of a nearly stoichiometric continuous SiC fibre with trademark Cansas-3301 (C3). The coated fibre was then subjected to continuous pyrolysis at 1800 °C, obtaining a fibre named Cansas-BN-1800 (C18). After annealing in Ar at 1500 °C for 1 h, the strength retention ratio of C3 was 49%, and that of C18 was almost unchanged. The strength decrease of the C3 fibre was mainly caused by the formation of surface defects resulting from fibre decomposition and active oxidation. However, the in situ BN coating on C18 protected the fibre from forming surface defects, resulting in high strength. Due to slight growth of the grain and purification of the grain boundary during fast heating at 1800 °C, C18 showed excellent creep resistance in the range of 1200–1500 °C.