Various softwood and hardwood bark residues, primary sludges and softwood sawdust residues were processed by vacuum pyrolysis in a laboratory scale batch reactor. The pyrolysis oil, water, charcoal, and gas were recovered and analyzed. The pyrolysis oils were analyzed in details for their content in phenolic compounds after derivatization to their acetyl derivatives. The influence of temperature, heating rate, feedstock bed thickness, particle size and feedstock water pretreatment on the yield of phenols was investigated. The highest yield of phenols was obtained when hardwood bark was soaked in water for 48 hours and pyrolyzed at a temperature of 450°C and a heating rate of 10°C/min. Pyrolysis performance was evaluated in terms of total phenolic yield and composition. 相似文献
Various poly(arylsilane)s The poly(carbosilane)s prepared in this way are of higher molecular weight than when prepared by the Wurtz-type condensation route previously reported. TG shows 40–50% overll weight loss attained at 500–600°C. 相似文献
Two-dimensional plain-weave silicon carbide fiber fabric reinforced silicon carbide (2D-SiC/SiC) composites were molded by
stacking method and densified through precursor infiltration and pyrolysis (PIP) process. SiC coating was deposited as the
fiber/matrix interphase layer by chemical vapor deposition (CVD) technique. Fiber/matrix debonding and relatively long fiber
pullouts were observed on the fracture surfaces. Additionally, the flexural strength and elastic modulus of the composites
with and without fiber/matrix interphase layer were investigated using three-point bending test and single-edge notched beam
test. The results show that the fiber fraction and the porosity of 2D-SiC/SiC composites with and without coating are 27.2%
(volume fraction) and 11.1%, and 40.7% (volume fraction) and 7.5%, respectively. And the flexural strength and elastic modulus
of 2D-SiC/SiC composites with and without coating are 363.3 MPa and 127.8 GPa, and 180.2 MPa and 97.2 GPa, respectively. With
a proper thickness, the coating can effectively adjust the fiber/matrix interface, thus causing a dramatic increase in the
mechanical properties of the composites.
Foundation item: Project(NCET-07-0228) support by the New Century Excellent Talents in University 相似文献