镁合金化学镀镍层的结合机理

镁合金在直接化学镀前的活化处理时，表面生成一层氟化物保护膜，溶解度计算及XPS分析表明，氟化物膜在镀液中可稳定存在，用SEM，XPS，SAM考察了初始沉积Ni，镀层横截面以及开裂后的断面形貌与成分，发现在镀层与基体之间存在着氟化物，镀液成分与Ni的混杂层，这一混杂层是镀层与基体结合的最薄弱环节，镀层开裂通常首先发生在此混杂层内。     

Influence of nickel and molybdenum on the phase stability and mechanical properties of maraging steels

The effect of nickel and molybdenum concentrations on the phase transformation and mechanical properties of conventional 18Ni(350) maraging steel has been investigated. Both of these elements act as strong austenite stabilizers. When the concentration of molybdenum or nickel is greater than 7.5 or 24 wt %, respectively, the austenite phase remains stable up to room temperature. In both molybdenum- and nickel-alloyed steels, the austenite phase could be transformed to martensite by either dipping the material in liquid nitrogen or subjecting it to cold working. When 7.5 wt% Mo and 24 wt% Ni were added in combination, however, the austenite phase obtained at room temperature did not transform to martensite when liquid-nitrogen quenched or even when cold rolled to greater than 95% reduction. The aging response of these materials has also been investigated using optical, scanning electron, and scanning transmission electron microscopy.     

Zr65Al7.5Ni10Cu17.5和Zr65Al10Ni10Cu15合金的非晶和晶态薄带吸氢行为研究

研究两种不同成分具有较大过冷液相区的四元合金Zr65Al7.5Ni10Cu17.5和Zr65Al10Ni10Cu15，非晶和晶态薄带吸氢行为，结果表qt两种薄带的吸氢量均随着温度的升高而增大，非晶薄带的吸氢量要小于同等条件下的晶态薄带的吸氢量且只有在673K吸氢后形成了氢化物，Zr65Al7.5Ni10Cu17.5非晶和晶态薄带吸氢后分别生成了Zr2NiH4.7和ZrH2；而Zr65Al10Ni10Cu15非晶和晶态两种薄带最后生成的氢化物同为ZrH2。     

The Effect of Sulfur Segregation on the Adherence of the Thermally-Grown Oxide on NiAl—I: Sulfur Segregation on the Metallic Surface of NiAl(001) Single-Crystals and at NiAl(001)/Al2O3 Interfaces

The aim of this study was to improve the understanding of the deleterious effect of sulfur impurities on the adherence of the thermally-grown oxide on the boundary layer in thermal-barrier-coating systems. In Part I, the sulfur segregation on the free surface of NiAl(001) and at different interfaces between metal and transient alumina scales has been characterized by AES, XPS and LEED. The sulfur diffusion coefficient in the alloy has been determined (D = 0.15 exp(–218,000/RT) cm²/s). It is by three orders of magnitude larger than the nickel and aluminum self-diffusion coefficients. It has also been observed that the sulfur de-segregates upon Al enrichment of the metallic surface. The saturation of the metallic surface with an amorphous alumina layer formed at room temperature blocks the segregation of S. However, in the initial stages of oxidation where the transient -alumina grows by cationic transport and inject vacancies at the interface, S segregates at the interface between the alumina thin films and the metallic substrate.     

废镍触媒的综合利用

本文采用酸溶，除渣，分离及蒸发浓缩，冷却，过滤等操作步骤从废镍触媒中回收有实用价值的硫酸镍，硫酸镁晶体，其回收率分别为75％和90％，经济效益也比较好。     

热变形参数对23Cr-6.2Mn-2.1Ni-0.28N节Ni型双相不锈钢点蚀行为的影响

采用热模拟、动电位极化曲线、交流阻抗谱等手段研究了热变形参数对23Cr-6.2Mn-2.1Ni-0.28N节Ni型双相不锈钢点蚀行为的影响。结果表明:实验钢的耐蚀性对应变速率、变形温度比较敏感,晶粒细化有利于提高试样的耐点蚀性能。在1和10 s-1的较高应变速率下,随变形温度升高,试样的耐蚀性先增加后降低,1050℃耐蚀性最好。随应变速率增加,再结晶晶粒细化程度降低,钝化膜稳定性减弱,试样耐蚀性逐渐降低。点蚀坑主要分布在δ相和δ/γ相界,随应变速率增加点蚀坑数量明显增多,尺寸变大。     

铌对镍基合金蠕变性能的影响

研究了Nb对Ni基合金高温蠕变性能的影响，认为Nb主要是通过增强第二组γ’相沉淀强化，γ相固溶强化，晶界M23C6呈链状分布，而使Ni基合金抗蠕变性能提高。     

Cup-drawing formation of steel sheet with nickel coating by finite element method

The finite element method （FEM） simulation of deep-drawing of steel sheet with nickel coating based on the solid element and dynamic explicit method was reported. Penalty function method was used to treat the contact algorithm. The friction between the punch and coating sheet was based on a Coulomb formulation. The combination of coating and substrate was defined as tied with failure contact. The results of the simulation illustrate that the steel sheet and the nickel coating do not delaminate at the interface. The stress field of the nickel coating is more complicated thala that of the steel substrate. Furthermore, it is found that the punch-nose radius is the most unsubstantial part for the intensity of the entire deep-drawing part and the thinnest part, it is a dangerous zone for the break. At this zone, the thickness thinning of the steel sheet and the nickel coating are up to 4.8% and 6.7%, respectively. Meanwhile, it is found that the curve of the variable blankholder force （VBHF） designed can improve the formability of sheet.     

Effect of grain size on high-temperature oxidation behavior of Cu-80Ni alloy

1　INTRODUCTIONTheoxidationofunalloyedcopperandnickelhasalreadybeenstudiedindetail.Whilethehigh tem peratureoxidationofCu Nialloys ,alsostudiedanumberoftimestodate[13] ,isanexampleofarela tivelysimpleclassofscalingofbinaryalloysbyasin gleoxidant,becausethemetalsformacontinuousse riesofsolidsolutions ,whiletheiroxides ,CuO ,Cu2 OandNiO ,exhibitsmallmutualsolubilitiesandshowsignificantdifferencesinthethermodynamicstabilityandparabolicgrowthrates .Thus ,copper richalloysformexternalscales…