Different batches of natural graphite powders and electrographite powders were characterized by impurity, degree of graphitization, particle size distribution, specific surface area, and shape characteristics. The graphite balls consist of proper mix-ratio of natural graphite, electrographite and phenolic resin were manufactured and characterized by thermal conductivity, anisotropy of thermal expansion, crush strength, and drop strength. Results show that some types of graphite powders possess very high purity, degree of graphitization, and sound size distribution and apparent density, which can serve for matrix graphite of HTR-PM. The graphite balls manufactured with reasonable mix-ratio of graphite powders and process method show very good properties. It is indicated that the properties of graphite balls can meet the design criterion of HTR-PM. We can provide a powerful candidate material for the future manufacture of HTR-PM fuel elements. 相似文献
The importance of batch reactors in today's process industries cannot be overstated. Thus said, it is important to optimise their operation in order to consistently achieve products of high quality while minimising the production of undesirables. In processes like polymerisation, these reactors are responsible for a greater number of products than other reactor types and the need for optimal operation is therefore greater.
An approach based on an offline dynamic optimisation and online control strategy is used in this work to generate optimal set point profiles for the batch polymerisation of methyl methacrylate. Dynamic optimisation is carried out from which controller set points to attain desired polymer molecular end point characteristics are achieved. Temperature is the main variable to be controlled, and this is done over finite discrete intervals of time.
For on-line control, we evaluate the performance of neural networks in two controllers used to track the derived optimal set points for the system. The controllers are generic model control (GMC), ([P.L. Lee, G.R. Sullivan, Generic model control, Comput. Chem. Eng. 12(6) (1998) 573–580]) and the neural network-based inverse model-based control (IMBC), ([M.A. Hussain, L.S. Kershenbaum, Implementation of an inverse model based control strategy using neural networks on a partially simulated exothermic reactor, Trans. IchemE 78(A) (2000) 299–311]). Although the GMC is a model-based controller, neural networks are used to estimate the heat release within its framework for on-line control. Despite the application of these two controllers to general batch reactors, no published work exists on their application to batch polymerisation in the literature. In this work, the performance of the neural networks within each controller's algorithm for tracking and setpoint regulation of the optimal trajectory and in robustness tests on the system is evaluated. 相似文献
The behaviour of chromatographic simulated moving bed processes is described by the movement of concentration profiles through a circle of separation columns. A closed-loop control manipulates the profiles in order to meet demands concerning specified product purity and disturbance attenuation. If steep wave fronts of the concentration profiles occur, the controlled variables undergo fast changes in case of a transient of the process. In this case, a reconstruction of the wave fronts is necessary for a successful control.A simple and effective decentralised controller structure is proposed based on cascaded discrete-time PI controllers. On-line product purity measurements and the reconstructed wave fronts are used for control purposes. Two kinds of process models are used: a rigorous model for dynamic simulations, and strongly simplified plant models for the design of the wave front reconstruction and the controller. The latter models are identified based on experimental step tests with the reference plant and numerical simulations. The performance of the control system is evaluated by numerical simulations. 相似文献